Nanoparticles of ZnO Doped With Mn : Structural and Morphological Characteristics

In this study, the effects of dopant concentrations on the structural and morphological characteristics of Zn1-xMnxO powders (x= 0.025, 0.05, 0.075, and 0.1 mole) synthesized by the Pechini method has been investigated. The powder was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) specific surface, energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and Spectroscopy with Fourier transform (FTIR). An XRD analysis of the powder showed the formation of ZnO phase with a typical single phase wurtzite structure. The EDX analysis revealed Mn incorporated in the ZnO structure. The particle size calculated by BET ranged from 24 to 63 nm, confirming the nanometric size of the powder particles. The SEM analysis revealed irregular shaped particle agglomerates and the presence of nanosheets. From FTIR it was confirmed the wurtzite structure in ZnO and ZnO nanoparticles doped with Mn.


Introduction
ZnO is a well-known optoelectronic material belonging to the wide-bandgap semiconductor family, with relatively high exciton binding energy (~60 meV).It has been extensively investigated for various applications such as varistors 1 , transparent transistors 2,3 , sensors 4 , and UV light emitting devices 5,6 .The prediction 7 that p-type ZnO and GaN may exhibit ferromagnetism characteristic above room temperature in response to doping with Mn has initiated intensive experimental work on a variety of doped diluted magnetic semiconductors (DMS) [8][9][10][11][12][13][14] .Diluted magnetic semiconductors (DMSs), and particularly ferromagnetic oxides, are potential candidates for technological applications such as spin-transistors or the ultra-dense nonvolatile semiconductor memories 15 .This new field of semiconductor electronics controls and hence exploits the spin degree of freedom of the electron, in addition to or in place of its charge, for several applications.In doped ZnO, the Zn ions located in the tetrahedral sites of the wurtzite structure can be substituted by magnetic transition-metal (TM) ions, thereby forming a solid solution.The presence of TM ions in these materials leads to an exchange interaction between itinerant sp-band electrons or holes and the d-electron spins localized at the magnetic ions, resulting in versatile magnetic fieldinduced functionalities 16 .
The polymeric precursor method, which consists in polymerizing a solution of ethylene glycol, citric acid and metal ions to form a polyester-type resin, has recently received attention because of its simplicity.This method enables the metal ions to become immobilized in a rigid polyester lattice, which greatly reduces the segregation of a particular metal during processing.Therefore, it offers a distinct advantage over most other methods, in that very pure mixed oxides can be prepared 17 .Furthermore, nanosized powders render the ceramic system highly attractive for the design of new functional materials, whose properties depend on particle size.Knowledge about nucleation and growth is therefore essential to control particle size 18 .
The aim of this work was to evaluate the effect of different concentrations of Mn +2 on the structural and morphological characteristics of ZnO synthesized by the polymer precursor route.

