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Articles • J. Braz. Chem. Soc. 20 (7) • 2009 • https://doi.org/10.1590/S0103-50532009000700009   copy

Oxidation of chalcogenides using the peroxo complex of molybdenum [MoO(O2)2(H2O)(hmpa)], hmpa = hexamethylphosphoramide

Authorship SCIMAGO INSTITUTIONS RANKINGS

This work reports the oxidation of a variety of selenides, sulfides, tellurides, selenoxides, sulfoxides and telluroxides with [MoO(O2)2(H2O)(hmpa)] [hmpa = (Me2N)3PO] in tetrahydrofuran at 65-70 ºC to produce the corresponding selenones, sulfones and tellurones in high yields.

chalcogenides; sulfide; selenide; telluride; oxidation; [MoO(O2)2(H2O)(hmpa)]

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