ABSTRACT
Tubular ceramic microfiltration membranes were prepared by extruding thermally treated clay (TC) and raw clay (NC) mixtures in different fractions with the addition of cationic manioc starch. Previous studies have verified that membranes containing TC possess higher hydraulic permeability and permeate flow values than those containing only NC for application in crossflow filtration. However, TC membranes had a low mechanical strength. Therefore, this study aimed to increase the mechanical strength without adversely affecting their permeate flow and hydraulic permeability. The physical, mineralogical, and morphological characteristics of the membranes were determined. The membranes were used for microfiltration of Acutodesmus obliquus microalgae with applied pressure of 1 bar with a volumetric flow rate of 250 L/h at a temperature of 10 ± 5°C. The efficiency of each ceramic membrane was evaluated in terms of the permeate flow for water and microalgae and hydraulic permeability. The mixture of 70% TC, 15% starch fractions and sintered at 1150°C exhibited optimal performance in mechanical strength (15.1±0.2 MPa), water permeate flow of 522.4±0.3 Kg•m-2•h-1, microalgae permeate flow of 114.8±0.8 Kg•m-2•h-1 and hydraulic permeability of 568.0±0.3 Kg•m-2•h-1•bar.
Keywords
membranes; kaolinite; mechanical strength
RESUMO
Membranas de microfiltração em cerâmica tubular foram preparadas por extrusão de misturas de argilas naturais (NC) e argilas tratadas termicamente (TC) em diferentes frações com a adição de amido de mandioca catiônico. Estudos anteriores verificaram que membranas contendo TC possuíam maior permeabilidade hidráulica e fluxo permeado do que aquelas que continham somente NC para a aplicação em filtração tangencial. Entretanto, as membranas TC tinham uma baixa resistencia mecânica. Assim sendo, este estudo teve como objetivo aumentar a resistência mecânica sem afetar adversamente seu fluxo permeado e permeabilidade hidráulica. As características físicas, mineralógicas e morfológicas das membranas foram determinadas. As membranas foram usadas para microfiltração de microalga Acutodesmus obliquus com pressão aplicada de 1 bar com taxa de fluxo volumétrica de 250 L/h em uma temperatura de 10 ± 5°C. A eficiência de cada membrana cerâmica foi avaliada em termos de fluxo permeado para água e microalga e permeabilidade hidráulica. A mistura de 70% de TC, 15% de fração de amido e sinterizado em 1150ºC exibiu ótimo desempenho em resistência mecânica (15.1±0.2 MPa), fluxo permeado de água de 522.4±0.3 Kg•m-2•h-1, fluxo permeado de microalga de 114.8±0.8 Kg•m-2•h-1 e permeabilidade hidráulica de 568.0±0.3 Kg•m-2•h-1•bar.
Palavras-chave
membranas; caulinita; resistência mecânica
1. INTRODUÇÃO
Microalgae are widely used in biofuel production given their unique characteristics of high growth rate, productivity, and oil concentration, as well as their excellent adaptability to different environmental conditions. In addition, the cultivation of microalgae does not require large areas of arable land [11 CHISTI, Y., “Biodiesel from microalgae”, Biotechnology Advances, v. 25, pp. 294-306, May. 2007.,22 MATA, T. M., MARTINS, A. A., CAETANO, N. S., “Microalgae for biodiesel production and other applications: A review”, Renewable and Sustainable Energy Reviews, v. 14, pp. 217-232, Jan. 2010.].
The separation of algal biomass is particularly challenging because of the small size and low density of algae, as well as the large volumes of water necessary for algal recovery [33 BRENNAN, L., OWENDE, P., “Biofuels from microalgae - A review of technologies for production, processing, and extractions of biofuels and co-products”, Renewable and Sustainable Energy Reviews, v.14, pp. 557-577, Feb. 2010.,44 ZHANG, X., HU, Q., SOMMERFELD, M., PURUHITO, E., et al., “Harvesting algal biomass for biofuels using ultrafiltration membranes”, Bioresource Technology, v. 101, pp. 5297-5304, Jul. 2010.].
