Gold deposits in poly-deformed metasedimentary rocks : a case study of the C 1-Santaluz gold deposit , Itapicuru Greenstone Belt , Northeast of Brazil

Manuscript ID: 20170124. Received on: 09/23/2016. Approved on: 08/27/2018. ABSTRACT: The C1-Santaluz gold deposit is located in the Itapicuru greenstone belt in Bahia State, Brazil. Metavolcanic and metasedimentary rocks dominate at the base and top, respectively. The ore minerals related to the auriferous mineralization are pyrite, arsenopyrite, sphalerite, chalcopyrite and stibnite. Arsenopyrite is related to, and associated with the presence of gold in quartz veins, a feature which is detected by scanning electron microscope analyses. The deposit is structurally complex, with tree deformational phases being recognized: Dn-1, Dn, and Dn+1. Phases Dn-1 and Dn have a direct relation to the mineralization, and mineralized quartz veins are parallel to the Sn foliation (S0 //Sn-1 //Sn ). The intersection between the S0//Sn-1 bedding and the Sn foliation generates an intersection lineation parallel to the Dn fold axis, plunging to the NW, which has favored an increase in the volume of mineralized bodies.


INTRODUCTION
Structural controls play a major role in gold deposits, and understanding the different structures and their relationships with one another is fundamental to the interpretation of the gold system.
According to Groves et al. (2003), there are important factors regarding orogenic gold deposits (definition after Groves et al. 1998), such as the source of ore fluids and metals, tectonic setting, age of mineralization of some provinces, features of hydrothermal alteration and depositional mechanisms specific to gold.These factors are not always well known during the exploration phase and may be compared to those from important world-class deposits already documented, leading to a better understanding of their characteristics.Assessing the structural factors that contribute to gold deposition can aid gold exploration.
The genesis of most orogenic gold deposits around the world is closely related to the processes of metamorphism and deformation, with orebodies commonly formed in low metamorphic grade (Large et al. 2011).The main orogenic gold deposits are strongly associated with deformed metamorphic terranes, and gold is commonly related to greenschist facies rocks (Groves et al. 1998, 2000, 2003, Hagemann & Cassidy 2000, Goldfarb et al. 2005, Goldfarb & Groves, 2015).
The Rio Itapicuru greenstone belt (RIGB) is an important geological entity located at the northeastern region of Brazil, in Bahia State, and hosts two main auriferous deposits, Fazenda Brasileiro and C1-Santaluz (Fig. 1).
The Fazenda Brasileiro gold deposit is located in the meridional part of the RIGB, and has been the subject of several studies (Kishida 1979, Marimom et al. 1986, Xavier 1987, Reinhardt 1988, Reinhardt & Davison 1989, Teixeira et al. 1990, Mello et al. 1996, Alves da Silva et al. 1998, Vieira et al. 1998, Silva et al. 2001, Pimentel & Silva 2003).The C1-Santaluz deposit is located in the central portion of the belt (Fig. 1) and is the focus of the present study.As a structurally controlled gold deposit, C1-Santaluz (Fig. 2) has features that correspond to an orogenic auriferous mineralization, similar to those described by Colvine et al. (1984), Robert (1996), Goldfarb et al. (2001), such as poly-deformed host rocks, greenschist facies assemblage (sulfide-carbonate-chlorite-sericite), low sulfide volume and strong degree of structural control.
The RIGB auriferous mineralization results from hydrothermal fluid influx in magnetite and carbonaceous schists, carbonate-quartz veins, gabbros and breccias (see, for example, Kishida 1979).Ruggiero (2008) points out the presence of gold in the RIGB in association with small-to medium-scale shear zones, typical of orogenic lode gold deposits.Vasconcelos and Becker (1992) and Mello et al. (2006) constrained the age of the Fazenda Brasileiro mineralization to 2.083-2.031Ga.
Fazenda Brasileiro deposit mineralization was formed under temperature conditions of 250-400ºC, and the orebodies were developed primarily as stratabound with free gold in quartz veins emerging at a later stage (Teixeira 1984).Reinhardt (1988) points out that gold also occurs as ore shoots (rods) marked by quartz veins orientated along the stretching lineation parallel to an intersection lineation.Furthermore, breccia zones tend to be enriched in gold with metal grades strictly related to the presence of arsenopyrite and pyrite.
The C1-Santaluz gold deposit is hydrothermally associated with shear zones and folds, in a poly-deformed scenario.
RIBG: Rio Itapicuru greenstone belt.Therefore, understanding the structural framework of the study area is a key task because it can help guide future prospective work, not only in the study area but in other structurally complex localities.

