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Química Nova

Print version ISSN 0100-4042On-line version ISSN 1678-7064

Abstract

BOECHAT, Núbia; PINTO, Angelo da Cunha  and  BASTOS, Mônica Macedo. SELECTIVE FLUORINATION METHODS OF ORGANIC MOLECULES. Quím. Nova [online]. 2015, vol.38, n.10, pp.1323-1338. ISSN 1678-7064.  https://doi.org/10.5935/0100-4042.20150140.

Presently, the world depends on a wide variety of new materials based on organofluorine compounds. These compounds can be used as surfactants, high resistance polymers, liquid crystals, agrochemicals, radiopharmaceuticals for positron emission tomography, and drugs. However, the selective formation of C–F bonds remains a challenge. This study reviews our knowledge of organofluorine compounds and describes conventional and modern selective fluorination methods for obtaining these compounds. Here, we highlight the most common fluorination reagents and describe the fluorination reactions. This review is organized by the type of fluorine transfer: nucleophilic, electrophilic, and enzymatic

Keywords : fluorine chemistry; organofluorine; electrophilic fluorination; nucleophilic fluorination.

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