Preliminary XRD, IR, Raman and SEM data indicate that porous glass-ceramic monoliths (pgc-LVCP) with skeleton of V(PO3)3 and Ca3(VO4)2 with three-dimensional network structure using an original Li2O-V2O3-CaO-P 2O5 glass as precursor was obtained. The pgc-LVCP is a promising porous host for integrated chemical systems because the Ca3(VO4)2 has ferroelectric and luminophor properties while V(PO3)3 exhibits magnetic properties associated with high degree of mechanical, chemical and thermal stability.
porous materials; vanadium metaphosphate; calcium orthovanadate; vanadium glass; devitrification