Geochronological Ages
The main goal of this paper is to characterize the structural evolution of the C1-Santaluz deposit.To attain this objective, geological and structural mapping of the area was undertaken, including description and interpretation of deformational features, both at macro-and microscopic scales.The paper also discusses stratigraphic and petrographic features, as well as types of gold occurrences, including the sulfide minerals present in quartz and carbonate-quartz veins.Mineralogical studies are aided by analytical XRD, SEM and BSE data.

REGIONAL GEOLOGICAL SETTING
São Francisco Craton (Fig. 1) is located in northeast central Brazil (Almeida 1977, Alkmim 2004).Together with the African plate, São Francisco Craton forms San Francisco-Congo Craton (Almeida et al. 1976;Alkmim 2004), which was part of the western Gondwana prior to the formation of the Atlantic Ocean in the Cretaceous.At the end of the Neoproterozoic, this supercontinent comprised a group of tectonic plates that were coalesced by successive diachronic collisions (Alkmim 2004).According to Almeida (1977) and Almeida et al. (1981), São Francisco Craton is bordered by Neoproterozoic belts, and northern exposures preserve features of Paleoproterozoic orogens, divided into four main lithotectonic compartments, namely, Gavião, Serrinha, Jequié Blocks, and the Itabuna-Salvador-Curaçá Belt (Barbosa & Sabaté 2002, 2004).
Serrinha Block is located in the northeastern portion of the Craton and forms an oval structure of approximately 21,000 km 2 .It is composed of migmatized orthogneisses superposed by sequences of greenschist-facies supracrustal rocks intruded by granites (Gaál et al. 1987, Alves da Silva 1994).The RIGB belongs to Serrinha Block, and is 100-km long (N-S) and 30-km wide (E-W) (Chauvet et al. 1997, Alves da Silva 1998).It is a metavolcano-sedimentary sequence intruded by syn-to post-tectonic granites (Silva 1992).
The supracrustal rocks of the RIGB are approximately 9.5-km wide covering an area of 7,500 km 2 and are composed of mafic volcanic rocks, at the base, and felsic/intermediate volcanic and metasedimentary rocks at the top (Kishida 1979, Kishida & Riccio 1980, Silva 1992).The whole sequence is characterized by low-grade metamorphism (Kishida 1979).
They have a preferred N-S orientation in the central and northern parts, where geological contacts are typically parallel to the main foliation.In the southern part, the preferred orientation is E-W (Silva 1992) (Fig. 1).
According to Kishida (1979) and Silva (1992), the RIGB supracrustal rocks are Paleoproterozoic and may reach up to 9.5 km in thickness.From bottom to top, they are divided into three domains and intrusive rocks are commonly present (Kishida 1979;Silva 1983;Silva et al. 2001, Barbosa andSabaté 2004): 1. a volcanic mafic unit, composed of metamorphosed tholeiitic basalts and mafic tuffs with associated iron formations, cherts and graphitic phyllites; 2. a volcanic intermediate to felsic unit, consisting of felsic rocks of andesitic to dacitic, calc-alkaline composition, with aphanitic, porphyritic, variolitic and pyroclastic texture, also exemplified by tuff and agglomerate lapillis; 3. a sedimentary unit, characterized by conglomerates, phyllites, sandstones and siltstones, which may be associated with banded iron formations, marbles, gondites and cherts.
The basal volcanic mafic unit is aged 2,209 ± 60 Ma (Pb-Pb whole rock method) and a Sm-Nd TDM age (whole-rock) of 2.2 Ga (Silva 1992, Barbosa & Sabaté 2004).Oliveira et al. (2010) presented U-Pb SHRIMP ages in zircons of 2,145 ± 8 Ma and 2,142 ± 6 Ma for tholeiitic basalts of the sequence.Silva (1992) presented ages of 2,080 ± 90 Ma (Rb-Sr), 2,109 ± 80 Ma (Pb-Pb) and 2.1 Ga (Sm-Nd) for the volcanic intermediate to felsic unit.Grisólia (2010) also states that the metasedimentary rocks (in the sedimentary unit) of the RIGB are Paleoproterozoic, with deposition ages between 2,110-2,120 Ma for Sm-Nd isotopes.Grisólia (2010) also adds that these rocks originated either from the erosion of the RIGB itself, or from other sources with similar ages.
Several intrusive bodies (dikes and sills) occur in the RIGB and are represented by diorite and gabbro of tholeiitic composition (Kishida 1979, Silva 1992).Granitic bodies have ellipsoidal shapes and may be grouped into two main types: granite-gneiss domes, and isotropic bodies that intrude the supracrustal sequence (Kishida 1979;Rocha Neto 1994).According to Silva (1992), these bodies may be syn-or post-tectonic, and are related to the first deformation phase of the structural setting.
Syn-tectonic granitic intrusions are associated with the drift phase of the Rio Itapicuru volcano-sedimentary basin and are represented by granitoids such as Barrocas, Teofilândia and Nordestina (Fig. 1), which have a calcium-alkaline nature and Paleoproteozoic ages (Rios et al. 2003).Post-tectonic granitoids intruding into the RIGB rocks are alkaline and represented by Ambrósio and Pedra Vermelha (Rios et al. 2003).They have an U-Pb SHRIMP (xenotime) age of 2,080 ± 2 Ma (Mello et al. 2006) and an U-Pb isotope dilution (zircon) age of 2,080 ± 8 Ma (Rios et al. 2005), respectively.A summary of ages presented in the literature is shown in Figure 2. Kishida (1979) and Silva (1992) indicate that ultramafic bodies are composed of carbonate-rich, serpentinized peridotites.They have an elongated shape, which is displayed parallel to the regional foliation.Kimberlite intrusions are also documented in the RIGB.The main body occurs at the Nordestina batholith, as an elongated intrusion with a N30W direction with an age (U-Pb perovskite) of 642 ± 6 Ma (Donatti Filho et al. 2012).Silva (1992) proposes a back-arc basin type evolutive model for the RIGB.Kishida (1979) interprets the RIGB metasedimentary rocks from the top of the sequence as volcanoclastic.

