Impact of an Alkaline Solution on the Chemistry, Mineralogy, and Sorption Properties of a Typic Rhodudult Soil

Abstract

The preferred option for disposal of short-lived low and intermediate level radioactive wastes is a near surface disposal facility in which soil is one of the barriers that avoid radionuclide migration outside the controlled area. For construction of that kind of facility, concrete is widely used, and its interaction with water induces its degradation, resulting in a high pH solution. The alkaline solution may affect the near-field environment of radioactive waste repositories, including the soil, promoting mineralogical alterations that result in significant changes in key properties of materials, compromising their performance as safety components. In this study, a sample of a Brazilian Typic Rhodudult soil, previously investigated concerning its performance for Cs sorption, was subjected to interaction with the alkaline solution for 24 h and for 7, 14, and 28 days in order to evaluate the impact on its chemical, mineralogical, and sorption properties. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), atomic absorption spectrometry (AAS), scanning electron microscopy (SEM), and electron microprobe analysis were performed before and after each alteration period. Results indicated dissolution of minerals, such as kaolinite and quartz, associated with incorporation of K and Ca from the alkaline solution, likely resulting in the formation of hydrated calcium silicate phases (CSH), which are expected to be worse sorbents for alkaline elements (e.g., Cs) than the original minerals. The Kd values for Cs in the altered samples also decreased according to the alteration period, demonstrating that alkaline interaction effectively modifies the soil sorption properties for Cs.

repository; alkaline alteration; Cs sorption; CSH phases

INTRODUCTION

A near-surface disposal facility is being designed by the Brazilian Commission for Nuclear Energy (CNEN) to dispose of the low and intermediate level radioactive waste generated in the country. According to this disposal concept, the waste package and other barriers are to isolate the radioactive wastes until they reach natural levels of radioactivity (Tello, 2008). Therefore, the safety of the overall waste disposal system depends on the ability of each individual component to retard radionuclide migration (the form of waste, waste container, engineered barriers, and geosphere) (IAEA, 2001). In a near-surface facility, the host environment is mainly composed of the soil and large amounts of cement, which are used in construction of the structures and facilities that comprise the engineered barrier system. This cement, when hydrated, will generate a high pH plume that may change the near-field properties, including soil properties, in the long term, affecting performance of the cement as a safety component of the repository.

Systematic study of this phenomenon began in the 1990s when the effect of alkaline solutions on the properties of isolated minerals was investigated (Bérubé et al., 1990; Savage et al., 1992). In the years that followed, alkaline alteration was evaluated for different materials comprising a wide range of commercial or natural clays and soils, as well as a combination of minerals, rocks and clay (Ramírez et al., 2002; Savage et al., 2002; Gaucher et al., 2004; Ramírez et al., 2005; Fernández et al., 2006; Savage et al., 2007; Yamaguchi et al., 2007; Rozalén et al., 2008; Fernández et al., 2009; Rozalen et al., 2009; Honty et al., 2010; Moyce et al., 2014). These studies demonstrated that the nature and extension of the modifications caused by the interactions of the minerals with the alkaline solution depend on the chemical/mineralogical composition of the initial solid material, the composition of the alkaline solution, and the alteration conditions, including temperature, period of exposure, and size of the solid sample (Gaucher and Blanc, 2006).

Several studies show that the dominant interaction mechanism of minerals with alkaline solutions is the dissolution of primary aluminosilicates followed by precipitation of secondary phases of hydrated calcium silicates (CSH) (Bérubé et al., 1990; Savage et al., 1992; Hodgkinson and Hughes, 1999; Wieland and Loon, 2003). These CSH phases are formed by a combination of Al and Si dissolved from the sample and Ca from the alkaline solution. However, the complexity of this phenomenon makes it an ongoing point of study in order to clarify the mechanisms of these alterations and to assess their actual influence on the performance of the disposal facilities.

