ABSTRACT The aim of this study was to characterize buckwheat flours produced using different processing methods, including with or without tegument removal and sieving with different mesh sizes. Flour A was produced by milling clean grains without husks or any other waste derived from peeling and separation processes and by sieving using 0.21-mm sieves. Flour B was a by-product of flour A, with grain size measuring 0.21–0.25 mm. Flour C was produced by milling whole grains, which after grain separation using 0.21-mm sieves resulted in a fine, whole-grain flour. Flour D was produced from what remained in the 0.21-mm sieves after sieving flour C and was processed using 0.25-mm sieves. Flours were assessed regarding water content, water activity, pH, acidity, color, microscopic characteristics, and protein and ash content. The study design was completely randomized, and differences were tested using an analysis of variance and comparison-of-means tests. Milling and separation procedures changed most quality parameters, except for water activity. Flour D contained the largest proportion of crude protein (19.87%) and showed high solubility and darker coloration than the other flours. The results of this study may be of relevance for consumers and for commercial buckwheat processing to optimize processing methods for food manufacturing.

RESUMO O cártamo é uma cultura de elevado valor econômico que possui alto teor de óleo nos grãos e grande versatilidade industrial com vários benefícios à saúde humana. Assim, como outras culturas agrícolas é comum o armazenamento do cártamo para disponibilização em diferentes épocas do ano, e devido suas características higroscópicas tornam-se relevantes estudos que avaliem o efeito da temperatura e da umidade relativa do ar no teor de água. Deste modo, objetivou-se neste estudo determinar as isotermas de adsorção de água das sementes de cártamo e analisar as propriedades termodinâmicas. Os teores de água de 6,5; 6,9; 7,3; 7,7; 8,3 e 9,1% (base seca) foram obtidos por adsorção em condições controladas de temperatura (30 °C) e umidade relativa do ar (90%). As isotermas de adsorção foram obtidas pelo método estático indireto em diferentes temperaturas (10, 20, 30 e 40 °C). Com o aumento da temperatura, para um mesmo teor de água, tem-se elevação da atividade de água e, para uma atividade de água constante, os valores do teor de água de equilíbrio diminuíram com o aumento da temperatura. O modelo de Chung-Pfost apresentou o melhor ajuste para descrever o fenômeno de higroscopicidade das sementes de cártamo. As propriedades termodinâmicas foram influenciadas pelo teor de água das sementes, reduzindo a energia necessária para a absorção de água no produto com o aumento da adsorção, sendo a teoria da compensação entalpia-entropia controlada pela entalpia.

ABSTRACT Safflower is a crop of high economic value with high oil concentration in its seeds and great industrial versatility, besides various benefits to human health. As with other agricultural crops, it is common to store safflower to make it available in different periods of the year and, due to its hygroscopic characteristics, studies evaluating the effect of temperature and air relative humidity on its moisture content become relevant. Thus, the objective of the present study was to determine the water adsorption isotherms of safflower seeds and analyze their thermodynamic properties. Moisture contents of 6.5, 6.9, 7.3, 7.7, 8.3 and 9.1% (dry basis) were obtained by adsorption under controlled conditions of temperature (30 °C) and relative air humidity (90%). The adsorption isotherms were obtained by the indirect static method at different temperatures (10, 20, 30 and 40 °C). As temperature increased, for the same moisture content, there was an increase in water activity and, for constant water activity, the values of equilibrium moisture content decreased with increasing temperature. Chung-Pfost model showed the best fit to describe the phenomenon of hygroscopicity of safflower seeds. The thermodynamic properties were influenced by the moisture content of the seeds, reducing the energy necessary for water absorption in the product with the increase in adsorption, and the enthalpy-entropy theory was controlled by enthalpy.

RESUMO O processo de secagem de grãos é uma prática comum e necessária à manutenção da qualidade, porém é uma das atividades de maior demanda energética dentre as fases pós-colheita. Neste contexto, realizou-se este estudo com objetivo de avaliar os efeitos de diferentes períodos de repouso na eficiência energética do processo de secagem e manutenção da integridade das membranas dos grãos colhidos com teor de água de 0,34 ± 0,01 b.s. Os grãos foram secos em um secador experimental de camada fixa com controle de temperatura e fluxo de ar. O experimento foi montado em delineamento inteiramente casualizado, com cinco períodos de repouso (0, 4, 8, 12 e 16 horas) e quatro repetições, em que zero corresponde à secagem contínua e os demais à secagem intermitente. Os grãos foram secos a 100 ºC de temperatura e fluxo de ar de 15,4 m3 min-1 t-1 até atingir 0,16 ± 0,02 b.s. Para a secagem intermitente, o processo foi interrompido com 0,22 ± 0,03 b.s. e retomado após o período de repouso. O aumento do período de repouso diminuiu o tempo efetivo de secagem, consumo específico de energia, condutividade elétrica, danos da reação do iodo e aumentou a taxa de secagem e eficiência energética global. A secagem intermitente foi 30,25% mais eficiente que contínua.