Gold mineralization at the C1-Santaluz deposit
C1-Santaluz is the main gold deposit in the central part of the RIGB, presently being mined.Formerly known as Fazenda Maria Preta, the mine was explored by Vale S.A. (former Companhia Vale do Rio Doce) from the early 1980's until the 1990's, when it was passed on to Companhia Baiana de Pesquisa Mineral (CBPM).It was later decommissioned, and, in 2003, Yamana Gold Inc. bought the property and started an exploration program, which continued after mining began in 2008.In 2013, the mine was decommissioned due to operational problems.In 2015, Brio Gold Inc., the subsidiary of Yamana Gold Inc., was created and became the exploration and mining group at the C1-Santaluz deposit.
The extraction ranges from low-to -high gold grades, with proven and probable mineral reserves of 1.2 million ounces of gold, which corresponds to 26.7 million tonnes at 1.42 g/t (at the end of 2016).It also has measured and indicated resources of 780,000 ounces at 1.95 g/t Au, as well as 395,000 ounces at 2.07 g/t Au of inferred resources.The forecast scenario is for an annual production of 114,000 ounces of gold (after decommission, in 2018), with a recovery rate of 84% (Brio Gold Inc., 2017).
Mineralization in C1-Santaluz is hosted at the contact between an intrusive body of intermediate composition and brecciated metasedimentary rocks, with veins, quartz veinlets, and quartz-veined stockwork zones, typically with sulfide minerals.The auriferous mineralization in quartz and quartz-carbonate veins is associated with ductile N-S shear zones, all hosted in a carbonaceous phyllite (Xavier 1987, Carvalho 1991).
The mineralized veins have a N40E preferred orientation; according to Alves da Silva et al. (1998), veins are embedded in a ductile-brittle shear zone that follows the main contact between the ore and the hanging wall.At depth, quartz veins occur in brecciated carbonaceous phyllite, and are typically associated with lenses of brecciated metadacite.These lenses may be mineralized and correspond to 10% of the ore deposit (Alves da Silva et al. 1998).Coelho and Silva (1998) describe hydrothermal alteration dominated by silicification, and enrichment of pyrite and albite related to the auriferous C1-Santaluz deposit, normally appearing in quartzose stockwork structures.

METHODS
This work was carried out based on field work, sample descriptions, drill core logging, as well as laboratory analyses, such as petrographic, microstructural, scanning electron microscope and X-ray diffraction analyses with the purpose of better describing the geology of the C1-Santaluz deposit.
A detailed map of the C1-Santaluz deposit is presented (Fig. 3) with the support of descriptions by the Yamana Gold Inc.'s drill holes, and results from the work by Assis (2016).A total of 34 thin sections were described identifying minerals and microstructures.Four samples were analyzed by Scanning Electron Microscopy (SEM) at the Department of Petrology and Metalogeny, State University of São Paulo.Analyses were carried out on a JOEL JSM6010LA instrument, equipped with backscattered (BSE), secondary electrons and Energy Dispersive Spectroscopy (EDS) detectors.Selected samples correspond to mineralized schists from the C1-Santaluz deposit.Analyses were performed to identify possible accessory minerals and gold occurrences in the study area.
X-Ray Diffraction (XRD) analyses were conducted at the Department of Petrology and Metallogeny, State University of São Paulo, using the PANalytical EMPYREAN diffractometer with radiation CuKα1 (WL = 1 54056 Å) and Ni filter.Analyses were carried out on four samples with carbonaceous material, not identifiable under the petrographic microscope.These rocks were classified by the author as carbonaceous phyllite and breccia.Analyses were carried out to identify the chemical structure of the carbonaceous materials.
The metandesite is only observed in drill holes of Yamana Gold, and is not exposed in the study area.A schematic, simplified lithotectonic column of the C1-Santaluz deposit is shown in Figure 4.

