Acessibilidade / Reportar erro

Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction

An efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using ¹H-NMR spectroscopy.

Hetero Diels-Alder; tetra-methyl purpurogallin; nitrosobenzene


Sociedade Brasileira de Química Instituto de Química - UNICAMP, Caixa Postal 6154, 13083-970 Campinas SP - Brazil, Tel./FAX.: +55 19 3521-3151 - São Paulo - SP - Brazil
E-mail: office@jbcs.sbq.org.br