ABSTRACT Grain drying is a common process, due to its need for the maintenance of quality, but it is the activity with the highest energy demand among the postharvest stages. Thus, this study aimed to evaluate the effect of different tempering times on the energy efficiency of drying process and maintenance of cell membrane integrity of maize grains harvested with moisture content at 0.34 ± 0.01 d.b. The grains were dried in an experimental fixed-bed dryer with control of temperature and air flow conditions. The experiment was conducted in a completely randomized design with five tempering times (0, 4, 8, 12 and 16 hours) and four repetitions, where zero corresponds to continuous drying, while the remaining times correspond to the intermittent dryings. The grains were dried at the temperature of 100 ºC and air flow of 15.4 m3 min-1 t-1 until reaching moisture content of 0.16 ± 0.03 d.b. For intermittent drying, the process was interrupted with 0.22 ± 0.02 d.b. and restarted after the tempering time. The increase of tempering time led to reductions in effective drying time, specific energy consumption, electrical conductivity and damage and increase in the drying rate and overall energy efficiency. Intermittent drying reduced the drying time, being 30.25% more efficient than continuous drying.

RESUMO Dentre as inúmeras plantas medicinais utilizadas pela população brasileira está a Solanum paniculatum L. (jurubeba), em que o uso de suas folhas é bastante popular, na forma de chá, como remédio contra ressacas após o consumo exagerado de álcool e comida, além de serem usadas na forma de pomadas como cicatrizantes, e, também, no tratamento de problemas hepáticos e digestivos. As folhas de plantas medicinais, normalmente, possuem elevado teor de água, necessitando a redução do mesmo por meio da secagem, para que o produto possa ser armazenado com segurança até o seu processamento. Objetivou-se com o presente estudo avaliar a cinética de secagem de folhas de jurubeba, bem como determinar o coeficiente de difusão efetiva e a energia de ativação durante a secagem. As folhas de jurubeba foram submetidas a secagem em diferentes temperaturas (30, 40, 50, 60 e 70 °C) e velocidade do ar (0,4 e 0,8 m s-1) . O modelo de Midilli ajustou-se satisfatoriamente aos dados observados da secagem das folhas de jurubeba para todas as condições. O aumento da temperatura e da velocidade do ar de secagem reduziu o tempo de secagem e aumentou o coeficiente de difusão efetiva. Para a faixa de temperatura de 40 a 70 °C, ao aumentar a velocidade do ar de secagem, reduz-se a energia de ativação para a secagem das folhas de jurubeba.

ABSTRACT Solanum paniculatum L. (jurubeba) is among the numerous medicinal plants used by the Brazilian population, and the use of its leaves is quite popular, in the form of tea, as a remedy against hangovers after excessive consumption of alcohol and food, besides being used in the form of ointments as healing agent and also in the treatment of liver and digestive problems. Leaves of medicinal plants usually have a high moisture content, requiring its reduction by drying, so that the product can be stored safely until its processing. The objective of this study was to evaluate the drying kinetics of jurubeba leaves and to determine the effective diffusion coefficient and activation energy during drying. Jurubeba leaves were dried at different air temperatures (30, 40, 50, 60 and 70 °C) and speed (0.4 and 0.8 m s-1). The Midilli model satisfactorily fitted to the observed data of drying of jurubeba leaves for all air conditions. Increasing the drying air temperature and speed reduced the drying time and increased the effective diffusion coefficient. For the air temperature range from 40 to 70 °C, as the drying air speed increases, the activation energy for the drying of the jurubeba leaves is reduced.

ABSTRACT This study aimed to obtain and evaluate thermodynamic properties and hygroscopic equilibrium isotherms of urunday seeds as a function of air relative humidity and temperature, as well as identify the best-fitted mathematical models for adsorption phenomenon. A static-gravimetric method was used to obtain hygroscopic equilibrium moisture content. Seeds were placed in airtight containers with different saturated saline solutions for relative humidity control. These were then kept in BOD incubator chambers at 10, 20, 30, and 40 °C. Hygroscopic equilibrium moisture content decreased as temperature increased, for the same water activity. The Sigma-Copace model best-fitted seed adsorption data for equilibrium water activity intervals between 0.1129 and 0.8232 (dry basis). Both vaporization latent-heat and differential sorption entropy increased with decreasing hygroscopic equilibrium moisture content. Adsorption process in urunday seeds was controlled by enthalpy.