Filtration using low-pressure membranes has been highlighted as an excellent separation process given its facile operation, low energy input, and high filtering efficiency without the need for additional chemical contaminants to the system [44 ZHANG, X., HU, Q., SOMMERFELD, M., PURUHITO, E., et al., “Harvesting algal biomass for biofuels using ultrafiltration membranes”, Bioresource Technology, v. 101, pp. 5297-5304, Jul. 2010.,55 ZOU, S., GU, Y., XIAO, D., et al., “The role of physical and chemical parameters on forward osmosis membrane fouling during algae separation”, Journal of Membrane Science, v. 366, pp.356–362, Jan. 2011.].
Ceramic membranes have several advantages that enable their use in separation processes and are produced from value-added synthetic materials, such as zirconia, alumina, titania, and silica [66 KUMAR, R. V., GHOSHAL, A. K., PUGAZHENTHI, G., “Elaboration of novel tubular ceramic membrane from inexpensive raw materials by extrusion method and its performance in microfiltration of synthetic oily wastewater treatment”, Journal of Membrane Science, v. 490, pp. 92-102, Sep. 2015.]. The production of porous ceramic membranes by incorporating natural raw materials with competitive prices, combined with highly efficient production processes, can help increase the use of these membranes worldwide [77 HENRIQUES, J.D. O., PEDRASSANI, M.W., KLITZKE, W., et al., “Thermal treatment of clay-based ceramic membranes for microfiltration of Acutodesmus obliquus”, Applied Clay Science, v. 150, pp. 217–224, Dec. 2017.]. The synthesis of porous ceramics frequently includes a substance which disappears during the thermal treatment of sintering generating an additional network of pores that modify the membrane pore size distribution that could be obtained with the ceramic composition by itself [88 LORENTE-AYZA, M. M., ORTS, M. J., PÉREZ-HERRANZ, V., MESTRE, S., “Role of starch characteristics in the properties of low-cost ceramic membranes”, Journal of the European Ceramic Society, v.35, pp. 2333-2341, Aug. 2015.].
Therefore, the thermally treated of the clay can be an alternative in the development of membranes. Interactions between the raw materials present in the green body and between the constitutive minerals can be affected by any change in the thermal treatment [99 CASTELEIN, O., SOULESTIN, B., BONNET, J.P., et al., “The influence of heating rate on the thermal behaviour and mullite formation from a kaolin raw material”, Ceramic International, v. 27, pp. 517–522, 2001.].
Considering the potentials benefits of previous works, this study aimed to develop tubular ceramic membranes by using thermally treated clay (TC) - raw clay (NC) mixture with organic additives such as pore-generating agents. The fabricated membranes were applied to crossflow microfiltration for the recovery of Acutodesmus obliquus. The efficiency of the membranes was evaluated in terms of the mechanical strength, microalgae retention and permeate flow.
2. MATERIALS E METHODS
2.1 Materials
A commercial composition of faience clay obtained from Cermassas–Pastacer Ltda. (Campo Largo/PR) was used to produce the ceramic membranes applied in this study. This clay was obtained in two forms: raw clay (NC) and thermal treatment clay (TC), which was obtained by exposing the NC to a temperature of 500ºC for 24 h with subsequent slow cooling. To form pores in the ceramic membrane, commercial cationic manioc starch (CMS) (Superion 300, with a degree of substitution of 0.033 mol/mol to 0.036 mol/mol) was added to the clay mixtures. The CMS was obtained from Grupo Horizonte-Agrícola Horizonte Ltda. PR (Brazil).
The commercial clay was oven dried for 12 h and ground. The clay NC and TC samples were each crushed in a bench ball mill (TECNAL) with alumina balls and stored for 4 h. Each of the clay samples was passed through a sieve with #60 Tyler/mesh (0.250 mm). The TC and NC mixtures in different fractions were named BC. Then, different CMS fractions (SF) varying from 12.3 to 22.5% were mixed with the BC and homogenized with water to form a paste with an initial moisture content of 25%. The membranes were then formed via extrusion. The membranes were then sintered at temperature between 872 and 1150ºC for 30 min. Table 1 shows the experiments with different compositions of BC, SF and temperature.
