Menu
Brasil
home Sumário navigate_before Anterior Atual Seguinte navigate_next
home Sumário
Communications • J. Braz. Chem. Soc. 16 (4) • Aug 2005 • https://doi.org/10.1590/S0103-50532005000500002 linkcopy

Open-access Isobutane/2-butene alkylation with zeolite Y without Br<FONT FACE=Symbol>Æ</FONT>nsted acidity

AuthorshipSCIMAGO INSTITUTIONS RANKINGS

    Abstracts

    Alkylation of isobutane with 2-butene was performed on metal-exchanged Y zeolites, using an alkylchloride as carbocation initiator. The results indicated that, compared with a protonic zeolite, the deactivation was significantly slower and the production of trimethylpentanes was higher on the metal-exchanged zeolites. The metal cations act as Lewis acids, interacting with the chloride initiating the carbocationic reactions. The results also support the view that protonic sites on the catalyst favor adsorption of the olefin, thus increasing oligomerization rate.

    alkylation; zeolite; Br<FONT FACE=Symbol>Æ</FONT>nsted acidity; gasoline

    vertical_align_top show_chart
    location_on
    Sociedade Brasileira de Química Instituto de Química - UNICAMP, Caixa Postal 6154, 13083-970 Campinas SP - Brazil, Tel./FAX.: +55 19 3521-3151 - São Paulo - SP - Brazil
    E-mail: office@jbcs.sbq.org.br
    rss_feed Acompanhe os números deste periódico no seu leitor de RSS
    Reportar erro