Metavolcanic Rocks Domain
The metavolcanic rocks domain occurs at the central-eastern to eastern part of the study area (Fig. 3).It is represented by metadacite lenses striking N-S-to NE-SW (Fig. 5).
At the southern part of the C1-Santaluz deposit, the metadacite is mineralized with gold and normally embedded within metasubvolcanic and metasedimentary rocks.In the surrounding area, metandesite bodies are recognized, typically containing feldspar phenocrysts.

Metasedimentary Domain
The metasedimentary domain consists of chlorite-sericite-quartz schist, carbonaceous phyllite and carbonaceous breccia (Fig. 5).Rocks of this domain have a well marked foliation that is commonly folded.Outcrops are highly weathered.
The chlorite-sericite-quartz schist crops out in the central-western portion of the study area, with thicknesses varying from 10 to 120 m.The carbonaceous phyllite is up to 80 m thick, however where inserted in the domains of metadiorite and metadacite it may occur as lenticular bodies up to 20 m in thickness.
The carbonaceous phyllite sits below the metadiorite body, and has an intrusive contact relationship with this metasubvolcanic domain.A breccia with abundant quartz veinlets is situated between these two domains.In the present work, the breccia layer is classified as a separate unit, named carbonaceous breccia, as it hosts gold mineralization of the studied deposit.It occurs in the central part of the study area (Fig. 3) where it is in contact with the metadiorite; in the southern part, it is in contact with the metadacite.It has a thickness of up to 20 m and covers about 10% of the study area.In some portions, both at the macro-and microscopic scales, the matrix still preserves the main foliation and has the same preferential orientation as the carbonaceous phyllite schistosity.

Mineralized Quartz Veins of the Metasedimentary Domain
Mineralized quartz veins are contained in the carbonaceous breccia.Quartz in veins is typically white, milky to translucent.Veins are up to 60 cm thick, generally oriented parallel to the top of the metadiorite contact, and to the main foliation of the host rock.Discordant veins are also common, but are typically thinner.They are mainly perpendicular to concordant veins, and generally fill fractures (Fig. 6).Quartz veins and veinlets are associated with carbonate (ankerite identified in the SEM analysis), albite, and sulfide minerals, represented by fine-grained anhedral-euhedral aggregates of pyrite, and finegrained anhedral-subhedral grains of arsenopyrite.Under the EDS/SEM, chalcopyrite, sphalerite and stibnite are identified in quartz veins.These opaque minerals are directly related to the auriferous mineralization at the C1-Santaluz deposit, characterizing its hydrothermal alteration.

SEM / EDS analyses
The SEM analyses were carried out to identify accessory minerals and investigate textural relationships.The study emphasizes opaque minerals since gold mineralization in the C1-Santaluz deposit is directly related to hydrothermal alteration richly represented by sulfide minerals.The lithological units analyzed are carbonaceous phyllite and breccia, and also quartz veins hosted in carbonaceous breccia.
Also, the data indicate that, in general, the matrix of the carbonaceous phyllite and breccia is composed of sericite/ muscovite, quartz, chlorite and carbonaceous material (Fig. 9).

X-Ray Diffraction Analyses (XRD)
Analyses by XRD were carried out in samples of carbonaceous phyllites and breccias.Out of the four samples analyzed, three contain amorphous carbonaceous material and one shows the presence of graphite (Fig. 9).The graphite-bearing sample is located to the east of the mineralized body at the C1-Santaluz deposit, far from the shear zone in the central part of the study area.

Metasubvolcanic Intrusive Rocks Domain
In the C1-Santaluz deposit, the metasubvolcanic bodies are always in contact with gold mineralization.Exceptions are lenses and apophyses of metadiorite, which occur in the northeastern part of the area (Fig. 3).The basal contact of these bodies with the carbonaceous breccia, as shown in Figure 3, is where the mineralized zone of the pit is located (auriferous mineralization of quartz veins).
Metadiorite is abundant in the C1-Santaluz deposit, covering about 35% of the study area.The innermost portion of the green-gray, massive metadiorite body has a granular to incipient schistose texture, and is coarse to medium grained (Fig. 5).A well marked foliation may be present at its contact with other domains.The basal contact with the carbonaceous breccia usually features sheared and/or fractured textures.The main foliation is strong in the contact zone, and has high dip angles.However, in some places, this contact truncates the main foliation of the host rock.
The metadiorite covers the western, northwestern portion of the area and has a thickness of up to 350 m (Fig. 3).In the eastern part of the area it forms lenses or apophyses of up to 20 m thick, commonly with a N-S or NW-SE strike.