The obtained membranes had a tubular shape with an outside diameter of 18.85 mm, inside diameter of 10.75 mm, thickness of 4.05 mm, and length of 200 mm, as shown in Figure 1.
2.2 Characterization of clays and membranes
The ceramic membranes were characterized using a variety of techniques as follows:
X-ray fluorescence (XRF) tests were performed to quantitatively determine the chemical composition of the samples. The tests were conducted using PANalytical equipment (Axios Max) equipped with a rhodium X-ray tube at 4 kv. The loss of ignition of the samples was determined by calcination at 1000 °C for 2 h.
X-ray diffraction (XRD) experiments were performed to identify the glass and mineral phases in the samples. The tests were conducted on PANalytical equipment EMPYREAN with X’Celerator detector and copper tube at a 2θ range of 3.5° to 70°. X’Pert High Score Plus was used to interpret the results of XRD analysis. SD, XRF, and XRD analyses were performed in the Laboratory of Analysis of Minerals and Rocks at the Federal University of Paraná (UFPR).
Scanning electron microscopy (SEM) with a 10-kV beam voltage was used to estimate the particle sizes and morphologies of samples (Tescan, LMU; model, Vega 3). The imaging was performed at the Center for Electronic Microscopy, UFPR.
The pore size distributions and densities of the green and sintered samples were determined using AutoPore IV 9500 V1.07 (Micromeritics Instrument Corporation).
The standard three-point bending test was performed to examine the maximum load that could be supported by the membranes. EMIC-DL 30000, a universal test machine, was used with a maximum load capacity of 300 kN and a constant speed of 5 mm·min−1. The distance between the support points was 90 mm. The mechanical strength of the membrane was determined in accordance with Equation (1)[6]:
where σis the mechanical strength of the membrane (MPa); F is the applied force (N); L is the distance between the sample support points (mm); and dinand doutare the inner and outer diameters of the membrane (mm), respectively.
2.3 Microfiltration with ceramic membranes
Filtration experiments were conducted to compare the efficiencies of the membranes in terms of the water permeability under the following operating parameters: a volumetric flow rate of 250 L·h−1, pressure of 1.0 bar, and a temperature of 10 ± 5°C. The benchtop scale filtration system comprised a feed tank, a pump for fluid circulation, and a membrane module (Fig. 2).
Prior to flow measurements, each membrane was characterized and then compacted with water under a constant flow rate of 250 L·h−1 and pressure of 1.0 bar for 45 min. At the end of each experiment, the membranes and filtration unit were chemically cleaned with sodium hypochlorite solution (1000 ppm) [1010 BILAD, M. R., VANDAMME, D., FOUBERT. I., et al., “Harvesting microalgal biomass using submerged microfiltration membranes”, Bioresource Technology, v. 111, pp. 343–352, May. 2012.]. The water tests were repeated to verify that the membrane and filtration system were effectively cleaned.
After compaction, microfiltration tests were conducted with a constant flow rate of 250 L·h−1 and pressure of 1.0 bar. In each test, permeate samples were collected every 4 min to determine the retention efficiency of the membranes.
2.4 Measurement of water flow through the ceramic membrane
The permeate flow, J (kg·m−2·h−1), was determined according to the following equation.
where mp is the mass of the permeate (kg), Ap is the membrane area (m2), and t is the operating time (h).
The hydraulic permeability, Lp (kg·m−2·h−1·bar−1), was determined according to Eq. (3) [66 KUMAR, R. V., GHOSHAL, A. K., PUGAZHENTHI, G., “Elaboration of novel tubular ceramic membrane from inexpensive raw materials by extrusion method and its performance in microfiltration of synthetic oily wastewater treatment”, Journal of Membrane Science, v. 490, pp. 92-102, Sep. 2015.,1111 NANDI, B.K., UPPALURI, R., PURKAIT, M.K., “Preparation and characterization of low cost ceramic membranes for micro-filtration applications”, Applied Clay Science, v. 42, pp. 102–110, Dec. 2008.].
where J is water permeate flow versus the transmembrane pressure, ΔP (bar).
