Structural , Optical , Morphological and Dielectric Properties of Cerium Oxide Nanoparticles

Nanoscience deals with matter at nanoscale dimension, typically in the size range between 1 nm and 100 nm. Unique phenomena/novel properties that are found in materials at the nanoscale enable nanotechnology to be applied in various fields and form a solid basis towards technological breakthrough. Interestingly, such properties are not observed at the atomic/molecular scale or at the bulk scale, thus making nanotechnology an emerging technology of the 21st century. The surface to volume ratio is much higher in nanoparticles compared with their respective bulk materials. Therefore, surface atoms that are known to be in an energetic state different from that of the bulk atoms make significant contribution to the total free energy. Cerium oxide (CeO2) is a semiconductor with wide band gap energy (3.19eV). In the recent years, much effort has been made towards the development of new synthetic routes for preparing nanostructure cerium oxides due to their potential uses in many applications, such as high-storage capacitor devices, buffer layers for conductors, fuel cells, polishing materials, UV blocks and optical devices 1-7. The cerium oxide nanoparticles are prepared by various methods 8-12. This paper deals with the preparation of cerium oxide nanoparticles using the precipitation method. The prepared nanoparticles were characterized by powder X-ray diffraction analysis, FTIR, Raman spectrum, Scanning Electron Microscopy (SEM), Transmission Electron Microscope (TEM) UV-analysis and dielectric studies.


Introduction
Nanoscience deals with matter at nanoscale dimension, typically in the size range between 1 nm and 100 nm.Unique phenomena/novel properties that are found in materials at the nanoscale enable nanotechnology to be applied in various fields and form a solid basis towards technological breakthrough.Interestingly, such properties are not observed at the atomic/molecular scale or at the bulk scale, thus making nanotechnology an emerging technology of the 21 st century.The surface to volume ratio is much higher in nanoparticles compared with their respective bulk materials.Therefore, surface atoms that are known to be in an energetic state different from that of the bulk atoms make significant contribution to the total free energy.Cerium oxide (CeO 2 ) is a semiconductor with wide band gap energy (3.19eV).In the recent years, much effort has been made towards the development of new synthetic routes for preparing nanostructure cerium oxides due to their potential uses in many applications, such as high-storage capacitor devices, buffer layers for conductors, fuel cells, polishing materials, UV blocks and optical devices [1][2][3][4][5][6][7] .The cerium oxide nanoparticles are prepared by various methods [8][9][10][11][12] .This paper deals with the preparation of cerium oxide nanoparticles using the precipitation method.The prepared nanoparticles were characterized by powder X-ray diffraction analysis, FTIR, Raman spectrum, Scanning Electron Microscopy (SEM), Transmission Electron Microscope (TEM) UV-analysis and dielectric studies.

Experimental Procedure
Cerium oxide (CeO 2 ) nanoparticles were prepared by the precipitation method using cerium sulfate (Ce 2 (SO 4 ) 2 ), oxalic acid (H 2 C 2 O 4 ).In a typical synthesis procedure, 1 g of cerium sulfate dispersing was put into 100 mL distilled water to form a clear solution, which was stirred strongly at room temperature for about 5 h.The obtained clear solution was added drop-wise to 10 ml ammonia water under constant stirring condition for 2 h.The resultant synthesis precipitate was washed with deionized water and dried at 70 o C for 24 h.The X-ray diffraction analysis (XRD) pattern of the CeO 2 nanoparticles was recorded by using a powder X-ray diffractometer (Schimadzu model: XRD 6000 using CuKα (λ=0.154nm)) radiation, with a diffraction angle between 20 and 80º.The crystallite size was determined from the broadenings of corresponding X-ray spectral peaks by using Scherer's formula.The FTIR spectrum of the CeO 2 nanoparticles was taken using an FTIR model Bruker IFS 66W Spectrometer.Raman spectrum was obtained using a

