Abstract Presented study focused on the incidence of pesticides: malathion, chlorpyrifos and λ-cyhalothrin and heavy metal, arsenic in the rice samples collected from the three main rice growing areas. 30 samples of brown Super Kernel Basmati rice and Super Basmati rice varieties, irrigated through tube well irrigation were selected. Highly sensitive and selective method of High Performance Liquid Chromatography was used for determination of pesticides. Results of analysis showed the presence of malathion in one sample in concentration of 18.26 mg/kg, chlorpyrifos in two samples in concentration of 3.3 mg/kg and 1.45 mg/kg respectively and λ-cyhalothrin in one sample in concentration of 1.848 mg/kg. Amount of pesticides detected in these samples were exceeding their maximum residual limits thus showed their strong potential to pose significant health risk. The presence of arsenic in rice was determined by Atomic Absorption Spectrophotometer and it was detected in 12 samples out of 30 in range of 0.04-0.28ppm. The detected arsenic concentration of arsenic in all samples was within the permissible limits set by WHO/FAO.

Abstract Tea is one of the most consumed beverages after water, but unfortunately the application of pesticides and heavy metals in crops make it unsafe for use. This research was conducted to evaluate the risk of heavy metals and pesticides in samples of natural source tea (gardens) and different local market brands. High Performance Liquid Chromatography was used to detect pesticides, Bifenthrin, Lambda chalothrin, Imadachloroprid, Dichlorovas, Glyphosate and Emamectin. Heavy metals such as Zinc, Iron, Chromium, copper, manganese and cobalt were determined by atomic absorption spectroscopy. The value of HRI and THQ was still calculated for some exceeded samples. From results obtained some of the tea samples were contaminated from with heavy metals i.e., cobalt and manganese and pesticides as: dichlorovas, imacloroprid, bifenthrin, emamectin, glyphosate, difenaconazole and lambda above the allowed limits. The assessments revealed the potential for potential health risk for the consumers. The results of the study suggested that risk assessment and monitoring should be done at source that is at the production and processing area so that toxic effects are not passed on to the consumers or to the environment.

Abstract The presence of pesticides in the environment is highly toxic to environment and human health. Aim of the study was determination, quantification and assessment of associated health risk due to presence of pesticide residues in chicken eggs using high pressure liquid chromatography. HPLC method was successfully employed and validated. From collected samples pesticides were extracted in presence of petroleum ether and acetonitrile. Bifenthrin and Difenoconazole residues were found in all samples with different concentration exceeding maximum residue limits (MRL) of Codex Alimentarius Commission. However imidacloprid was not detected in any sample. Concentration of bifenthrin in house egg samples ranged from 0.256206 to 4.112387 mg/kg while in poultry farm samples it varied from 1.5862 to 5.80796 mg/kg. Difenoconazole was found in concentration of 0.02835 mg/kg, 1.7668 mg/kg, 3.7205 mg/kg, 21.8937 mg/kg 21.9835 mg/kg, 19.26407 mg/kg in samples collected from houses while and in poultry farm samples its detected concentration was 10.939 mg/kg, 12.3296 mg/kg, 29.3617 mg/kg, 18.6116 mg/kg, 40.0523 mg/kg and 19.2335 mg/kg. Concentrations of both pesticides Bifenthrin and Difenoconazole exceeded the MRLs (0.05 mg/kg). Health risk index surpassed 1 (the cut off value) for Difenoconazole in seven samples while for Bifenthrin values were less than 1, indicating the possibility of potential medium to long term health risk associated with ingestion of contaminated eggs.

In this paper, an account for determination of chlorinated byproducts by High Performance Liquid Chromatography in various tap water samples is presented. The key objective of this study was to develop an analytical method for selectively and sensitively detecting the concentration of CBPs in addition to analyze selected parameters affecting CBP formation. Concentration of targeted compounds i.e. hydrazine sulfate, Dichloroacetic acid, Bromodichloromethane and chloroform were analyzed in tap water samples collected from a low socioeconomic area in a developing country. Hydrazine sulfate, Dichloroacetic acid and chloroform were detected in four water samples i.e. T4, T7, T9 and T10 while no samples contained Bromodichloromethane. Presence of these compounds in water is associated with cancer mortality and adverse reproductive outcomes.