The percent of turbidity removal, TR, can be calculated using the following equation [1212 BELIBI, P.B., NGUEMTCHOUIN, M.M.G., RIVALLIN, M., et al., “Microfiltration ceramic membranes from local Cameroonian clay applicable to water treatment”, Ceramic International, v. 41, pp. 2752–2759, Oct. 2015.]:
2.5 Application of ceramic membranes to retain microalgae
An A. obliquus strain was isolated by the Nucleus of Self-sustaining Energy Research and Development in Curitiba. The alga was cultivated in a tubular photobioreactor using a photoautotrophic technique involving water and 2.5% (v/v) biodigested swine wastewater effluent as the culture medium. Cultures were maintained at ambient temperature and irradiation conditions and supplied with compressed air comprising 0.04% (v/v) CO2. For use in the experiments, fresh cultures were taken from the photobioreactor at day 15 during the exponential growth phase (cell density: 2.54 × 1013 cells·m−3; cell concentration: 0.60 kg·m−3) [77 HENRIQUES, J.D. O., PEDRASSANI, M.W., KLITZKE, W., et al., “Thermal treatment of clay-based ceramic membranes for microfiltration of Acutodesmus obliquus”, Applied Clay Science, v. 150, pp. 217–224, Dec. 2017.].
Filtration experiments were conducted with the membranes to compare the effects of BC, SF and sintering temperature. The tests were conducted at pressures of 1 bar. Tests for each set of conditions were performed in triplicate with a new membrane for each trial. The operating temperature was 10 ± 5°C. Then, the permeate flow, hydraulic permeability and retention of the microalgae suspension were calculated using Eqs. 2, 3 and 4, respectively.
RESULTS AND DISCUSSION
Characterizations of clays (NC and TC) using techniques of Granulometric analysis, Scanning electron microscopy (SEM), Thermogravimetric analysis (TGA) are reported in Henriques et al 2017 [77 HENRIQUES, J.D. O., PEDRASSANI, M.W., KLITZKE, W., et al., “Thermal treatment of clay-based ceramic membranes for microfiltration of Acutodesmus obliquus”, Applied Clay Science, v. 150, pp. 217–224, Dec. 2017.].
3.1 Results for mechanical strength
The membranes were characterized according to their mechanical strength to determine the maximum load that they can support. The mechanical strength of each membrane was calculated according to Eq. (1). The average results mechanical strengths are presented in Figure 3.
The results indicate a significant difference between the membranes in terms of the mechanical strength. As shown in Figure 3, the obtained mechanical strength varied from 2.4 ± 0.2 to 18.9 ± 0.3 MPa. Experiment 4 has a higher mechanical strength than experiment 3; this difference was related to the sintering temperature, which was higher for experiment 4 (1150ºC) than for experiment 3 (1000ºC), for the same BC (70%) and SF (15%). The comparison of the mechanical strength of experiments 2 and 4 verified that the increase in the BC of 30% for 70% decreased the mechanical strength of 18.9 ± 0.3 for 15.1± 0.2 MPa. Opposite results were obtained for experiments 6 and 9, in which the increase in the BC of 50% for 77% increased mechanical strength of 4.4 ± 0.2 for 7.0 ± 0.5 MPa. The higher sintering temperature may be related to higher mechanical strength. This suggests that higher temperature enhances the mechanical strength. The maximum mechanical strength was obtained in experiment 2 (BC of 30%, SF of 15% and temperature of 1150ºC).
3.2 Permeate flow and hydraulic permeability
The average results permeate flow and hydraulic permeability are presented in Figure 4.
Permeated flow and hydraulic permeability of the experiments. Jw- water permeate flow; Jm- microalgae permeate flow; Lpa- hydraulic permeability
As shown in Figure 4, experiments 4 and 3 had the highest water permeate flow of 522.4±0.3 and 462.6±0.5 Kg·m−2·h−1, respectively. During microalgae microfiltration, a maximum flow of 114.8±0.8 Kg·m−2·h−1 was reached with the experiment 4, and a flow of 49.9±0.7 Kg·m−2·h−1 was found with the experiment 3. Although the two experiments (3 and 4) exhibited good water filtration performance, the mechanical strength of experiment 4 was almost triple the experiment 3. The superior filtering characteristics of the experiment 4 compared with the experiment 3 can be explained by the structural changes related to higher sintering temperature and higher BC.