Recently, Calábria (2015) evaluated the cesium (Cs) sorption capacity for different soils from the southeast of Brazil as a measure of the performance of these soils as safety components for the future near-surface repository project. The study found that the soil classified as a Typic Rhodudult (Soil Survey Staff, 2014) had the best results among the soil types evaluated, showing that soils with similar properties are promising for this proposed use. Typic Rhodudult soil exhibited the highest values for maximum sorption capacity, Q (18.4 mg g^-1), and distribution coefficient, Kd (90.5 mL g^-1), as well as elevated cation exchange capacity (CEC), iron content, and clay mineral content. All these parameters are directly correlated with the sorption process (EPA, 1999a). The Cs migration study is particularly relevant because, in Brazil, ¹³⁷Cs is responsible for 45 % of the isotopic inventory of the current nuclear power plants in Brazil, located in Angra dos Reis (Aguiar, 2006). Furthermore, the waste generated in these plants represents 80 % of the low and intermediate waste generated in the country (Tello, 2008).

With the hypothesis that alkaline alteration causes dissolution of primary minerals reducing the soil sorption capacity, this study aimed to investigate the effect of alkaline dissolution on the chemical mineralogical and sorption properties of a Typic Rhodudult soil by examination of the unaltered and altered samples after different periods of contact.

MATERIALS AND METHODS

Soil sampling

A sample of Typic Rhodudult (Soil Survey Staff, 2014), which corresponds to Argissolo Vermelho Eutrófico típico according to the Brazilian System of Soil Classification (Santos et al., 2013), was taken from the municipality of Conselheiro Pena, Minas Gerais, in the southeast of Brazil. This soil type was previously investigated among almost 500 samples of Minas Gerais soils and was chosen as promising for use as a repository host or backfill. This screening was first made by geoprocessing and then by experimental investigation (Calábria, 2015; Calábria et al., 2017). The sampling procedure followed the Soil Sampling Manual for Quality Reference Values in the State of Minas Gerais (Abrahão and Marques, 2013) and consisted of five samples: a central point and four other points surrounding the central one at a distance of 3-5 m in the cardinal directions (N, S, E, and W). The central sampling point was georeferenced by GPS (GPSmap 76CSx, Garmin) and the geographic coordinates are 19^° 07’ 57” S, 41° 34’ 21” W (WGS 84). The surface of the sampling area was previously cleared and a pit of 0.20 m depth and 0.50 m side widths was dug at each point. The samples were collected from the bottom of these pits. The five samples were combined to produce one composite sample, which was air dried and passed through a 20# Tyler 0.841-mm sieve using a vibrating sifter (Mavi-Hude 6.12/M-03-4). The material that was <0.841 mm was crushed in a 0.25 × 0.15 m roll crusher (Denver 1076). Finally, the soil was thoroughly homogenized before taking samples for the alteration process and characterization.

Alteration of the soil sample with alkaline solution

The soil sample was placed in contact with an alkaline solution, simulating pore water derived from a fresh cement barrier of a radioactive waste disposal facility after interaction with water. This simulated solution was prepared from analytical-grade reagents and was composed of 0.11 mol L^-1 NaOH and 0.25 mol L^-1 KOH, and saturated with Ca(OH)₂ (Holgersson and Albinsson, 2002)_. The soil sample and the alkaline solution were mixed in polyethylene flasks in a 1:25 ratio (Bérubé et al., 1990; Ramírez et al., 2002). The flasks were kept under stirring for 24 h and 7, 14, and 28 days in a climatic chamber at 25 °C. At the end of each alteration period, the soil was separated from the solution, centrifuged, and washed with ethanol until the ionic conductivity of the washing solution reached a value between 55 and 40 μS cm^-1. Each flask provided nearly 10 g of altered sample; therefore, to gather the amount necessary to perform all the analyses, we used 10 flasks for each alteration period. The sample investigated for each alteration period was then a composite sample, made by the mixture of each one of these individual flasks.

Analytical characterization

The soil samples were characterized before and after interaction with the alkaline solution as follows.

To provide a general mineralogical characterization, we performed analyses by the X-ray diffraction (XRD) powder method using a Rigaku D-max Ultima Plus, 40 kV and 30 mA, (Cu Kα1 = 1.5405 Å and Cu Kα2 = 1.5443 Å) diffractometer. The 2θ scanning interval was 4° to 80°, the 2θ step radiation was 0.02°, and the scanning speed was 4° (2θ) per min. Phase identification was made by comparison with the ICDD database (International Center for Diffraction Data/Joint Committee on Powder Diffraction Standards).

