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versão impressa ISSN 0100-4042versão On-line ISSN 1678-7064
SOUZA, Tomaz Alves de; MATTA, Marcia Helena de Rizzo da; MONTAGNER, Émerson e ABREU, Adley Bergson Gonçalves de. Study of recovery and stability of derivatized gliphosate and AMPA in soil using national resins. Quím. Nova [online]. 2006, vol.29, n.6, pp.1372-1376. ISSN 0100-4042. http://dx.doi.org/10.1590/S0100-40422006000600037.
In the present paper we studied the recoveries of glyphosate, N-(phosphonomethyl)glycine (GLY) and its major metabolite, (aminomethyl)phosphonic acid (AMPA) in soil using national (Brazilian) ion-exchange resins, derivatization by a mixture of trifluoroacetic anhydride and trifluoroethanol and analyses by GC-MS. The quantification limits were 12 ng.g-1 for both compounds and the methodology showed a range of recuperation from 85 to 94% with coefficients of variation (CV) ranging from 4.07 to 6.91% for GLY. For AMPA, the mean recoveries ranged from 87 to 102% with CVs ranging from 5.81 to 6.99%. Additional studies showed that, due to the instability of the derivatized compounds, they must be analysed keeping constant time between derivatization and analysis, preferably less than 24 h.
Palavras-chave : glyphosate; AMPA; GC/MS.