The comparison of the experiments 2 and 4 verified that the increase in the BC of 30% for 70% increased the water permeate flow of 202.9±0.7 for 522.4±0.3 Kg·m−2·h−1 and microalgae permeate flow of 47.7±0.2 for 114.8±0.8 Kg·m−2·h−1. These responses indicated that TC strongly influenced the microfiltration process. These results are within the range of values reported by other authors in literature [44 ZHANG, X., HU, Q., SOMMERFELD, M., PURUHITO, E., et al., “Harvesting algal biomass for biofuels using ultrafiltration membranes”, Bioresource Technology, v. 101, pp. 5297-5304, Jul. 2010., 1313 BHAVE, R., KURITZ, T., POWELL, L., et al., “Membrane-based energy eficient dewatering of microalgae in biofuels production and recovery of value added co-products”, Environmental Science & Technology, v. 46, pp. 5599-5606, Apr. 2012., 1414 GERARDO, M. L., OATLEY-RADCLIFFE, D. L., LOVITT, R. W., “Minimizing the Energy Requirement of Dewatering Scenedesmus sp. by Microfiltration: Performance, Costs, and Feasibility”, Environmental Science & Technology, v. 48, pp. 845-853, Dec. 2014.]. These experiments (1-7) exhibited a retention above 99.5%. TR was calculated using Eq. (4).
Compared with other experiments, experiment 8 was sintered at a low temperature (872 °C). This membrane did not withstand the filtration process and even broke. Although the membrane in experiment 9 was sintered at 1075 °C, it also ruptured during filtration.
Henriques et al. 2017 [77 HENRIQUES, J.D. O., PEDRASSANI, M.W., KLITZKE, W., et al., “Thermal treatment of clay-based ceramic membranes for microfiltration of Acutodesmus obliquus”, Applied Clay Science, v. 150, pp. 217–224, Dec. 2017.], previously have verified that membranes containing only TC possess higher hydraulic permeability and permeate flow values than those containing only NC. However, TC membranes have low mechanical strength (4.34 MPa). Thus, it can be proved that the TC-NC mixture significantly increases mechanical strength without compromising the filtering characteristics.
To verify the reason for the increase in mechanical strength, XRF, XRD and SEM analysis of the experiments 2, 3, 4, 6 and 9 were evaluated.
3.3 XRF analysis
The quantitative compositions of the clay and experiments as oxide were determined by XRF analysis and are presented in Figure 5.
Figure 5 shows that the clays and experiments 2, 3, 4, 6, and 9 were mainly composed of SiO2 and Al2O3, as well as other oxides in small amounts. These oxides are characteristic components of clay minerals. The loss on ignition at 1000 °C during 2 h was due to the loss of water and organic matter, compared with other experiments, experiment 3 had the highest loss on ignition. This loss may be due to higher NC in its composition. The compositions of CaO (4.6 wt%) and MgO (4.1 wt%) in experiment 4 were higher than those in other experiments (experiments 2, 3, 6, and 9).
3.4 XRD analysis
The clays and membranes were analyzed by XRD to identify the crystalline and amorphous phases. The XRD patterns of NC and TC (Figure 6) contain more expressive crystalline reflections that indicate quartz, Kaolinite, Calcite, Dolomite, Talc and Anatase, in addition to the alkali feldspar phase that is identified only in the TC sample.
The thermal treatment in NC provided a possible phase change of kaolinite (Al2Si2O5(OH)4) in metakaolinite, observed as a decrease in the reflection intensity related to kaolinite (Figure 6). The diffraction peaks of Kaolinite become less intense, thus indicating the progress of the dihydroxylation reaction and, consequently, the kaolinite is transformed into amorphous metakaolinite [1515 GASPARINI, E., TARANTINO, S.C., GHIGNA, P., RICCARDI, M.P., CEDILLO-GONZALEZ, E.I., SILIGARDI, ZEMA, C., M., “Thermal dehydroxylation of kaolinite under isothermal conditions”, Applied Clay Science, v. 80–81, pp. 417–425, Aug. 2013.].