To perform chemical characterization, the samples were initially analyzed by energy dispersive X-ray spectroscopy (EDX) using a Shimadzu EDX-720 spectrometer for elemental identification. In a second step, quantitative chemical measurement was made by atomic absorption spectrometry (AAS) using an Agilent-Varian AAFS-20 spectrometer. Before performing chemical analysis by AAS, the samples were digested with analytical grade HNO₃ 65 % (v/v) and H₂O₂ 30 % in a Millestone Ehos One microwave oven. The residual fraction was solubilized with concentrated HF, complexed with boric acid, and jointed to the previously digested liquid phase. The chemical composition of the alkaline solution after each alteration period was also determined by EDX and then AAS. Quantitative determinations by AAS were made in triplicate.

Specific surface area was determined by the multiple-point Brunauer-Emmett-Teller (BET) method, using the NOVA 2200 Ver. 6.11 analyzer. Cation exchange capacity (CEC) was determined by the sodium acetate at pH 8.2 (5A2a) method of the Soil Survey Laboratory Methods Manual (USDA, 1996).

To identify possible poorly-ordered newly-formed phases present in small quantities and structurally similar to other already existing phases, Scanning Electron Microscopy (SEM) analyses in combination with EDX and Wavelength dispersive X-ray spectroscopy (WDX) were performed using a scanning electron microscope coupled to a JEOL JSM-6360LV electron microprobe. This technique allowed identification of minor phases and determination of chemical composition at specific points of the sample. Experiments and analyses involving electron microscopy were conducted in the Center of Microscopy at the Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil. To perform these analyses, glass slide mounts were made from the fine earth samples. We screened the whole mount (excluding the edges, to avoid possible defects of preparation) to choose the specific grains to be investigated and recorded.

Sorption batch experiments

The sorption isotherms were determined according to the Variable Soil:Solution Ratio Method (Roy et al., 1992). The procedure consisted of mixing different amounts of the sorbent with 200 mL of solutions containing 100 mg L^-1 of nonradioactive Cs. The soil:solution ratios were 1:10, 1:20, 1:40, 1:60, 1:80, 1:100, 1:150, and 1:200. The CsCl solution was prepared from analytical-grade reagents. The pH of the suspension was adjusted to 5.5 ± 0.1 using 0.01 mol L^-1 NaOH or HCl, and the flasks with the suspensions were kept under stirring at 25 °C for 24 h in a climatic chamber in order to reach the sorption equilibrium. The soil was centrifuged and the supernatant was filter using a 0.45 µm membrane. The concentration of Cs in the solution was determined by atomic emission spectrometry (AES) in an Agilent-Varian AAFS-20 spectrometer. This procedure was performed in duplicate. The linear isotherm model, the simplest model, was fitted to these data using OriginPro 9.2. In this isotherm (Equation 1), the retention of the solute (S) is assumed to be proportional to the solution concentration (C_eq):

S = Kd × C_eq Eq.1

The constant of proportionality, Kd, given by the slope of equation 1, is called the distribution coefficient and has dimensions of mL g^-1.

RESULTS AND DISCUSSION

Mineralogical and chemical modifications

The XRD patterns for the unaltered and altered sample after 28 days are shown in figure 1. The sample is mainly composed of quartz, kaolinite, goethite, and a mica phase, in which we identified muscovite and illite. However, it was not possible to determine each mineral separately, and thus we assumed that the mica phase is a physical mixture of muscovite/illite. Changes in the intensities of the peaks of the X-ray diffraction patterns for the altered sample suggested modification of the mineralogical composition (percentage of each phase) due to the alkaline alteration process. The relevant mineralogical modifications were the decrease in kaolinite and quartz content and the increase in muscovite/illite. However, the increase in the relative intensity of muscovite/illite may not necessarily mean an increase in mineral contents, but only a concentration due to solubilization of the silicates. No new crystalline phases were observed, although this does not mean that they were not formed. It could be that the alteration in the minerals was not high enough to be revealed by this technique or that the degree of crystallinity of the new phases was not sufficiently high to make them detectable by XRD (Bérubé et al., 1990).

Figure 1
X-ray diffractograms of the unaltered sample and sample altered over 28 days with alkaline solution. The highlighted peaks evidence changes in quartz and muscovite/illite content.

The table 1 presents the results of chemical characterization of the Typic Rhodudult soil samples, before and after the alteration process, and a compilation of mineralogical identification by XRD.