Structural geology
Considering the geometric aspects and superposition criteria, the analysis of tectonic structures indicates the presence of three deformational phases, classified as D n-1 , D n , and D n+1 .The main structure in the area is the S n foliation, an axial planar foliation of D n folds that fold the compositional banding S 0 .The D n folds have axis plunging to the NW.In the metasedimentary domain, S 0 is marked by alternating layers with bands composed of quartz and sericite and bands composed of carbonaceous material.In some cases, such as in microliths of the S n crenulation cleavage, a foliation parallel to S 0 is noted; this has been interpreted as S n-1 , which pre-dates S n , from the D n-1 deformational phase.
The D n+1 phase is characterized by the folding of the S n foliation and older structures, locally generating an axial planar foliation with a NW-SE orientation.Only the S n foliation and structures associated with subsequent phases are present in the metasubvolcanic bodies.The metavolcanic domain shows structural features of the D n-1 , D n and D n+1 phases.Likewise, the metasedimentary domain has structures that belong to deformation phases D n-1 , D n , and D n+1 .Gold deposits in poly-deformed metasedimentary rocks: a case study of the C1-Santaluz gold deposit

D n-1 Deformation Phase
The D n-1 phase is marked by a foliation (schistosity) that is parallel to the rocks compositional banding S 0 .It is better observed in the hinge zones of the D n folds, where this primary structure has not been transposed by the penetrative schistosity of the D n phase.Also, the D n-1 deformational phase is marked by abundant sericite in the rock matrix, which is present in phases D n and D n+1 .
In the eastern part of the study area, the metasedimentary domain has a NW-SE strike, differing from the north, central and southeastern parts, where it is oriented N-S (Fig. 10).The mineralized metadiorite/carbonaceous breccia contact also has a N-S strike in the northern and southern areas, while in the central of the open pit it is oriented E-W.
Where the lithological contacts have a NW-SE strike in the east, they show an almost perpendicular relationship (truncation) with the metadiorite/carbonaceous breccia contact.In the eastern portion, the chlorite-sericite-quartz schist unit appears as a repeated layer (Fig. 10).

D n Deformation Phase
The D n deformation is the main evident phase in the study area.It is mainly defined by a S n foliation, represented   by a schistosity or crenulation cleavage (Fig. 11), depending on the rock type and the scale of observation.
In carbonaceous breccias, the S 0 compositional layering is parallel to the S n-1 foliation.Where folded (isoclinal folds), it forms the S n schistosity (axial planar foliation).Moreover, quartz veins and veinlets are embedded in the compositional banding being deformed by the D n deformation phase.
The S n foliation has a N-S to NNW-SSE strike, dipping to the west and southwest, respectively.The attitude that reflects the general pattern of the study area is 266/50 (Fig. 11).
The intersection between S n and the compositional banding S 0 , parallel to the S n-1 foliation, has created an intersection lineation (L in ) on the S n surface.This structure plunges to the NW (main attitude of 330/21, Fig. 11).The D n folds  have an axis plunging to the NW (335/21, Fig. 11) and SW, subordinately.The intersection lineation is parallel-subparallel to the D n fold axis.
The contact between the metadiorite and the carbonaceous breccia has a N-S strike in the northern part, but displays an E-W strike in the south-central area.This structure delineates an overturned synform (both flanks dipping to the NW) with an axis plunging to the NW (Fig. 11).While the contact (S 0 ) is oriented E-W, the S n foliation is oriented N-S to NNW-SSE (the axial plane of this fold).

D n+1 Deformation Phase
The D n+1 phase is represented by folds and, locally, the crenulation cleavage S n+1 .The distribution of the structures associated with this deformation phase is not homogeneous throughout the area.The attitude of the S n+1 foliation varies along the area and only a few measurements could be made in the field.The S n+1 foliation has a NE-SW strike dipping to the NW and averaging 325/38 (Fig. 12).Also, the range of attitudes seems to indicate a subsequent deformational phase, in which the S n+1 foliation is folded.During D n+1 , sulfide minerals, mainly pyrite, appear to be embedded in the compositional banding S 0 ; where S 0 is folded, opaque minerals typically accompany this structure.