The XRD patterns of experiments 2, 3, 4, 6 e 9 (Figure 7) contain more expressive crystalline reflections that indicate mullite, albite and quartz, in addition to the cristobalite phase that is identified only in the experiments 2 and 4.
The higher mechanical strength of the experiments 2 and 4 was possibly due to the sintering temperature, providing similarity in many of their reflections coinciding. The onset crystallization temperature of cristobalite was near 1150°C. Tao et al [1616 TAO, X., ZHANG, L., MA, X., XU, X., GUO, A., HOU, F., LIU, J., “Preparation of a flexible high emissivity coating on quartz fiber fabric for thermal protection”, Ceramic International, v. 43, pp. 14292–14300, Nov. 2017.], obtained the onset crystallization temperature of cristobalite near of 1100°C, and the peak intensity of cristobalite became higher as calcination temperature increased. The decrease in the reflection intensity was slightly greater for experiment 2 than that for experiment 4, indicating more disruption of the crystalline structure that may be associated the metakaolinite. The XRD results for experiments 3, 6, and 9 were strongly similar, with a large part of their peaks coinciding. The experiment 3 had a lower incidence of mullite phase, due to the sintering temperature (1000ºC).
3.5 XRD SEM of 2, 3, 4, 6 e 9 experiments
The morphologies of the clays and the membranes were evaluated by SEM as shown in Figure 8. The structures of the membranes were characterized by different pore shapes and sizes and a relatively complex pore distribution.
SEM micrographs of a) Experiment 2, b) Experiment 3, c) Experiment 4, d) Experiment 6 and e) Experiment 9 at magnifications of 5000x.
A larger number of pores were seen in the micrographs of the experiments 2 and 4 compared with those of the experiments 3, 4, 6 and 9. The higher agglomeration of the experiment 2 may be associated with the organic matter contained in the NC, and the greater particle dispersion may have been due to the thermally treatment and temperature applied to the experiments 2 and 4. These observations suggested that the experiment 4 had a higher porosity and the experiment 2 has a higher mechanical strength.
3.6 Mercury intrusion method for experiment 4
Figure 9 shows the cumulative volume as a function of pore size for experiment 4. There was an initial increase in the cumulative volume followed by a constant region of intrusion. Due to the presence of larger pores, the total pore volume was greater. According Henriques et al. 2017 [77 HENRIQUES, J.D. O., PEDRASSANI, M.W., KLITZKE, W., et al., “Thermal treatment of clay-based ceramic membranes for microfiltration of Acutodesmus obliquus”, Applied Clay Science, v. 150, pp. 217–224, Dec. 2017.], the cumulative volume was by approximately 45% with the thermal treatment clay (TC). The mixtures (TC/NC) of the clays caused an increase in the cumulative volume of the membrane by approximately 35%.
4. CONCLUSION
Tubular ceramic membranes were effectively fabricated by the extrusion of NC- TC mixtures. The results showed that the experiment 4 made with BC of 70%, SF of 15% and 1150ºC had higher water and microalga permeate fluxes and mechanical strength of 15.1±0.2 MPa. The higher sintering temperature may be related to higher mechanical strength. A maximized water permeate flow of 522.4±0.3 kg·m−2·h−1 was obtained. The better filtration performance of the experiment 4 can be explained by the addition of TC observed through several analyses. These results indicate that the experiment 4 may be used to recover A. obliquus microalgae by microfiltration.
ACKNOWLEDGEMENTS
The authors acknowledge with gratitude the support of the Brazilian National Council of Scientific and Technological Development - CNPq Project 454669/2014-3. They also thank the Federal University of Paraná (UFPR) and Technology Sector from UFPR for infrastructural support. LAMIR and CME of the Federal University of Paraná (UFPR) for analytics support.
BIBLIOGRAPHY
-
1CHISTI, Y., “Biodiesel from microalgae”, Biotechnology Advances, v. 25, pp. 294-306, May. 2007.