Devadoss Mangalam Durai Manoharadoss Prabaharan a *, Karuppasamy Sadaiyandi b , Manickam Mahendran c , Suresh Sagadevan d
Bruker RFS 27: stand-alone model Raman spectrometer.Scanning Electron Microscopy (SEM) studies were carried out on JEOL, JSM-67001.Transmission Electron Microscope (TEM) image was taken using an H-800 TEM (Hitachi, Japan) with an accelerating voltage of 100kV.UV-Vis absorption spectrum for the CeO 2 nanoparticles was recorded using a Varian Cary 5E spectrophotometer in the range of 300-800 nm.The dielectric constant and the dielectric loss of the pellets of CeO 2 nanoparticles in disk form were studied at different temperature using a HIOKI 3532-50 LCR HITESTER in the frequency range of 50 Hz to 5 MHz.

XRD analysis
Structural identification of cerium oxide nanoparticles was done by means of X-ray diffraction in the range of angle 2θ between 20• and 80• as shown in Fig. 1.The excellent peaks (111), ( 200), ( 220), ( 311), ( 222), ( 400), (331), and (422) were obtained.It was clearly indicated that the fine crystalline and single phase of CeO 2 , could be indexed to the cubic structure.The broadened peak showed the nanometer-sized crystallites.The average nano-crystalline size (D) was calculated using the Scherrer formula, .cos where λ is the X-ray wavelength, θ is the Bragg diffraction angle, and β is the full width half maximum (FWHM) of the XRD peak appearing at the diffraction angle θ.The average crystalline size was calculated from X-ray line broadening using Scherrer equation and it was found to be about 11 nm.

FTIR and FT-Raman Analysis
The FTIR spectrum of the cerium oxide nanoparticles are shown in Fig. 2. The spectrum clearly shows the three intense peaks situated at 3418, 1612 cm −1 and below 700 cm −1 .The weak absorption peaks at 2380 and 1430 cm −1 are attributed to the bending vibration of C-H bands of the incorporated surfactant residuals.Furthermore, the O-C-O stretching band is also observed in the region 1300-1600 cm −1 .The absorption band around 1634 cm −1 is attributed to the bending vibration of absorbed molecular water, which can be seen in all the specimens.The peak at 450 -550 cm -1 is attributed to the O-Ce-O stretching mode of vibration.
Fig. 3 shows the Raman spectrum of cerium oxide nanoparticles.Ceria, which are cubic fluorite structure-metal dioxides, have a single Raman mode at 464 cm -1 13 .This peak confirms the cubic nature of the cerium oxide, which has F 2g symmetry and can be viewed as a symmetric breathing mode of O atoms around each cation.As only the O atoms move, the vibrational mode is nearly independent of cation mass.

SEM analysis
Scanning Electron Microscopy (SEM) provided further approaching into the morphology and size details of the nanoparticles.The surface morphology of the prepared cerium oxide nanopartices was revealed through the SEM image as shown in Fig. 4. It is clearly shown that the particles are formed in a spherical shape.

TEM analysis
TEM is commonly used for imaging and analytical characterization of the nanoparticles to assess the shape, size, and morphology.TEM images of the cerium oxide nanoparticles are shown in Fig. 5.It is evident from the Fig. 5 that the particles were smaller in size and uniform in shape.The estimated particle size was around 16 nm with a narrow size distribution.

UV analysis
Optical absorption measurement was carried out on cerium oxide nanoparticles.Fig. 6 shows the variation of the optical absorbance with the wavelength of the nanoparticles.
The optical absorption coefficient was calculated in the wavelength range of 300 -800 nm.The UV-Vis absorption spectrum reveals that the absorption threshold edge was found to be 421 nm.The spectra show a strong red shift of the absorption threshold edge compared with bulk CeO 2 material (E g =3.19eV).
The optical absorption coefficient (α) was calculated from transmittance using the following relation where T is the transmittance and d is the thickness.The study has an absorption coefficient (α) obeying the following relation for high photon energies (hν) where α, E g, and A are the absorption coefficient, band gap, and constant respectively.The fundamental absorption corresponding to the optical transition of the electrons from the valence band to the conduction band can be used to determine the nature and value of the optical band gap E g of the nanoparticles.A plot of (αhν) 2 vs (hν) is used to evaluate the direct optical band gap of the material and is shown in Fig. 7.The band gap is determined by extrapolating the linear portion of the curve.The band gap was found to be 2.8 eV.

