SnO2 nanofibers were fabricated by calcination of the electrospun PVP/SnCl4 composite nanofibers. For the first time, SnS nanofibers and SnSe nanofibers were successfully synthesized by double-crucible sulfurization and selenidation methods via inheriting the morphology of SnO2 nanofibers used as precursors, respectively. X-ray diffraction (XRD) analysis shows SnS nanofibers and SnSe nanofibers are respectively pure orthorhombic phase with space group of Pbnm and Cmcm. Scanning electron microscope (SEM) observation indicates that the diameters of SnS nanofibers and SnSe nanofibers are respectively 140.54±12.80 nm and 96.52±14.17 nm under the 95 % confidence level. The photocatalytic activities of samples were studied by using rhodamine B (Rh B) as degradation agent. When SnS or SnSe nanofibers are employed as the photocatalysts, the respective degradation rates of Rh B solution under the ultraviolet light irradiation after 200 min irradiation are 92.55 % and 92.86 %. The photocatalytic mechanism and formation process of SnS and SnSe nanofibers are also provided. More importantly, this preparation technique is of universal significance to prepare other metal chalcogenides nanofibers.

In order to develop new-typed multifunctional composite nanofibers, PANI/Fe3O4/PVP flexible bifunctional composite nanofibers with simultaneous electrical conduction and magnetism have been successfully fabricated via a facile electrospinning technology. Polyvinyl pyrrolidone (PVP) is used as a matrix to construct composite nanofibers containing different amounts of polyaniline (PANI) and Fe3O4 nanoparticles (NPs). The bifunctional composite nanofibers simultaneously possess excellent electrical conductivity and magnetic properties. The electrical conductivity reaches up to the order of 10-3 S · cm-1. The electrical conductivity and saturation magnetization of the composite nanofibers can be respectively tuned by adding various amounts of PANI and Fe3O4 NPs. The obtained electricity-magnetism bifunctional composite nanofibers are expected to possess many potential applications in areas such as electromagnetic interference shielding, special coating, microwave absorption, molecular electronics and future nanomechanics. More importantly, the design concept and construct technique are of universal significance to fabricate other bifunctional one-dimensional nanostructures.

Um novo complexo de coordenação, [Zn(MCZ)3](NO3)2·H2 O, foi sintetizado através da reação de soluções aquosas de nitrato de zinco(II) e metilcarbazato. O complexo foi caracterizado por espectroscopia IV, análise elementar e por um estudo de difração de raios X. Cristaliza no grupo espacial monoclínico P2(1)/n. O íon metálico central é hexa-coordenado, com geometria octaédrica distorcida e se encontra ligado aos ligantes bidentados MCZ através dos átomos de oxigênio das carbonilas e dos átomos de nitrogênio terminais. Os cátions [Zn(MCZ)3]2+, os anions NO3- e as moléculas de água do retículo encontram-se interconectadas por forças eletrostáticas e por ligações de hidrogênio em um arranjo tridimensional. O mecanismo da decomposição térmica foi sugerido pelos estudos de DSC e TG-DTG. O composto [Zn(MCZ)3](NO3)2·H2 O começa a decompor-se a 181,9 °C, e o resíduo final, a 300,0 °C é ZnO.

A new coordination complex, [Zn(MCZ)3](NO3)2·H2O, was synthesized by the reaction of the aqueous solutions of zinc(II) nitrate and methyl carbazate. The complex was characterized by IR spectroscopy, elemental analysis and X-ray diffraction. It crystallizes in the monoclinic space group P2(1)/n. The central metal ion has distorted octahedral six-coordination environment, and is coordinated to bidentate MCZ ligands through carbonyl oxygen atoms and the terminal nitrogen atoms. [Zn(MCZ)3]2+ cations, NO3- anions and lattice water molecules are interconnected by electrostatic forces and hydrogen bonds into a 3-D network. The thermal decomposition mechanism was suggested by DSC and TG-DTG studies under the linear heating rates. [Zn(MCZ)3](NO3)2·H2O begins to decompose at 181.9 °C, and the final solid residue at 300 °C is ZnO.