-
2MATA, T. M., MARTINS, A. A., CAETANO, N. S., “Microalgae for biodiesel production and other applications: A review”, Renewable and Sustainable Energy Reviews, v. 14, pp. 217-232, Jan. 2010.
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3BRENNAN, L., OWENDE, P., “Biofuels from microalgae - A review of technologies for production, processing, and extractions of biofuels and co-products”, Renewable and Sustainable Energy Reviews, v.14, pp. 557-577, Feb. 2010.
-
4ZHANG, X., HU, Q., SOMMERFELD, M., PURUHITO, E., et al, “Harvesting algal biomass for biofuels using ultrafiltration membranes”, Bioresource Technology, v. 101, pp. 5297-5304, Jul. 2010.
-
5ZOU, S., GU, Y., XIAO, D., et al, “The role of physical and chemical parameters on forward osmosis membrane fouling during algae separation”, Journal of Membrane Science, v. 366, pp.356–362, Jan. 2011.
-
6KUMAR, R. V., GHOSHAL, A. K., PUGAZHENTHI, G., “Elaboration of novel tubular ceramic membrane from inexpensive raw materials by extrusion method and its performance in microfiltration of synthetic oily wastewater treatment”, Journal of Membrane Science, v. 490, pp. 92-102, Sep. 2015.
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7HENRIQUES, J.D. O., PEDRASSANI, M.W., KLITZKE, W., et al, “Thermal treatment of clay-based ceramic membranes for microfiltration of Acutodesmus obliquus”, Applied Clay Science, v. 150, pp. 217–224, Dec. 2017.
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8LORENTE-AYZA, M. M., ORTS, M. J., PÉREZ-HERRANZ, V., MESTRE, S., “Role of starch characteristics in the properties of low-cost ceramic membranes”, Journal of the European Ceramic Society, v.35, pp. 2333-2341, Aug. 2015.
-
9CASTELEIN, O., SOULESTIN, B., BONNET, J.P., et al, “The influence of heating rate on the thermal behaviour and mullite formation from a kaolin raw material”, Ceramic International, v. 27, pp. 517–522, 2001.
-
10BILAD, M. R., VANDAMME, D., FOUBERT. I., et al, “Harvesting microalgal biomass using submerged microfiltration membranes”, Bioresource Technology, v. 111, pp. 343–352, May. 2012.
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11NANDI, B.K., UPPALURI, R., PURKAIT, M.K., “Preparation and characterization of low cost ceramic membranes for micro-filtration applications”, Applied Clay Science, v. 42, pp. 102–110, Dec. 2008.
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12BELIBI, P.B., NGUEMTCHOUIN, M.M.G., RIVALLIN, M., et al, “Microfiltration ceramic membranes from local Cameroonian clay applicable to water treatment”, Ceramic International, v. 41, pp. 2752–2759, Oct. 2015.
-
13BHAVE, R., KURITZ, T., POWELL, L., et al, “Membrane-based energy eficient dewatering of microalgae in biofuels production and recovery of value added co-products”, Environmental Science & Technology, v. 46, pp. 5599-5606, Apr. 2012.
-
14GERARDO, M. L., OATLEY-RADCLIFFE, D. L., LOVITT, R. W., “Minimizing the Energy Requirement of Dewatering Scenedesmus sp. by Microfiltration: Performance, Costs, and Feasibility”, Environmental Science & Technology, v. 48, pp. 845-853, Dec. 2014.
-
15GASPARINI, E., TARANTINO, S.C., GHIGNA, P., RICCARDI, M.P., CEDILLO-GONZALEZ, E.I., SILIGARDI, ZEMA, C., M., “Thermal dehydroxylation of kaolinite under isothermal conditions”, Applied Clay Science, v. 80–81, pp. 417–425, Aug. 2013.
-
16TAO, X., ZHANG, L., MA, X., XU, X., GUO, A., HOU, F., LIU, J., “Preparation of a flexible high emissivity coating on quartz fiber fabric for thermal protection”, Ceramic International, v. 43, pp. 14292–14300, Nov. 2017.
Publication Dates
-
Publication in this collection
25 Nov 2019 -
Date of issue
2019
History
-
Received
28 Mar 2018 -
Accepted
07 May 2018