Estanatos de metais alcalinos terrosos aplicados em fotocatálise: prospecção e revisão da literatura

Honorio, L. M. C.; Santos, M. V. B.; Silva Filho, E. C. da; Osajima, J. A.; Maia, A. S.; Santos, I. M. G. dos

doi:10.1590/0366-69132018643722480

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Articles • Cerâmica 64 (372) • Oct-Dec 2018 • https://doi.org/10.1590/0366-69132018643722480 copiar

Estanatos de metais alcalinos terrosos aplicados em fotocatálise: prospecção e revisão da literatura

Autoria SCIMAGO INSTITUTIONS RANKINGS

Resumo

A classe de óxidos mistos ABO₃ conhecida por sua estrutura do tipo perovskita vêm despertando grande interesse científico-tecnológico nas últimas décadas, em função de suas propriedades ópticas, magnéticas e condutoras. Este trabalho teve por objetivo buscar, nos bancos de artigos e de patentes, trabalhos que relacionem a atividade fotocatalítica dos estanatos de metais alcalinos terrosos - BaSnO₃, CaSnO₃ e SrSnO₃ como fotocatalisadores para aplicação ambiental. Os bancos de dados pesquisados foram o Web of Science, Scopus e Scielo para os artigos e USPTO, EPO e INPI para os bancos de patentes. A partir dos critérios de exclusão, 21 artigos de revisão apresentaram parâmetros e condições experimentais distintas. Devido ao excelente desempenho fotocatalítico, os estanatos apresentam-se como candidatos promissores na fotocatálise heterogênea.

Palavras-chave:
estanatos; perovskita; fotocatálise

Table I Number of articles found on the Web of Science, Scopus and Scielo databases.

Keywords	Web of Science		Scopus		Scielo
Keywords	Total	2007-2017	Total	2007-2017	Total	2007-2017
Stannates or MSnO₃	263	153	332	216	5	3
Barium stannate or BaSnO₃	559	388	247	169	1	0
Calcium stannate or CaSnO₃	172	121	68	43	1	0
Strontium stannate or SrSnO₃	177	119	72	48	3	3
Photocatalytic properties	6931	6396	6866	6306	11	11
BaSnO₃ and photocatalytic	18	17	1	1	1	1
CaSnO₃ and photocatalytic	11	11	2	2	1	1
SrSnO₃ and photocatalytic	22	21	1	1	0	0

Table II Summary of the synthesis methods and experimental parameters.

