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Eclética Química

Print version ISSN 0100-4670

Abstract

ARENAS, L. T. et al. A water soluble 3-n-propyl-1-azonia-4-azabicyclo[2.2.2]octanechloride silsesquioxane grafted onto Al/SiO2 surface: chromium adsorption study. Eclet. Quím. [online]. 2006, vol.31, n.2, pp. 53-58. ISSN 0100-4670.  http://dx.doi.org/10.1590/S0100-46702006000200008.

The water soluble material, 3-n-propyl-1-azonia-4-azabicyclo[2.2.2]octanechloride silsesquioxane (dabcosil silsesquioxane) was obtained. The dabcosil silsesquioxane was grafted onto a silica surface, previously modified with aluminum oxide. The resulting solid, dabcosil-Al/SiO2, presents 0.15 mmol of dabco groups per gram of material. The product of the grafting reaction was analyzed by infrared spectroscopy and N2 adsorption-desorption isotherms. The dabcosil-Al/SiO2 material was used as sorbent for chromium (VI) adsorption in aqueous solution.

Keywords : dabco; sol-gel; chromium (VI).

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