The films of chitosan (CS)-silane crosslinked-poly(vinyl alcohol) (PVA) with different weight % were prepared. The effect on conductivity of CS/PVA blended films due to change in the concentration of PVA and temperature was investigated by impedance spectroscopy and showed good conductance properties. The complex impedance plots revealed single semicircular arcs indicating the bulk contribution to overall electrical behavior of all synthesized samples. The ac conductivity obeyed the Jonscher's power law for all samples in the frequency range of 2 kHz to 2 MHz. The ionic conductivity of the films was increased with the increase in temperature for all synthesized samples which showed an increase in the number of effective charge carriers while it was decreased at a specific higher temperature for each film. The observed activation energy for CP4, CP8 and CP10 were 0.431, 0.610 and 0.425 eV, respectively. These properties showed that the films were promising materials to be employed for conducting properties.