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Materials Research, Volume: 3, Número: 2, Publicado: 2000
  • Zanotto, Edgar Dutra
  • Materials selection as an interdisciplinary technical activity: basic methodology and case studies Review Article

    Ferrante, M.; Santos, S.F.; Castro, J.F.R. de

    Resumo em Inglês:

    The technical activity known as Materials Selection is reviewed in its concepts and methodologies. Objectives and strategies are briefly presented and two important features are introduced and discussed; (i) Merit Indices: a combination of materials properties, which maximises the objectives chosen by the designer and (ii) Materials Properties Maps: a bi-dimensional space whose coordinates are pairs of properties in which materials can be plotted and compared directly in terms of their merit indices. A general strategy for the deduction of these indices is explained and a formal methodology to establish a ranking of candidate materials when multiple constraints intervene is presented. Finally, two case studies are discussed in depth, one related to materials substitution in the context of mechanical design and a less conventional case linking material selection to physical comfort in the home furniture industry.
  • Hygrothermal effects on the tensile strength of carbon/epoxy laminates with molded edges Original Articles

    Cândido, Geraldo Maurício; Rezende, Mirabel Cerqueira; Almeida, Sérgio Frascino Müller de

    Resumo em Inglês:

    The interlaminar stresses are confined to a region near the free edge. Therefore, the laminate stacking sequence and the free edge finishing are some of the factors that affect the strength of the laminate and limit its life. The use of molded edges eliminates the need for trimming and machining the laminates edges thus improving productivity. However, this fabrication technique may have a detrimental effect on the laminate strength for certain stacking sequences. This effect in the presence of moisture has not been characterized. This work presents the results of a comparative study of the resistance to delamination of laminates with machined edges and molded edges. Additionally, two environmental conditions were considered: dry laminates and laminates saturated with moisture. The tensile strength of the laminates were measured and micrographs were used to analyze the microstructure of the laminates near the free edges. It is concluded that the mechanical properties of advanced composites depend on the environmental conditions and the fabrication techniques used to produce the laminates. Therefore, it is necessary to account for these factors when experimentally determining the design allowables.
  • Rheological analysis of the phenolic and furfuryl resins used in the carbon materials processing Original Articles

    Botelho, Edson Cocchieri; Scherbakoff, Natália; Rezende, Mirabel Cerqueira

    Resumo em Inglês:

    Carbon materials processing is an advanced technology due to its aerospace and medical applications. In the aerospace area one can mention the carbon/carbon composites used in rockets and aeronautical brakes; in the medical area one can mention the intrabody implant tools such as heart and hydrocephalic valves and pacemaker electrode tips. The highly sophisticated purpose of its application requires a very tight processing control, which defines the microstructure the mechanical, thermal and electrical characteristics of the final material. The objective of this study is to correlate rheological, chromatographic and thermal analysis of phenolic and furfuryl resins, aiming their use as raw materials in carbon/carbon composite and glassy carbon processing. The obtained results are correlated and used directly in the establishment of the adequate parameters for carbon reinforcement impregnation and to prepare glassy carbon samples with controlled porosity.
  • Rice hull-derived silica: applications in Portland cement and mullite whiskers Original Articles

    Souza, M.F. de; Batista, P.S.; Regiani, I.; Liborio, J.B.L.; Souza, D.P.F. de

    Resumo em Inglês:

    Silica was extracted from rice hulls by three processing routes, starting with acid treatment followed by burning and milling. The amorphous white silica powder showed a surface area of 260 to 480 m²/g, purity above 99% and average particle size of 2.0 to 0.6 mm. This silica is suitable for the preparation of mullite whiskers employing the rare earth aluminosilicate glass technique. Due to its highly pozzolanic reaction, this prepared silica is used as an additive in high performance concrete.
  • Reis, G.S.; Jorge Jr., A.M.; Balancin, O.

    Resumo em Inglês:

    Two types of duplex stainless steels were deformed by torsion at a temperature range of 900 to 1200 °C and strain rate of 1.0 s-1 and their final microstructures were observed. The austenite volume fraction of steel A (26.5Cr - 4.9Ni - 1.6Mo) is approximately 25% at room temperature, after conventional annealing, while that of steel B (24Cr - 7.5Ni - 2.3Mo) is around 55%. Experimental data show that steel A is ductile at high temperatures and displays low ductility at low temperatures, while steel B has low ductility in the entire range of temperatures studied. At high temperatures, steel A is essentially ferritic and shows dynamic recrystallized grains after deformation. When steel A is strained at low temperatures and displays low austenite volume fraction, microstructural observations indicate that failure is triggered by grain boundary sliding due to the formation of an austenite net structure at the ferrite grain boundaries. At intermediate volume fraction, when austenite forms a dispersed second-phase in steels A and B, failure begins at the ferrite/ferrite boundaries since some of the new ferrite grains may become immobilized by the austenite particles. When steel B is strained at volume fraction of around 50% of austenite and both phases percolate the microstructure, failure occurs after low straining as a consequence of the different plastic behaviors of each of the phases. The failure characteristics of both steels are correlated not only with the volume fraction of austenite but also with its distribution within the ferrite matrix, which limits attainable strain without failure.
  • Mechanical and morphological characterization of polypropylene toughened with olefinic elastomer Original Articles

    Lotti, Cybele; Correa, Carlos A.; Canevarolo, Sebastião V.

    Resumo em Inglês:

    The effect of incorporating (C2-C8) ethylene-octene elastomer on the mechanical properties and morphology of polypropylene copolymers has been investigated employing two types of PP copolymer, with and without nucleating agent. The results were compared to the ones presented by a commercial PP heterophase (reactor impact modified PP/EPR). The addition of the elastomer increases the toughness of the blends but reduces their stiffness. PP blends in the low elastomer content region (< 20%) show low values of the Izod impact strength and both, elastomer content and impact strength, are directly proportional to the area under the beta damping peak or its maximum intensity of the elastomer. The morphology is a continuous pattern of segregate elastomeric particles with average particle size in the range of 0.27 mum to 0.39 mum. The average particle size and particle size distribution plotted in log-normal distribution curves, increases slightly with the increase in the elastomer content. The reactor modified PP heterophase has a broader particle size distribution and an average particle size of 0.56 mum, at the lower limit but inside the range for good impact performance, as observed.
  • Growth and optical properties of Cr3+ doped GdAlO3 single crystals Original Articles

    Andreeta, J.P.; Jovanic, B.R.

    Resumo em Inglês:

    High-Temperature Solution crystal growth experiments on Cr3+ doped GdAlO3, are described where the flux and solute stoichiometry was changed for the process optimization to obtain homogeneous and inclusion free larger crystals. Transparent single crystals up to 3.8 cm³ have been grown. The pressure-induced wavelength shift of laser excited fluorescence in some of these crystals was measured up to 115 kbar at room temperature in relation to the R1 shift of ruby. The wavelength shift fluorescence behaviors of these doped crystals, with low Cr3+ concentrations, indicate that this material could be used in producing a new class of pressure sensors.
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