Table 1
Characterization of the soil samples and chemical analysis of solutions for each alteration period

	Unaltered	24 h	7 days	14 days	28 days
Physicochemical analysis
CEC (cmolc kg-1)	10.08	13.61	11.32	13.67	12.10
Specific surface area (m2 g-1)	39.96	31.32	32.64	30.89	34.55
Chemical analysis of soil samples
Measured elements
MgO (%)	0.20 + 0.01	0.37 + 0.02	0.26 + 0.01	0.20 + 0.01	0.41 + 0.02
Al2O3 (%)	24.50 + 1.23	24.10 + 1.21	24.11 + 1.21	24.60 + 1.23	23.80 + 1.19
SiO2 (%)	46.70 + 2.34	47.40 + 2.37	47.80 + 2.39	47.40 + 2.37	45.60 + 2.28
K2O (%)	1.74 + 0.09	2.80 + 0.14	2.98 + 0.15	2.99 + 0.15	2.90 + 0.15
CaO (%)	0.36 + 0.02	0.52 + 0.03	0.57 + 0.03	0.58 + 0.03	0.55 + 0.03
Fe2O3 (%)	9.19 + 0.46	9.69 + 0.48	9.42 + 0.47	9.82 + 0.47	9.28 + 0.46
Na2O (%)	< 1.00	< 1.00	< 1.00	< 1.00	< 1.00
TiO2 (%)	1.13 + 0.06	1.00 + 0.05	1.00 + 0.05	0.98 + 0.05	0.90 + 0.05
SiO2 (mg L-1)	10.00 + 0.05	40.00 + 2.00	2.30 + 0.30	6.00 + 0.30	10.00 + 0.50
K2O (mg L-1)	10,000 + 500	9,005 + 450	4,500 + 225	6,000 + 300	7,400 + 370
CaO (mg L-1)	90.00 + 4.50	18.2 + 0.91	14.0 + 0.70	6.50 + 0.33	2.20 + 0.11
	Mineral identified*
Major (<50 %)	Kaolinite, Quartz	Kaolinite, Muscovite/Illite	Kaolinite, Quartz	Kaolinite, Quartz	Kaolinite, Quartz, Muscovite/Illite
Minor (<15 %)	Muscovite, Illite, Goethite	Quartz, Goethite	Muscovite/Illite, Goethite	Muscovite/Illite, Goethite	Goethite
Minority (<3 %)	Microcline, Albite	Microcline, Albite	Microcline, Albite	Microcline, Albite	-
Kaolinite Al2Si2O5(OH)4; Quartz: SiO2; Muscovite: KAl2Si3,AlO10(OH)2; Illite:(K,H3O)Al2Si3AlO10(OH)2; Goethite: FeO(OH); Microcline: KAlSi3O8; Albite: (Na,Ca)(Si,Al)4O18.

• CEC was determined by the sodium acetate at pH 8.2 (5A2a) method of the Soil Survey Laboratory Methods Manual. Specific surface area was determined by multiple-point Brunauer-Emmett-Teller (BET) method. ^* The minerals in the same line are presented in ascending order of content.

Results of chemical analysis of the soil samples (Table 1), show that, considering the respective errors, only K₂O, CaO, and MgO contents changed due to the alteration. The increase in K₂O and CaO contents is clearly seen comparing unaltered and altered samples, but no conclusion can be made about the altered samples among themselves. These results indicate that these elements were incorporated into the soil from the alkaline solution. The sample becomes more potassic and calcic, given the greater affinity of these cations for clay phases and the presence of high K and Ca concentrations in the alkaline fluid. Clay alterations generally begin with a modification of the adsorbed cation population (Ramírez et al., 2002, 2005) and then continue with an illitization (Bauer and Berger, 1998). Illite formation could be one of the hypothesis to explain potassium incorporation into the soil, but since we observed a decrease in cesium sorption, as discussed below, simple K fixation by soil charges is more likely, or the incorporation of K in the new CSH phases. Regarding Mg, an initial increase in MgO content after 24 h was followed by a progressive decrease after 7 and 14 days, and a final increase after 28 days. Precipitation of low-solubility magnesium phases can cause desorption of the Mg fixed on the clays through the low of mass action (Gaucher et al., 2004).