Metamorphism
The mineral assemblages in the C1-Santaluz rocks, with biotite, chlorite and muscovite, indicate a regional progressive metamorphism typical of the low greenschist facies, in the chlorite to the biotite zones (Fig. 13) (Barrow 1893;Tilley 1925).Although most of the chlorite is in equilibrium with biotite and muscovite, part of it may be product of later alteration.Actinolite was not identified in any of the studied rocks.The mineral assemblage described above, occurs in all studied lithotypes, as chlorite-sericite-quartz schist; carbonaceous phyllite; carbonaceous breccia, metandesite, metadacite and metadiorite.
Textures such as recrystallization of quartz grains in both metavolcanic and metasedimentary lithostratigraphic domains and saussuritization of plagioclase are also present.The recrystallization of the quartz crystals is displayed by subgrain rotation, which indicates lower temperature environment, with a maximum temperature value of 400ºC (Eskola 1920, 1939, Miyashiro 1961, 1973, Turner 1981).

Lithological and mineralogical aspects
Geological mapping at the C1-Santaluz deposit reveals a complex stratigraphic sequence.It is difficult to separate the sub-units of the Rio Itapicuru greenstone belt because of the common alternation between lenses and apophyses of each domain into one another (e.g., metavolcanic lenses present in the metasedimentary domain; chlorite-sericite-quartz schist layers inserted into the metavolcanic domain).This is why lithotypes are classified into domains.Moreover, the structural features of the deposit have an important role in the structural control of the gold mineralization (Figs. 10 and 11).
Gold mineralization is hosted in carbonaceous breccia, which is interpreted as a lithotectonic unit generated by the intrusion of the metadiorite body (metasubvolcanic intrusive) and/or metadacite unit (metavolcanic rocks domain; Fig. 5) in this carbonaceous rock.The contact of these two lithological domains is abrupt, and interpreted as a brittle/ductile shear zone, with a dip angle of 65º for both foliation S n and the contact (S 0 ).Thus, the metadiorite may be used as a prospective guide, as it is easily recognizable in the field as well as in drill hole cores.This may be interpreted as a carbonaceous hydraulic breccia in light of the abundance of quartz veins and veinlets, which are commonly folded and ruptured.Besides, the top contact of the breccia with metadiorite is fractured.
In the C1-Santaluz deposit carbonaceous breccia hosts mineralized quartz veins, which are concordant (most commonly) or discordant to S n //S 0 , where the associated sulfide minerals are pyrite and arsenopyrite.The highest Au grades are typical of concordant veins (Yamana Gold Inc. data).Where carbonaceous breccia with veinlets host lenses of altered brecciated metadacite, gold results tend to increase (personal communication from Yamana Gold Inc. personnel).The presence of arsenopyrite, either in veins or in the host rock is indicative of mineralization.Gold deposition took place in the late stages of the ductile, shear event in which temperatures ranged from 360 to 420ºC (Xavier 1987).
SEM analyses show that pyrite replaces chalcopyrite, which often presents a cubic habit in subhedral-euhedral crystals.Pyrite also occurs as subhedral to euhedral crystals, as much in quartz veins as in the host rock.Though less common, sphalerite is identified as inclusions in chalcopyrite.Stibnite is present exclusively in quartz veins.In general, sulfide minerals cannot be directly used as guide to gold, although the presence of arsenopyrite in quartz veinlets or in the host rocks, associated or not with pyrite, suggests anomalous gold values.
The XRD data show the presence of graphite.With regards to metamorphic grade, a low temperature character is indicated by the low degree of crystallinity of graphite (Barrenechea et al. 1992, Suchy et al. 1997, Crespo et al. 2006).Graphite is only observed in one sample located in the contact region between the metadacite and carbonaceous breccia.Since this is a lithotectonic contact, it is possible that it provided enough heat to the system to favor its local development of this mineral phase.Furthermore, this contact may have aided the generation of arsenopyrite, which is typically deposited under low to moderate temperature in hydrothermal systems (lower or middle greenschist grades, Kretschmar & Scott 1976;320 ± 30ºC, Kerrich & Hoder 1982).The presence of arsenopyrite is indicative of a low temperature formation correlating to the maximum metamorphic temperature of the C1-Santaluz deposit (400ºC), suggested by Xavier (1987) and the present contribution.
In the other three samples analyzed by XRD, carbonaceous material, and not graphite, is present.Additionally, carbonaceous material occurs in quartz crystals interstices in the matrix, or even forming a surface layer on these same grains, suggesting that this material is not the only component of the carbonaceous phyllites or breccias.