Experiment
Zn 1-x Mn x O powders (x = 0.025, 0.05, 0.075, and 0.10) were prepared by the polymeric precursor method Pechini 19 .Citric acid was dissolved in distilled water pre-heated at 70 o C. The ratio of citric acid/metal cations was of 3:1 (in mol), according to Carreno et al. 20  Ethylene glycol was added with a ratio of 40/60%w/w relative to the citric acid according to stoichiometric calculations.The mixture was heated to 120° C, to form polymer resin by esterification and polyesterification reactions.
The resin was pyrolysed at temperature of 400°C/1hs, with heating rate of 10°C/min, to obtain a semi-carbonized material, similar to foam.Then, the material was deagglomerated, passed in a sieve with 200 mesh and calcined at 500° C/1hs, with heating rate of 10° C/min, to obtain the ZnO powder doped with manganese.
The material was characterized by powder X-ray diffraction (XRD) using a SHIMADZU XRD-6000 diffractometer operating with CuKα radiation.The average crystallite size was calculated from the X-ray peaks, using the Scherrer equation 21 .The chemical compositions and microstructures of the samples were examined in an energy dispersive X-ray analyzer (EDX) coupled to a scanning electron microscope (Philips XL-30 FEG SEM).The particle morphology and size were also analyzed by scanning electron microscopy (Philips XL-30 FEG SEM).The information about the molecular geometry, intermolecular interaction and vibration present in ZnO nanoparticles doped with Mn were obtained from the analysis of infrared spectroscopy with Fourier transform (FTIR).The FTIR spectra were recorded using the spectrometer PERKIN-ELMER Spectrum 400 IR with resolution of 4 cm -1 .The XRD patterns for the powders with x > 0.025 composition indicate that the ZnO structure was unaffected by the substitution.The XRD patterns showed no detectable reflections due to any secondary phase.The width of the reflections increased in response to increasing Mn content, indicating decreasing particle (crystallite) size.The average particle sizes were calculated from X-ray line broadening using the Scherrer equation.Note that the average particle size decreased with increasing Mn content, which is in agreement with similar results reported in the literature 22 .The average particle sizes obtained in the different Zn 1−x Mn x O compositions were 63, 49, 37 and 24 nm for x = 0.025, 0.05, 0.075 and 0.1, respectively.The expanded XRD patterns of the 30°-38° 2θ region shown in Figure 2 clearly indicate that the XRD reflections shifted to lower 2θ values as the concentration of Mn increased.This is a proof of the incorporation of Mn ions inside the ZnO crystal lattice.The ionic radius of Zn 2+ is 0.60 Å and of Mn 2+ is 0.66 Å, for 4-fold coordination 23 .Hence, the addition of Mn to Zn causes the ZnO lattice to expand.A similar pattern was observed by Sasanka et al. 24 .Table 1 describes the particle size (D BET ), crystallite size (D DRX ) and lattice parameter (a=b, c) of the samples doped with different concentrations of Mn.

Results and Discussion
Table 1 also shows that the specific surface area increased with increasing amounts of dopant at a given temperature, while the particle size calculated by BET decreased.Table 2 lists the wt% of the elements in undoped ZnO and Mndoped Zn.
The EDX analysis revealed that the amount of Mn element in the sample increased in response to increasing Mn content in the solution.The incorporation of Mn can affects the optical, structural and morphological properties of ZnO.The EDX image in Figure 3    As can be seen, the adsorption/desorption curves are of type II, with aspects of sigmoidal sorption isotherm and with hysteresis typical of mesopores.The phenomenon of hysteresis is caused by the process of capillary condensation in the structures of mesopores.The position and shapes of the hysteresis loops are closely related with the geometry of the mesopores.In Figure 4, four isotherms can be classified as type H-1, in accordance with the IUPAC classification.
Figure 5 show SEM micrographs of Zn 1-x Mn x O powder synthesized by the Pechini method and calcined at 500ºC.From Figure 5 the samples a and c exhibit irregular shaped particle agglomerates and the presence of nanosheets.These nanosheets are interconnected and have approximately uniform size.Sample b, on the other hand, shows high porosity and a high degree of agglomeration.
Figure 6 shows the FTIR spectra for the composition Zn 1-x Mn x O with (x = 0.025, 0.05 and 0.075, 0.10), respectively.The strong band is observed centered at 450cm -1 for all the samples and is assigned to the asymmetric stretching vibration of the group O-Zn-O in the octahedral coordination, while the peak at approximately 620cm -1 is assigned to the group stretch of Mn-O.These bands confirm the wurtzite structure in ZnO and ZnO nanoparticles doped with Mn.The absorption band in the range between 3350-3650cm -1 is assigned to the -OH groups of H2O, indicating the existence of water absorbed on the surface of the nanoparticles of ZnO.The two absorption peaks observed at 1400 and 1600 cm -1 correspond   to the symmetric and asymmetric C=O bond stretching.The deformation bands of C=O can also be observed at 980 cm -1 .

Conclusions
Nanocrystalline Zn 1-x Mn x O powders with x= 0.025, 0.05, 0.075, and 0.1 mole hve been synthesized.The X-ray diffraction patterns of the samples showed the formation of ZnO phase as main phase.The crystallite size of the samples calcined at 500°C changed from 14 to 23nm, confirming the nanometric size of the powder particles.The lattice parameters increased in response to increasing dopant content, due to a structural defect.The EDX analysis confirmed the presence of manganese in the ZnO lattice.An analysis of the sorption curves indicated that the phases calcined at 500°C contained mesopores and H-1 type hysteresis.The powder morphology revealed the formation of irregular shaped soft agglomerates and the presence of nanosheets.These findings confirmed the effectiveness of the Pechini method for the production of ceramic powders with nanoscale features.From FTIR it was confirmed the wurtzite structure in ZnO and ZnO nanoparticles doped with Mn.