Stannate	Method of synthesis	Precursors	T (°C)	t (h)	Ref.
Hydrogen production
SrSnO₃	Sol. chemistry / solid state	Sr(NO₃)₂ / SnCl₄ Sr(NO₃)₂ / H₂O₂ / Sr(NO₃)₂ / SnCl₄	700-1000	6-6	¹⁵15 C.W. Lee, D.W. Kim, I.S. Cho, S. Park, S.S. Shin, S.W. Seo, K.S. Hong, Int. J. Hydrogen Energy 37 (2012) 10557.
MSnO₃	Solid state	MCO₃ (M= Ca, Sr, Ba) SnO₂	1000-1450	6-15	³⁶36 W. Zhang, J. Tang, J. Ye, J. Mater. Res. 22 (2007) 1859.
MSnO₃	Hydrothermal and calcination	CaCl₂ / SrCl₂ / BaCl₂.2H₂O / SnCl₄ / NaOH	180-700	24-6	⁴³43 F. Zhong, H. Zhuang, Q. Gu, J. Long, RSC Adv. 6 (2016) 42474.
SrSnO₃	Hydrothermal and calcination	Sr(NO₃)₂ / Na₂SnO₃	180-1000	16-6	⁴⁴44 D. Chen, J. Ye, Chem. Mater. 19 (2007) 4585.
BaSnO₃	Polymer complex	SnCl₄.5H₂O / ethylene glycol / citric acid / BaCO₃ / SrCO₃	1000	3	⁴⁵45 Y. Yuan, J. Lv, X. Jiang, Z. Li, T. Yu, Z. Zou, J. Ye, Appl. Phys. Lett. 91 (2007) 27.
SrSnO₃	Solid state	Sr(NO₃)₂ / SnO₂	-	-	⁴⁶46 W.F. Zhang, J. Tang, J. Ye, Chem. Phys. Lett. 418 (2006) 174.
SrSnO₃	Solid state	SrCO₃ / SnO₂	1200	-	⁵⁰50 B. Bellal, B. Hadjarab, A. Bouguelia, M. Trari, Theoret. Exp. Chem. 45 (2009) 172.
BaSnO₃	Citrate modified	Ba (NO₃)₂ / Pb(CH₃CO₂)₄ SnCl₄.5H₂O	700	10	⁵¹51 P.H. Borse, U.A. Joshi, S.M. Ji, J.S. Jang, J.S Lee, E.D. Jeong, H.G. Kim, Appl. Phys. Lett. 90 (2007) 34103.
SrSnO₃	Hydrothermal and calcination	Sr(CH₃COO)₂ / SnCl₄.5H₂O / NaOH	700	3	⁵²52 T. Alammar, I. Hamm, V. Grasmik, M. Wark, A.V. Mudring, Inorg. Chem. 56 (2017) 6920.
Dye photodegradation
SrSnO₃	Hydrothermal and calcination	SnCl₂.2H₂O Sr(CH₃CO₂)₂	500, 700, 900	3	¹⁶16 P. Junploy, S. Thongtem, T. Thongtem, Superlattices Microstruct. 57 (2013) 1.
BaSnO₃	Co-precipitation	Ba(Sal)₂ / SnCl₂.2H₂O	700	4	⁴¹41 S. Moshtaghi, S. Zinatloo-Ajabshir, J. Mater. Sci. Mater. Electron. 27 (2016) 834.
BaSnO₃	Co-precipitation	Ba(Sal)₂ / SnCl₂.2H₂O	700	4	⁴²42 S. Moshtaghi, S. Zinatloo-Ajabshir, J. Mater. Sci. Mater. Electron. 27 (2016) 425.
SrSnO₃:N	Solid state	SrCO₃ / SnO₂	800-1000	6-24	⁵³53 T.M. Lobo, R. Lebullenger, V. Bouquet, M. Guilloux-viry, I.M.G. Santos, I.T. Weber, J. Alloys Compd. 649 (2015) 491.
Sr1-xBaxSnO₃	Solid state	SrCO₃, SnO₂, BaCO₃ SrCO₃ / SnO₂ / Sr(NO₃)₂	1000-1100	6-8	⁵⁴54 H.B. Sales, V. Bouquet, S. Députier, S. Ollivier, F. Gouttefangeas, M. Guilloux-viry, I.M.G. Santos, Sol. State Sci. 28 (2014) 67.
SrSnO₃	Precipitation	Sr(sal)₂ / SnCl₂.2H₂O	900	5	⁵⁵55 S. Moshtaghi, S. Gholamrezaei, M.S. Niasari, P. Mehdizadeh, J. Mater. Sci. Mater. Electron. 27 (2016) 414.
MSnO₃	Hydrothermal and calcination	NaSnO₃ / Ca(NO₃)₂ / Sr(NO₃)₂ / Ba(NO₃)₂	800	6	⁵⁶56 W. Wang, S. Liang, K. Ding, J. Bi, C.Y. Jimmy, P.K. Wong, L. Wu, J. Mater. Sci. 49 (2014) 1893.
Ag/SrSnO₃	Hydrothermal and calcination	Sr(CH₃CO₂)₂ / SnCl₂·2H₂O / AgNO₃	900	3	⁵⁷57 P. Junploy, T. Thongtem, S. Thongtem, A. Phuruangrat, J. Nanomater. 2014 (2014) 261395.
BaSnO₃	Modified Pechini	Sn metal / Ba(NO₃)₂ citric acid / ethylene glycol / NH₄OH	800	4	⁵⁸58 K.F. Moura, L. Chantelle, D. Rosendo, E. Longo, I.M.G. dos Santos, Mater. Res. 20, Suppl. 2 (2017) 317.
CaSn(OH)₆	Sonochemical	Na₂Sn(OH)₆ / SnCl₄.5H₂O CaCl₂ / Na₂CO₃ / NaOH	-	-	⁵⁹59 S. Meng, D. Li, M. Sun, W. Li, J. Wang, J. Chen, G. Xiao, Catal. Commun. 12 (2011) 972.
CaSnO₃	Modified Pechini	Metallic Sn / Ca(NO₃)₂ citric acid / ethylene glycol / NH₄OH	800	4	⁶⁰60 G.L. Lucena, L.C. de Lima, L.M.C. Honório, A.L.M. de Oliveira, R.L. Tranquilim, E. Longo, A.G. de Souza, I.M.G. dos Santos, Cerâmica 63, 368 (2017) 536.
CaSnO₃	Co-precipitation	Ca(Sal)₂ / SnCl₂	900	5	⁶¹61 S. Moshtaghi, S. Gholamrezaei, M.S. Niasari, J. Mol. Struct. 1134 (2017) 511.