ABSTRACT This study aimed to evaluate drying kinetics for natural and pulped coffee, using different temperatures and drying airflows. For the conduction of the experiment, coffee fruits (Coffea arabica L. cv. Topázio) were harvested manually, selecting only ripe fruits and subsequent to the hydraulic separation. For drying the coffee, use a mechanical dryer with two temperatures (40 and 45°C) and four drying air streams (24; 60; 96 and 132 m3.min-1.m-2). Twelve models for employees to describe the drying kinetics of coffees. Among the models used to describe the drying process of natural coffee and pulped coffee, according to the results of the coefficient of determination, relative mean error, standard deviation of estimates and distribution of waste distribution, proposed model for the only one that presents fit for all as conditions study. The temperature of 45 ° C and the airflows of 96 and 132 m3.min-1.m-2 provide the shortest drying times regardless of the coffee processing type.

RESUMO As folhas de amora preta possuem algumas propriedades farmacológicas e um dos usos mais difundidos e estudados é para alivio dos sintomas do climatério e de outros durante o período pré-menstrual. Desta forma, a secagem se torna importante para a conservação e o armazenamento do produto até o seu uso ou processamento. Diante do exposto, objetivou-se com o presente estudo avaliar a cinética de secagem de folhas de amora preta, bem como determinar o coeficiente de difusão efetivo e a energia de ativação durante o processo de secagem. As folhas de amora preta foram submetidas à secagem em um secador experimental de leito fixo, em quatro condições controladas de temperatura (40, 50, 60 e 70 °C) e duas velocidades do ar de secagem (0,4 e 0,8 m s-1). Aos dados experimentais de razão de teor de água foram ajustados oito modelos matemáticos para representarem o processo de secagem em camada delgada de produtos agrícolas. Com base nos resultados obtidos, verificou-se que o modelo de Midilli foi o que melhor representou o fenômeno da secagem de folhas de amora preta. O aumento da temperatura e da velocidade do ar reduziu o tempo de secagem das folhas de amora preta, bem como aumentou os valores do coeficiente de difusão efetivo, sendo que esta relação pode ser descrita pela equação de Arrhenius, que apresenta uma energia de ativação para a difusão líquida durante a secagem de 65,94 e 66,08 kJ mol-1, para as velocidades do ar de secagem de 0,4 e 0,8 m s-1, respectivamente.

ABSTRACT Blackberry leaves have some pharmacological properties and one of the most widespread and studied uses is to relieve symptoms of the climacteric and other symptoms during the premenstrual period. Thus, drying becomes important for the conservation and storage of the product until its use or processing. The present study aimed to evaluate the drying kinetics of blackberry leaves, as well as to determine the effective diffusion coefficient and the activation energy during the drying process. Blackberry leaves were dried in an experimental fixed-bed dryer under four controlled temperature conditions (40, 50, 60 and 70 °C) and two drying air speeds (0.4 and 0.8 m s-1). With the experimental data of moisture ratio, eight mathematical models were fitted to represent the process of thin-layer drying of agricultural products. Based on the obtained results, it was found that the Midilli model represented best the phenomenon of drying of blackberry leaves. The increase in temperature and air speed reduced the drying time of blackberry leaves and increased the values of the effective diffusion coefficient. This relation can be described by the Arrhenius equation, which has an activation energy for the liquid diffusion during drying of 65.94 and 66.08 kJ mol-1, for drying air speeds of 0.4 and 0.8 m s-1, respectively.

ABSTRACT: The objectives of this study were to describe the process of drying niger seeds through the fitting of different mathematical models to the experimental drying data, to select the best model that represents the phenomenon, and to determine the diffusion coefficients and thermodynamic properties of the product. Seeds with an initial moisture content of 0.42 (d.b) were collected and dried at 40°, 50°, 60°, 70°, and 80°C in a fixed bed experimental dryer. After drying, different mathematical models were fitted to determine the diffusion coefficient by applying liquid diffusion theory, which allowed for calculation of the energy activation, enthalpy, entropy, and Gibbs free energy values. The Page model was selected to represent the drying process of niger seed drying, as it is a traditional and simple model. The effective diffusion coefficient increased as the temperature increased. The activation energy for liquid diffusion at the temperature range of 40°C to 80°C was 46.83 kJ mol−1. The enthalpy and entropy specific values decreased as the drying air temperature increased. The Gibbs free energy values also increased as the drying air temperature increased.

