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Calcium and magnesium release by porous ceramic cups used to extract soil solution

The use of porous cups to extract soil solution is interesting because it is a non destructive method. However, there are some uncertainties regarding the possible release of ions from the cups that would contaminate the extracted solution. An experiment was carried out at the College of Agricultural Sciences/UNESP, Botucatu, State of São Paulo (Brazil) to evaluate the Ca and Mg release by ceramic porous cups. Two tests were performed, consisting of four treatments: T1 - washing the cups with distilled water, forcing its passage through the cups with a vacuum pump; T2 - washing the cups with 0.01 mol L-1 HCl, forcing its passage through the cups with a vacuum pump; T3 - washing cups with water, without vacuum; e T4 - washing the cups with 0.01 N HCl, without vacuum. In the second test, the cups treated with 0.01 mol L-1 HCl in the first test were washed again with distilled water and left in purified (distilled and deionized) water taken for 45 minutes. After this, the cups were immersed in distilled water. Sub-samples were after 0, 0.5, 1.0, 2.0, 4.0, and 24.0 h to determine pH, Ca and Mg contents in solution. Each treatment of both tests was carried out in four replicates. The pH values and Ca and Mg release from the cups to solution was not significant when they were washed with 0.01 mol L-1 HCl employing vacuum and distilled water followed by immersion in purified water for 4 h.

solution contamination; ion release; soil chemistry


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