In the present work, polyesters were prepared from the polycondensation between glycerol and adipic acid using dibutyltin dilaurate as catalyst. Three glycerol: adipic acid molar ratio were used for the bulk polymerization namely: 2:2; 2:3 and 2:4. FTIR confirmed the esterification of glycerol by the acid for all the polymers. DSC and XRD indicated no crystallinity for all the polymers. The morphology of the materials are characterized by globular structure, which may suggest compositional fluctuations throughout the samples.

The production of polyester via polycondensation between glycerol and phthalic acid using dibutyltin dilaurate is reported. Three glycerol:phthalic acid molar ratio used for the bulk polymerization were: 2:2; 2:3 and 2:4. FTIR confirmed the esterification of glycerol by the acid for all the polymers. DSC indicated no crystallinity, although the XRD plots indicate a very incipient crystallinity for the polymers containing higher amounts of phthalic anhydride. Scanning electron microscopy results indicates high homogeneity for all the polymers prepared.