Structural aspects and gold mineralization
The mineralized contact (metadiorite and carbonaceous breccia) is almost perpendicular to all other lithological units located in the eastern part of the deposit (Fig. 3).Furthermore, the study area has pre-D n folds characterized by the repeating layers of the chlorite-sericite-quartz schist unit, and they are truncated by the metadiorite/carbonaceous breccias mineralized contact.All these features indicate that the metadiorite intrusion is syn-tectonic with respect to the shear zone marking this contact, and also represents a syn-D n fault zone, since it has the same strike of the S n foliation.
The D n deformation phase corresponds to the main deformation phase of the area.It correlates with the D2 stage described by Chauvet et al. (1997), and is associated with the emplacement of the granitoid plutons in the RIGB, generating a N-S penetrative foliation in the rocks, also marked by shear zones with the same direction.
Mineralized quartz veins embedded in carbonaceous breccias appear associated with the S n foliation, such as is the case in the northern and southern parts of the mine.However, in its central region, S n maintains the same N-S to NNW-SSE direction and the lithological contacts show an E-W orientation.Thus, at this central portion, the mineralized bodies are lodged into the S 0 bedding.This suggests that the mineralized quartz veins in the study area may have been generated prior to the formation of the D n phase, as they have already been constrained by S 0 //S n-1 structure, before deformation in the D n phase (S n schistosity).Large et al. (2011) point out that in orogenic gold systems, the combination of both regional stratigraphic and local structural controls can define the host rock as well as possible ore shoots.Hinge zones of D n folds may be able to concentrate and thicken gold mineralization.The intersection between a structure and a favorable lithotype can form geometric ore shoots (Squire et al. 2008).Thus, the relation between hinge zones of D n folds and the carbonaceous breccia at the C1-Santaluz deposit represents a favorable loci for the formation of gold ore rods.The attitude of the intersection lineation between the S 0 compositional banding and S n foliation (parallel to D n fold axis) reinforces the importance of such conditions for mining purposes.This is particularly important in the C1-Santaluz as auriferous mineralization is associated with carbonaceous phyllite and breccia layers, where ore bodies are marked by quartz rods (D n fold axis).These rods are thickening in the hinge zones of the D n fold dipping to NW, where the compositional banding is perpendicular to the axial plane.
Peak metamorphic conditions were reached during the D n phase, based on the presence of biotite formed and oriented according to the S n foliation.Also, quartz in the matrix is typically granoblastic, deformed and/or stretched according to the preferred orientation of S n .This feature suggests quartz recrystallization, and that subgrain rotation and recrystallization took place according to criteria of Passchier and Trouw (2006).In all rock domains, micaceous minerals define the S n foliation and chlorite zones, and they characterize a lower greenschist facies assemblage.Biotite is observed to be an index mineral for the identified parageneses biotite-chlorite-sericite-quartz-albite, which is indicative of pressure and temperature values of approximately 4 kbar and 400ºC, respectively (Passchier & Trouw 2006).
As already presented before, part of the chlorite in the area is product of metamorphism, being in equilibrium with biotite and muscovite, and representing later alteration.Moreover, pre-and syn-alteration stages of the units may contain chlorite as a hydrothermal alteration product.
For the Fazenda Brasileiro deposit, Vieira et al. (1998) suggest that hydrothermal alteration is subdivided in five stages, of which four and five can be attributed to the formation of orebodies, and their mineral assemblages are represented mostly by chlorite, biotite, arsenopyrite, albite, carbonate and gold.An identical mineral assemblage related to the mineralized host rock has been observed by the present authors in the C1-Santaluz deposit.

CONCLUSIONS
The identified rocks of the studied area are represented by the metavolcanic and metasedimentary domains, and the intermediate intrusive metasubvolcanic lithotype.The schematic simplified lithotectonic column of the C1-Santaluz deposit proposed in this study is composed from base to the top by chlorite-sericite-quartz schist; carbonaceous phyllite; carbonaceous breccia (metasedimentary rocks domain); metandesite & metadacite (metavolcanic rocks domain); metadiorite (metamorphic intermediate intrusive rocks); and quartz veins and veinlets (auriferous mineralization of quartz veins).The metadiorite and the metadacite form abrupt contacts with the mineralized carbonaceous breccia.Therefore, the metasubvolcanic rock assists as a prospective guide for mining in this deposit, since the contact with the metasedimentary domain is easily recognized either in outcrops or in drill holes.This contact is interpreted as a lithotectonic contact, which acted as channels that favored the flow of ore-bearing fluids, precipitating gold and related sulfides, such as arsenopyrite (Mihalasky 2001).
The SEM analyses show that gold is associated with arsenopyrite.The gold genesis is, therefore, directly related to the hydrothermal event that formed this sulfide mineral, either in quartz veins, carbonate-quartz veins, or in the rock matrix.
The XRD data show that most of the carbonaceous material is amorphous.Therefore, the term "carbonaceous material" is kept for the lithotypes carbonaceous phyllite and breccia.
In the C1-Santaluz deposit, three deformational phases are identified: D n-1 , D n and D n+1 .Gold mineralization occurs in intrusive quartz veins and veinlets in carbonaceous breccia.These veins were probably formed during the D n-1 deformational phase, as they also occur in the compositional banding S 0 .Mineralized veins, however, are also evident in hinge zones of D n folds, with axis dipping to NW. Ore shoots appear to be controlled by the orientation of D n fold axis, and as D n transposed all previous structures, in regions far from D n hinge zones, all planar structures and mineralized quartz veins are parallel.This explains why the quartz veins may occur parallel or discordant in respect to the compositional banding and the S n-1 foliation in the C1-Santaluz deposit.