Table III Numbers of patents found in the EPO, USPTO and INPI patents database.

Keywords	USPTO	EPO	INPI (Portuguese)
Stannates or MSnO₃	21	172	Estanatos ou MSnO₃
Barium stannate or BaSnO₃	5	167	Estanato de bário ou BaSnO₃
Calcium stannate or CaSnO₃	2	91	Estanato de cálcio ou CaSnO₃
Strontium stannate or SrSnO₃	1	32	Estanato de estrôncio ou SrSnO₃

Table IV Stannates applied in the H2 generation.

Photocatalyst	Measure	Reaction condition	Ref.
SrSnO₃	H₂ generation	Reactor quartz; closed gas circulation system 450 W Hg lamp	¹⁵15 C.W. Lee, D.W. Kim, I.S. Cho, S. Park, S.S. Shin, S.W. Seo, K.S. Hong, Int. J. Hydrogen Energy 37 (2012) 10557.
CaSnO₃, BaSnO₃ SrSnO₃	H₂ / O₂ generation	Quartz cell; closed gas circulation system - 400 W Hg lamp	³⁶36 W. Zhang, J. Tang, J. Ye, J. Mater. Res. 22 (2007) 1859.
CaSnO₃, BaSnO₃ SrSnO₃	H₂ generation	Container of quartz; closed gas circulation system - 125 W Hg lamp	⁴³43 F. Zhong, H. Zhuang, Q. Gu, J. Long, RSC Adv. 6 (2016) 42474.
SrSnO₃	H₂ / O₂ generation	Quartz cell; closed gas circulation system - 400 W Hg lamp	⁴⁴44 D. Chen, J. Ye, Chem. Mater. 19 (2007) 4585.
BaSnO₃	H₂ generation	Quartz cell; closed gas circulation system - 400 W Hg lamp	⁴⁵45 Y. Yuan, J. Lv, X. Jiang, Z. Li, T. Yu, Z. Zou, J. Ye, Appl. Phys. Lett. 91 (2007) 27.
SrSnO₃	H₂ / O₂ generation	Quartz cell; closed gas circulation system - 400 W Hg lamp	⁴⁶46 W.F. Zhang, J. Tang, J. Ye, Chem. Phys. Lett. 418 (2006) 174.
SrSnO₃ SrSnO₃/CuFeO₂	H₂ / O₂ generation	Pyrex reactor; closed gas circulation system - three 200 W- W lamps	⁵⁰50 B. Bellal, B. Hadjarab, A. Bouguelia, M. Trari, Theoret. Exp. Chem. 45 (2009) 172.
BaSnO₃	H₂ generation	Closed gas circulation system - 300 W Xe lamp	⁵¹51 P.H. Borse, U.A. Joshi, S.M. Ji, J.S. Jang, J.S Lee, E.D. Jeong, H.G. Kim, Appl. Phys. Lett. 90 (2007) 34103.
SrSnO₃	H₂ generation	Reactor quartz; closed gas circulation system 700 W Hg lamp	⁵²52 T. Alammar, I. Hamm, V. Grasmik, M. Wark, A.V. Mudring, Inorg. Chem. 56 (2017) 6920.

