A fast gas chromatography with a flame ionisation detector (GC-FID) method for the simultaneous analysis of methyl palmitate (C16:0), stearate (C18:0), oleate (C18:1), linoleate (C18:2) and linolenate (C18:3) in biodiesel samples was proposed. The analysis was conducted in a customised ionic-liquid stationary-phase capillary, SLB-IL 111, with a length of 14 m, an internal diameter of 0.10 mm, a film thickness of 0.08 µm and operated isothermally at 160 °C using hydrogen as the carrier gas at a rate of 50 cm s-1 in run time about 3 min. Once methyl myristate (C14:0) is present lower than 0.5% m/m in real samples it was used as an internal standard. The method was successful applied to monitoring basic and acidic catalysis transesterification reactions of vegetable oils such as soybean, canola, corn, sunflower and those used in frying process.

Na Amazônia as series climatológicas estão baseadas na rede de estações meteorológicas de superfície que estão instaladas preferencialmente nas margens de rios. Portanto, o efeito de brisas fluviais que promovem precipitação no interior do continente não está sendo contabilizado nas medidas realizadas nestas estações. Além disto, estudos anteriores encontraram máximo de precipitação no período noturno sobre rios. Assim, este artigo examina a variabilidade espacial e temporal da precipitação na região de confluência dos rios Tapajós e Amazonas em Santarém, visando descrever a importância da brisa fluvial na distribuição da precipitação durante a tarde e definir a extensão da área onde ocorre maxima precipitação no período noturno. A refletividade medida pelo radar meteorológico banda S, instalado em Santarém para um período de três anos foi utilizada, tendo estes dados sido calibrados através dos dados do sensor de precipitação instalado abordo do satélite TRMM. A intensidade de precipitação foi estimada utilizando a relação ZR para o caso convectivo tropical. No período noturno, a máxima precipitação foi encontrada ao longo do rio Amazonas, consistente com a hipótese de que esta precipitação estaria associada a passagem das linhas de instabilidade neste período, talvez esta precipitação também esteja sendo reforçada pela canalização do rio e pela confluência do vento de retorno da brisa fluvial durante a noite. Para o período diurno, observou-se duas bandas de precipitações localizadas no interior do continente, uma ao longo da margem leste e outra ao sul dos rios Tapajós e Amazonas, respectivamente.

Standard Amazonian rainfall climatologies rely on stations preferentially located near river margins. River breeze circulations that tend to suppress afternoon rainfall near the river and enhance it inland are not typically considered when reporting results. Previous studies found surprising nocturnal rainfall maxima near the rivers in some locations. We examine spatial and temporal rainfall variability in the Santarém region of the Tapajós-Amazon confluence, seeking to describe the importance of breeze effects on afternoon precipitation and defining the areal extent of nocturnal rainfall maxima.We used three years of mean S band radar reflectivity from Santarém airport with a Z-R relationship appropriate for tropical convective conditions. These data were complemented by TRMM satellite rainfall estimates. Nocturnal rainfall was enhanced along the Amazon River, consistent with the hypothesis that these are associated with the passage of instability lines, perhaps enhanced by local channeling and by land breeze convergence. In the daytime, two rainfall bands appear in mean results, along the east bank of the Tapajós River and to the south of the Amazon River, respectively.

Inositol is a polyalcohol required for the proper formation of cell membranes. In the body, its plays an important role in the transmission of nerve impulses, its also helps in the transporting of fats within the body. In mammals, inositol exists as phosphorylated derivatives, various phosphoinositides, and in its free form. Agonist stimulated hydrolysis of phosphatidylinositol 4,5-bisphosphate [PI(4,5)P2] is the first step in the transmembrane signalling mechanism when cells respond to external stimuli. Under control of activated phospholipase C (PLC) via G-protein, two second messengers D-myo-inositol 1,4,5-triphosphate [Ins(1,4,5)P3] and diacylglycerol are released into the cell. From Ins(1,4,5)P3, enzymatic process under phosphatases or kinases control affords subsequent inositol phosphate metabolites. During the last decade the synthesis of modified inositol phosphate derivatives has been strongly investigated. This paper reviews principal aspects about synthesis and biological functions of these biomolecules.