The dissolution of primary minerals, like quartz and mica, observed by XRD, releases elements that can combine with the elements from the alkaline solution and favor precipitation of certain phases, e.g., CSH. The increase in CaO content in the altered soil may show formation of the CSH phase, although we did not identify the dissolution of primary aluminosilicates from the variation of the Al₂O₃ and SiO₂ contents in the soil samples (their contents did not vary). To elucidate the dynamics of dissolution/incorporation of elements, the concentration of K, Ca, and Si in the alkaline solution was evaluated for each alteration period (Figure 2). These results show that the concentration of Si first increases, probably as a consequence of dissolution of the primary silicates, e.g., quartz. This step is followed by a decrease in the SiO₂ concentration, which remains almost the same throughout the alteration. It is possible that silica, once dissolved, is incorporated into new phases, and thus its content in the soil sample does not vary during the alteration, but the concentration in the alkaline solution varies. Thus, in consequence of the precipitation of secondary mineral phases due to the combination of Si with Ca in solution, the solution progressively loses Ca but maintains an almost constant Si concentration. Concerning K content, the loss of K from the solution corroborates its incorporation into the solid phase. Bérubé et al. (1990) and Savage et al. (1992), in a study on the interaction between minerals and an alkaline solution, also observed a progressive loss of calcium from alkaline solutions and a gain in Si as an initial step in the growth of CSH phases.

Figure 2
Silicon, K, and Ca concentrations in the alteration solution over time. The K concentrations were multiplied by 10-2 in order to facilitate data visualization.

The figure 3a shows the results of electron microprobe analysis for the unaltered Typic Rhodudult sample, and the figure 3b shows the results for the sample after 28 days of interaction with the alkaline solution. These analyses were performed to give an indication of the formation of the CSH phases, since these phases are often too finely grained and mixed with other phases to have their composition precisely determined by conventional XRD or EDX (Bérubé et al., 1990; Savage et al., 1992; Bateman et al., 1999; Hodgkinson and Hughes, 1999). The EDX analyses, which were made on each one of the surfaces indicated, are presented in figures 3c to 3h. They provided information that allowed the mineralogical composition to be inferred. The figures 3c and 3d are representative of iron oxide compositions (identified as goethite, due to morphology) and quartz, respectively. The Al:Si relationships and additional elementary information (presence or absence of some elements, such as Ca and Na) allow us to identify a clay phase (kaolinite or halloysite) (Figure 3e), mica, probably muscovite (Figure 3f), feldspar 1, probably microcline (Figure 3g), and feldspar 2, probably plagioclase (Figure 3h). All these phases had already been indicated by XRD. For the altered sample, scanning identified all the phases that were originally present, except for goethite, although some significant changes were visually observed. The quartz structures, abundant in the unaltered sample, practically disappear after 28 days of interaction, and the grains were of much smaller dimensions than those in the original sample, evidencing quartz dissolution. Another significant modification was the increase in acicular structures, which were identified as corresponding to clay (kaolinite or halloysite) and mica.

Figure 3
Microprobe scanning by backscattered electron emission for the unaltered Typic Rhodudult (a) and after 28 days of interaction with an alkaline solution (b).The EDX results on the goethite surface (c); EDX results on the quartz surface (d); results on the mica (muscovite?) surface (e); results on the clay (kaolinite?) surface (f); results on the feldspar 1 (microcline?) surface (g); and results on the feldspar 2 (albite?) surface (h). The images are representative of the whole sample.

Bérubé et al. (1990) and Savage et al. (1992) observed by electron microscopy analysis that the quartz was covered with secondary precipitates, mainly calcium silicate hydrate (CSH) of up to 30 µm, due to the alkaline interaction. However, in this study, it was not possible to identify this coating in the microscopy images for the altered sample. As the non-identification of coating on minerals may be related to the formation of small quantities of the new phases, probably due to the short alteration period and low temperature used during the alteration process, we carried out Wavelength Dispersive X-ray Spectroscopy (WDX) analysis on the mineral surfaces. Given that Ca identification on the quartz surface of the altered sample could indicate precipitation of calcium silicate hydrates on this mineral grain, Ca determination was an indirect measure to identify formation of the CSH phase. We analyzed the quartz and clay surfaces of the unaltered sample and the sample altered after 28 days. Calcium and K were identified in the clay phase, but no Ca deposition was found in the quartz phase. Since we identified Ca on the clay surface of both the unaltered and altered sample, the results of this analysis were not conclusive.