Table V Stannates applied to the degradation of textile dyes.

Photocatalyst	Dye	Reaction condition	Ref.
SrSnO₃	Methylene blue	Two 18W UV lamps	¹⁶16 P. Junploy, S. Thongtem, T. Thongtem, Superlattices Microstruct. 57 (2013) 1.
BaSnO₃	Erythrosine	UV irradiation in quartz reactor - 400 W Hg lamp	⁴¹41 S. Moshtaghi, S. Zinatloo-Ajabshir, J. Mater. Sci. Mater. Electron. 27 (2016) 834.
BaSnO₃	Eriochrome black T	UV irradiation in quartz reactor - 400 W Hg lamp	⁴²42 S. Moshtaghi, S. Zinatloo-Ajabshir, J. Mater. Sci. Mater. Electron. 27 (2016) 425.
SrSnO₃:N	Methylene blue	Reactor (batch) and UV and visible lamps (120 W - Hg) and (100 W - W)	⁵³53 T.M. Lobo, R. Lebullenger, V. Bouquet, M. Guilloux-viry, I.M.G. Santos, I.T. Weber, J. Alloys Compd. 649 (2015) 491.
Ba_1-xSr_xSnO₃	Remazol golden yellow	Petri plate and UVC lamp of λ= 254 nm	⁵⁴54 H.B. Sales, V. Bouquet, S. Députier, S. Ollivier, F. Gouttefangeas, M. Guilloux-viry, I.M.G. Santos, Sol. State Sci. 28 (2014) 67.
SrSnO₃	Acid blue-92 acid black-1	Reactor glass and UV and visible lamps (Osram Ultra-Vitalux 300 W)	⁵⁵55 S. Moshtaghi, S. Gholamrezaei, M.S. Niasari, P. Mehdizadeh, J. Mater. Sci. Mater. Electron. 27 (2016) 414.
CaSnO₃, BaSnO₃ SrSnO₃	Methyl orange	Reactor (tube) quartz with 3 lamps of 4 W - Philips, TUV4W / G4 T5	⁵⁶56 W. Wang, S. Liang, K. Ding, J. Bi, C.Y. Jimmy, P.K. Wong, L. Wu, J. Mater. Sci. 49 (2014) 1893.
Ag/SrSnO₃	Methylene blue	Two UV lamps - 15 W	⁵⁷57 P. Junploy, T. Thongtem, S. Thongtem, A. Phuruangrat, J. Nanomater. 2014 (2014) 261395.
BaSn_1-x Fe_xO₃	Remazol golden yellow	Irradiation of UVC lamp (0.5-1.0 mW) mod. ZG-30T8	⁵⁸58 K.F. Moura, L. Chantelle, D. Rosendo, E. Longo, I.M.G. dos Santos, Mater. Res. 20, Suppl. 2 (2017) 317.
CaSn(OH)₆	Methyl orange	UV irradiation	⁵⁹59 S. Meng, D. Li, M. Sun, W. Li, J. Wang, J. Chen, G. Xiao, Catal. Commun. 12 (2011) 972.
CaSnO₃	Remazol golden yellow	Petri plate and UVC lamp of λ= 254 nm	⁶⁰60 G.L. Lucena, L.C. de Lima, L.M.C. Honório, A.L.M. de Oliveira, R.L. Tranquilim, E. Longo, A.G. de Souza, I.M.G. dos Santos, Cerâmica 63, 368 (2017) 536.
CaSnO₃	Acid blue-92 acid brown-14	Reactor glass and UV and visible lamps (Osram Ultra-Vitalux 300 W)	⁶¹61 S. Moshtaghi, S. Gholamrezaei, M.S. Niasari, J. Mol. Struct. 1134 (2017) 511.

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