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Química Nova

versión impresa ISSN 0100-4042versión On-line ISSN 1678-7064


RICHTER, Eduardo M. et al. Electroanalytical applications of silver electrodes built from recordable CDs. Quím. Nova [online]. 2003, vol.26, n.6, pp.839-843. ISSN 0100-4042.

This paper presents a new way for the construction of silver electrodes utilizing recordable CDs. The new electrodes were explored for the quantification of chloride (by potentiometry/FIA), cyanide (by amperometry/FIA) and for lead analysis (by square wave voltammetry). For the flowing measurements, a digital multimeter, connected to a microcomputer (via RS 232 interface) was used to collect directly the potential signal (for Cl- measurements) or to take the output signal from a potentiostat (for CN- measurements). The square wave voltammetry analysis was performed in a commercial instrument. The results shown good performance of the new electrodes and the detection limit (s/n = 3) attained for these three analytes were: 0.2, 50, and 200 µg L-1 for Pb2+, Cl-, and CN- respectively.

Palabras clave : silver CD-R electrodes; interfaced multimeter; electroanalysis.

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