Impact of alkaline alteration on sorption of cesium

Because retention is a very important aspect in a repository, several studies related to estimation of the Kd values for common isotopes present in radioactive wastes are found (EPA, 1999a,b; Sheppard, 2003; Wieland and Loon, 2003; EPA, 2004; Aldaba et al., 2010), although there are very few studies related to the impact of alkaline interaction on this parameter (Euratom, 2005).

The table 2 shows the equations and parameters obtained for linear isotherms fitted to the sorption data from batch experiments. The Kd values decreased from 90.54 mL g^-1 in the unaltered sample to 42.53 mL g^-1 for the altered sample over 24 h. This decrease continues for the other altered samples, reaching 30.80 mg L^-1 in 28 days, although a slight increase was observed after 14 days of alteration. These data indicate that interaction with the alkaline solution negatively affected the sorption characteristics of the soil.

Table 2
Linear isotherm adjustments for Kd (Cs) determination before and after each interaction period (24 h and 7, 14, and 28 days) with the alkaline solution. Experimental conditions for batch experiments: equilibration period = 24 hours, T = 25 oC, pH = 5.5 + 0.1

Sample	Equation(1)	R2	Kd
			L g-1	mL g-1
Unaltered	S= 0.0905 Ceq	0.9720	0.0905	90.54
24 h	S= 0.0425 Ceq	0.9465	0.0425	42.53
7 days	S= 0.0304 Ceq	0.9576	0.0304	30.45
14 days	S= 0.0384 Ceq	0.9479	0.0384	38.40
28 days	S= 0.0308 Ceq	0.8907	0.0308	30.80

• ⁽¹⁾ S = Kd × C_eq. S = mass fraction of sorbed solute per unit of sorbent mass; C_eq = solution concentration; Kd = distribution coefficient.

Cesium adsorption, in general, occurs by cation exchange, except when mica-like minerals (e.g. illite) are present (EPA, 1999a). Since the observed mineralogical changes (kaolinite and quartz dissolution, or mica phase concentration) are not expected to lead to a decrease in Cs retention capacity, the reasons likely to explain the reduction in sorption in the altered samples are the saturation of exchangeable sites with K⁺ and the possible formation of hydrated calcium silicate (CSH) phases. Large hydrated cation such as Ca²⁺ and Mg²⁺ are considered “readily exchangeable”, but ions like K⁺ that adsorbed specifically are not; they compete with cesium for the available adsorption sites (Sposito, 1989; McBride, 1994).The CSH gels have high surface areas, making them good sorbents for many lanthanides and actinides (e.g., U, Th, and I); however, they are not good sorbents for alkaline and alkaline earth elements. Specifically for Cs, sorption is expected to be low, since high concentrations of Na⁺ and K⁺ in the CSH phases apparently have a strong competitive effect on Cs⁺ sorption (Wieland and Loon, 2003). Therefore, the incorporation of potassium in the solid phase and the formation of CSH phases should promote a decrease in Cs sorption.

Cesium may also adsorb to iron oxides or edge functional ionized groups. However, these groups do not fix Cs⁺; instead, they complex cesium to the ionized sites (EPA, 1999a). It should be noted that the silanol and aluminol edge functional groups of the clay will ionize in an alkaline medium and may be involved in adsorption reactions (Gaucher et al., 2004).

CONCLUSIONS

The chemical and mineralogical modifications of greatest impact identified as a result of alkaline interaction were dissolution of primary silicates (quartz) and kaolinite and an increase in the Ca and K contents in the altered soil samples. Joint assessment of the XRD, microprobe, and chemical results provided enough evidence for the formation of the CSH phases, though none of the analyses were able to identify them directly. Likewise, the decrease in the Kd values for Cs corroborates formation of the CSH phase. This decrease demonstrates that the sorption characteristics of Typic Rhodudult undergo reduction when it interacts with the alkaline solution.

Since ¹³⁷Cs is one of the most relevant radionuclides that compose the isotopic inventory of Brazilian radioactive wastes of low and intermediate level, the capability of facilities for retarding Cs migration is crucial. From the results, we may conclude that alkaline alteration is a phenomenon that must be considered if intends to use materials similar to the soil studied here as repository barriers.

ACKNOWLEDGMENTS

The authors would like to thank the FAPEMIG (Fundação de Amparo à Pesquisa do Estado de Minas Gerais) and the CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico) for funding this project.

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Publication Dates

• Publication in this collection
  2017

History

• Received
  2 Jan 2017
• Accepted
  30 May 2017