RESUMO Objetivou-se, neste trabalho, determinar o coeficiente de difusão efetivo e as propriedades termodinâmicas das folhas de Bauhinia forficata Link, considerando-se duas formas de medição de espessura, bem como descrever o processo de secagem por meio do ajuste de modelos matemáticos. As folhas foram coletadas, levadas ao laboratório e preparadas para dar início ao processo de secagem em quatro temperaturas (40, 50, 60 e 70 °C). Após a secagem determinou-se o coeficiente de difusão efetivo por meio da teoria da difusão líquida permitindo a obtenção dos valores da energia de ativação, entalpia, entropia e energia livre de Gibbs. Já a descrição do processo de secagem foi realizada por meio do ajuste de treze modelos matemáticos constantemente utilizados para representação de secagem de produtos agrícolas. O modelo de Valcam foi selecionado para representar a cinética de secagem de folhas de B. forficata Link. O aumento da temperatura promove: decréscimo de entalpia e entropia; aumento da energia livre de Gibbs e do coeficiente de difusão efetivo. O coeficiente de difusão efetivo é maior quando se considera a espessura da nervura, recomendando-se a padronização e/ou especificação dos pontos de medição da espessura da folha.

ABSTRACT The aim of this study was to determine the effective diffusion coefficient and the thermodynamic properties of Bauhinia forficata Link leaves, considering two forms of thickness measurements and to describe the process by fitting mathematical models. The leaves were collected, taken to the laboratory and prepared to start the drying process in which four temperatures (40, 50, 60 and 70 °C) were applied. After the drying process, the effective diffusion coefficient was determined through the theory of diffusion in liquid, allowing to obtain the values of the activation energy, enthalpy, entropy and Gibbs free energy. The description of the drying process was performed by setting the thirteen mathematical models used to represent constant drying of agricultural products. The Valcam model was selected to represent the drying kinetics B. forficata Link. Increased temperature promotes: decreasing enthalpy and entropy; increasing Gibbs free energy and effective diffusion coefficient. The effective diffusion coefficient is higher when the rib thickness is considered; thus, it is recommended to standardize and/or specify the points of measurement of leaf thickness.

Com base na necessidade de combustíveis que substituam o petróleo, do destaque do pinhão-manso na produção de biodiesel e da necessidade de construção e aperfeiçoamento dos equipamentos utilizados nas fases de colheita e pós-colheita desta cultura objetivou-se, com o presente trabalho, determinar a forma e o tamanho dos frutos de pinhão-manso durante a secagem em cinco condições de ar. Os frutos colhidos manualmente com o teor de água de 4,40 (kg de água por kg de matéria seca) foram submetidos a secagem em estufa com circulação de ar forçada em cinco condições de temperatura, 45, 60, 75, 90 e 105 °C, e umidades relativas de 14,5; 7,4; 3,8; 2,2 e 1,4%, respectivamente, até atingir teor de água de 0,10 ± 0,007 (kg kg-1 de matéria seca). Foram determinados circularidade, esfericidade, volume, área superficial, área projetada e relação superfície-volume, ao longo da secagem. Conclui-se que a redução do teor de água e as condições de secagem alteram a forma e reduzem o tamanho dos frutos de pinhão-manso sendo possível ajustar uma única equação aos dados experimentais do volume e da área superficial dos frutos de pinhão-manso ao longo da secagem, em diversas temperaturas.

Due to the need for substitution of fuel oil, the importance of Jatropha for biodiesel and the need for construction and improvements of the equipment used during harvest and postharvest of this crop, this research aimed to determine the shape and the size of Jatropha fruit during drying under five ambient conditions. The fruits harvested manually with moisture content of 4.40 kg kg-1 dry matter were dried in an oven with forced air ventilation in five temperature conditions: 45, 60, 75, 90 and 105 °C and relative humidities of 14.5, 7.4, 3.8, 2.2 and 1.4% respectively, until moisture content of 0.10 ± 0.007 (kg kg-1 dry matter). The roundness, sphericity, volume, surface area, projected area and surface-volume ratio were determined during drying. It is concluded that the reduction of the moisture content and the drying conditions alter the shape and reduce the size of the fruit of Jatropha, being possible to adjust a single equation to the experimental data of volume and surface area of the fruit of Jatropha during drying at different temperatures.