Figure 1
Figure 1 depicts the powder XRD patterns of different Zn 1−x Mn x O (0.025< x ≤ 0.1) samples.The XRD patterns for the powders with x > 0.025 composition indicate that the ZnO structure was unaffected by the substitution.The XRD patterns showed no detectable reflections due to any secondary phase.The width of the reflections increased in response to increasing Mn content, indicating decreasing particle (crystallite) size.The average particle sizes were calculated from X-ray line broadening using the Scherrer equation.Note that the average particle size decreased with increasing Mn content, which is in agreement with similar results reported in the literature22 .The average particle sizes obtained in the different Zn 1−x Mn x O compositions were 63, 49, 37 and 24 nm for x = 0.025, 0.05, 0.075 and 0.1, respectively.The expanded XRD patterns of the 30°-38° 2θ region shown in Figure2clearly indicate that the XRD reflections shifted to lower 2θ values as the concentration of Mn increased.This is a proof of the incorporation of Mn ions inside the ZnO crystal lattice.The ionic radius of Zn 2+ is 0.60 Å and of Mn 2+ is 0.66 Å, for 4-fold coordination23 .Hence, the addition of Mn to Zn causes the ZnO lattice to expand.A similar pattern was observed by Sasanka et al.24 .

Figure 2 :
Figure 2: Comparison of the expanded XRD patterns for powders with different compositions of Zn 1−x Mn x O (0.025 < x ≤ 0.1) in the 30°-38° 2θ regions.
(a) shows Zn and O and (b)-(c), confirming the presence of manganese in the ZnO particles.Moreover, the weight percentages are very nearly equal to the nominal value of Mn in ZnO.(Note: the peaks of Al are due to the sample holder used for depositing the samples for EDX testing.The trace Au of less than 0.1wt% is due to the coating used for the SEM test).

Figure 3 :
Figure 3: EDX image of the samples (a-c) calcined at 500°C for 1h on air.

Figure 4
Figure 4 illustrates the nitrogen adsorption/desorption curves of the phases in samples of zinc oxide doped with different amounts of manganese.As can be seen, the adsorption/desorption curves are of type II, with aspects of sigmoidal sorption isotherm and with hysteresis typical of mesopores.The phenomenon of hysteresis is caused by the process of capillary condensation in the structures of mesopores.The position and shapes of the hysteresis loops are closely related with the geometry of the mesopores.In Figure4, four isotherms can be classified as type H-1, in accordance with the IUPAC classification.

Figure 5 :
Figure 5: SEM micrographs of the morphology of Zn 1-x Mn x O prepared by the Pechini method and calcined at 500°C: (a) Zn 0.975 Mn 0.025 O; (b) Zn 0.95 Mn 0.05 O, and (c) Zn 0.925 Mn 0.075 O. Magnification x 320000.
, this relationship promotes the formation and stabilization of metallic citrate.The solution was kept under constant stirring.Next, the zinc nitrate hexahydrate Zn(NO 3 ) 2 .6H 2 O (from Merck) and manganese a Department of Materials Engineering, Federal University of Campina Grande, 58429-900, Campina Grande, PB, Brazil b Academic Unit of Materials Engineering, Federal University of Cariri, 63048-080, Juazeiro do Norte, CE, Brazil c Department of Materials Engineering, Federal University of São Carlos, 13565-905, São Carlos, SP, Brazil nitrate Mn(NO 3 ) 2 .xH 2 O (from Sigma-Aldrich) were added to the solution, in a fractional way to better homogenization.

Table 1 :
Particle size, crystallite size, and lattice parameters a, b and c of samples doped with different concentrations of Mn as a function of the calcination temperature of 500°C, for 1 hour.

Table 2 :
Dopant concentration (at %) in the target material and powders