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Química Nova

Print version ISSN 0100-4042On-line version ISSN 1678-7064

Abstract

LV, Yongjun. SPECTROSCOPIC STUDY OF EFFECTS OF TETRAALKYLAMMONIUM CATIONS ON F--SENSING PROPERTIES OF CALIX[4]PYRROLE BORADIAZAINDACENE DYE. Quím. Nova [online]. 2016, vol.39, n.7, pp.832-835. ISSN 1678-7064.  http://dx.doi.org/10.5935/0100-4042.20160091.

A novel meso-tetracyclohexylcalix[4]pyrrole-based boradiazaindacene dye 3 was synthesized and characterized. F--binding properties of the dye in the presence of tetrabutylammonium (TBA+), tetraethylammonium (TEA+), and tetramethylammonium (TMA+) counter ions were investigated by UV-Vis, fluorescence, and NMR spectroscopies. Dye 3 displayed various degrees of absorption red shift, fluorescence quenching, and downfield shifts of NH signals for the three fluoride salts. The association constants of these salts mainly depend on cation size effects and ion-pairing effects and were in the order KTMA+ > KTEA+ > KTBA+. Thus, we speculate that both F- and tetraalkylammonium cations are concomitantly located above and below a bowl-shaped calix[4]pyrrole cup in an ion-paired complex, respectively.

Keywords : calix[4]pyrrole; sensing; spectroscopy; cation size effect.

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