Figure 1 .
Figure 1.(A) São Francisco Craton highlighted in the South American Plataform.(B) The basement terrains of the São Francisco Craton, as well as the Rio Itapicuru greenstone belt located in the Serrinha Block.(C) Geological map of the Rio Itapicuru greenstone belt.The green star represents the current study area, the C1-Santaluz deposit.Modified from Donatti Filho (2007).

Figure 2 .
Figure 2. Synthesis of the geochronological ages of the RIGB and its surrounding lithotypes.

Figure 5 .
Figure 5. Macroscopic samples (A, D, E, F, G, I) and photomicrographs (B, C, H, J) of the C1-Santaluz units.(A) Gray-colored, fine-grained metadacite with oxidized bands; (B) Representative example of metadacite.Notice igneous phases transformed into sericite (highlighted by dashed, red rectangle); (C) Matrix of the chlorite-sericitequartz schist of the Metasedimentary Domain; (D) Chlorite-sericite-quartz schist with oxidized levels; (E) Drill core sample of carbonaceous phyllite showing folded quartz and pyrite veinlets; (F) Carbonaceous phyllite collected from a drill hole showing the main foliation (S n ) parallel to the banding (S 0 ), with both structures folded; (G) Carbonaceous breccia with quartz veinlets, clasts and oxidized features; (H) Carbonaceous breccia showing ductile-brittle features in the matrix; (I) Drill hole of green-gray-colored metadiorite; (J) Photomicrograph showing a metadiorite containing muscovite, plagioclase, quartz, and a carbonate-quartz vein.(B, C, H and J) Cross-polarized, transmitted light photomicrographs of thin sections.

Figure 6 .
Figure 6.Drill hole samples (A, B) and photomicrographs (C, D) of quartz veins and veinlets from mineralized zones of the C1-Santaluz deposit.(A) Concordant (in respect to the main foliation) and discordant quartz veins in hydrothermally altered or silicified carbonaceous phyllite; (B) Silicified carbonaceous breccia with a quartz vein containing arsenopyrite; (C) Sulfide paragenesis represented by pyrite and arsenopyrite in hydrothermally altered carbonaceous phyllite; (D) Free gold grains in quartz vein associated with arsenopyrite in carbonaceous breccia.(C and D) Cross-polarized, reflected light, photomicrographs of thin sections.

Figure 7 .
Figure 7. Intensity vs energy graphs (EDS) from the C1-Santaluz deposit obtained of: (A) Carbonaceous material present in carbonaceous breccia; (B) Ankerite in quartz veins present in carbonaceous phyllite; (C) Gold grain free in a quartz vein hosted in carbonaceous breccia; (D) Arsenopyrite in gold-bearing quartz vein of graph C; (E) Pyrite grain identified in carbonaceous breccia; (F) Chalcopyrite associated with pyrite in carbonaceous breccia; (G) Sphalerite, which represents a subordinate phase in carbonaceous phyllite; (H) Stibnite in carbonaceous phyllite, also a subordinate phase and described for the first time in the deposit.
Figure 8. Scanning electron microscope (SEM) images obtained from thin sections of the C1-Santaluz deposit.(A) Carbonaceous breccia with S 0 bedding parallel to an S n-1 foliation, folded with planar-axial S n foliation; (B) Free gold grains (analyses 5 and 6) associated with arsenopyrite (analyses 3 and 4) in carbonaceous breccia.

Figure 11
Figure 11.(A) Cross-polarized, transmitted light photomicrograph of thin section showing S n foliation transposing S 0 //S n-1 in carbonaceous phyllite.(B) Stereogram of the S n foliation (n = 127) of all lithotypes from the C1-Santaluz deposit.(C) Stereogram of intersection lineation of carbonaceous phyllite and chlorite-sericite-quartz schist.(D) Stereogram of D n fold axes of the metasedimentary domain.(E) Inflection of the metadiorite/carbonaceous breccia contact marking of an overturned synform fold dipping to the northwest.