Dielectric Properties
The dielectric constant and the dielectric loss of the pellets of cerium oxide nanoparticles in disk form were studied for different frequencies and different temperatures.The dielectric constant is evaluated using the relation, result of charge trapping 14 .The dipole moment can easily follow the changes in the electric field, especially at low frequencies.Hence, the contributions to dielectric constant increase through space charge polarization and rotation polarization, which occur mainly in interfaces 15 .Therefore dielectric constant of nanostructured materials should be larger than that of the conventional materials.One of the reasons for the large dielectric constant of nanocrystalline materials at sufficiently high temperature is the increased space charge polarization due to the structure of their grain boundary interfaces.Also, at sufficiently high temperature the dielectric loss is due to the sharp increase of the dielectric constant at low frequencies and at lower temperatures.
As temperature increases, the space charge and ion jump polarization decrease, resulting in a decrease in dielectric constant.
When a dielectric is subjected to an alternating electric field, the electric field strength changes as, The induced current in the dielectrics does not change exactly with the applied voltage.The current is found to lead the potential in phase.In a similar way, the electrical displacement is also not in phase with respect to E. Now the expression for D becomes, The factor sin δ is a measure of the energy absorbed by dielectrics.It is known that in a capacitor the dielectrics usually have a resistance R and impedance Z that are related to the phase angle.Assuming R to be very large, The factor tan δ is referred to as the dielectric loss.The variations of the dielectric loss of cerium oxide nanoparticles with frequency and temperature are shown in Fig. 9.It can be seen that the dielectric loss decreases with increase of frequency and at higher frequencies the loss angle has almost the same value at all temperatures.In dielectric materials, generally dielectric losses occur due to absorption current.The orientation of the molecules along the direction of the applied electric field in polar dielectrics requires a part of the electric energy to overcome the forces of internal friction 16 .One more part of the electric energy is utilized for rotations of dipolar molecules and other kinds of molecular transfer from one position to another, which also involve energy losses.In nanophase materials, inhomogeneities similar to defects and space charge formation in the inter phase layers create an absorption current ensuing in a dielectric loss 17 .
The ac conductivity of the CeO 2 nanoparticles, ac conductivity can be calculated by the following relation:  The ac conductivity shows a typical behaviour; a power law increase at frequencies between 10 5 and 10 7 Hz.This regime is attributed to hopping conduction which sets in frequency above 10 4 Hz and the regime is clearly visible for the sample.
There is a small increase in the electrical conductivity of the nanomaterial at the low frequency region for an increase in frequency and is the same for all temperatures.Conversely, at high frequencies especially in the KHz region, there is an abrupt increase in the conductivity and it is enormous at high temperatures which could be attributed to small polaron hopping.

Conclusions
Cerium oxide (CeO 2 ) nanoparticles were synthesized using simple chemical precipitation method.The formation of CeO 2 nanoparticles was confirmed by X-ray diffraction (XRD).The FT-IR spectrum indicated the presence of CeO 2 nanoparticles.Raman spectrum confirmed the cubic nature of the CeO 2 nanoparticles.The morphology and the size of the cerium oxide nanoparticles were characterized using Scanning and Transmission Electron Microscopy (SEM and TEM).The optical properties were studied by the UV-Visible absorption spectrum.The variations of the dielectric constant, the dielectric loss with frequency and temperature for CeO 2 nanoparticles were analyzed.The AC electrical conductivity was found to increase with an increase in the temperature and frequency.