1 |
18.036 |
5.23 |
136 |
– |
41(50) 69(100) 78, 81(20) 93(90) 107(25) 119(50) 135(80) 136 (trace) |
C10H16
|
Polzin and Rorrer (2003)Polzin, J.P., Rorrer, G.L., 2003. Halogenated monoterpene production by microplantlets of the marine red alga Ochtodes secundiramea within an airlift photobioreactor under nutrient medium perfusion. Biotechnol. Bioeng. 82, 415-428.
|
2 |
30.913 |
11.41 |
229; 230 |
149 (M+−Br) |
41(40) 53(40) 79(70) 91(100) 105 (95) 122(85) 133(55) 149(80) 185(30) 229, 230(70) |
C10H15OBr |
Paul et al. (1980)Paul, V.J., McConnell, O.J., Fenical, W., 1980. Cyclic monoterpenoid feeding deterrents from the red marine alga Ochtodes crockeri. J. Org. Chem. 45, 3401-3407.
|
3 |
31.636 |
2.82 |
292; 294; 296 |
213(M+−Br) 133(M+ -Br2) |
41(15) 65(15) 77(20) 93(50) 105(40) 118(50) 133(100) |
C10H14Br2
|
Barahona and Rorrer (2003)Barahona, L.F., Rorrer, G.L., 2003. Isolation of halogenated monoterpenes from bioreactor-cultured microplantlets of the macrophytic red algae Ochtodes secundiramea and Portieria hornemannii. J. Nat. Prod. 66, 743-751.
|
4 |
36.215 |
3.09 |
248; 249; 251 |
214(M+−Cl) 167(M+−Br) 133 (M+−BrCl) |
44(60) 51(10) 65(20) 77(30) 93(100) 105(40) 117(60) 133(60)167 169(20) 212 213(5) |
C10H14BrCl |
Burreson et al. (1975)Burreson, B.J., Woolard, F.X., Moore, R.M., 1975. Evidence for the biogenesis of halogenated myrcenes from the red alga Chondrococcus hornemanii. Chem. Lett. 4, 1111-1114.
|
5 |
39.856 |
13.82 |
311 |
229(M+−Br) 149 (M+−Br2) |
41(50) 55 (50) 65(40) 79(80) 91(100) 105(40) 118(60) 133(95) 149(25) 229(20) |
C10H12OBr2
|
Paul et al. (1980)Paul, V.J., McConnell, O.J., Fenical, W., 1980. Cyclic monoterpenoid feeding deterrents from the red marine alga Ochtodes crockeri. J. Org. Chem. 45, 3401-3407.
|
6 |
40.682 |
5.81 |
323;325 |
217 (M+−BrCl) 167 (M+−Br2) 133(M+−Br2Cl) |
41(40) 65(30) 77(50) 93(95) 105(50) 117(60) 133(100) 167(40) 217(40) |
C10H13Br2Cl |
Polzin et al. (2003)Polzin, J.J., Rorrer, G.L., Cheney, D.P., 2003. Metabolic flux analysis of halogenated monoterpene biosynthesis in microplantlets of the macrophytic red alga Ochtodes secundiramea. Biomol. Eng. 20, 205-215.
|
7 |
43.298 |
13.81 |
408; 410 |
375 (M+−Cl) 329 (M+−Br) 249 (M+−Br2) 167(M+−Br3) 133 (M+−Br3Cl) |
41(10) 77(40) 91(50) 105(30) 117(50) 133(100) 167 197 213 249 294 329 375 (5) |
C10H14Br3Cl |
Gerwick, 1984Gerwick, W.H., 1984. 2-Chloro-1,6 (S*),8-tribromo-3-(8) (Z)-ochtodene: a metabolite of the tropical red seaweed Ochtodes secundiramea. Phytochemistry 23, 1323-1324.
|
8 |
45.273 |
30.13 |
328; 330; 332 |
294 (M+−BrCl) 249 (M+−Br) 213 (M+−BrCl) 167 (M+−Br2) 133 (M+−Br2Cl) |
69(15) 77(40) 93(50) 105(40) 133(100) 167(50) 213(5) 249(5) 294(3) |
C10H15Br2Cl |
Coll and Wright (1987)Coll, J.C., Wright, A.D., 1987. Tropical marine algae. I. New halogenated monoterpenes from Chondrococcus hornemannii (Rhodophyta, Gigartinales, Rhizophyllidaceae). Aust. J. Chem. 40, 1893-1900.
|
9 |
46.900 |
2.52 |
344; 346; 348 |
310 (M+−Cl) 267 (M+−Br) 229 (M+−BrCl) 185(M+−Br2) 147 (M+−Br2Cl) |
65(20) 77(30) 91(100) 105(40) 117(60) 133(60); 147(15) 185, 187 (20) 197, 199(5) 212, 213(5) 229(10); 267 269(5) 285 287 (5); 310 311(5) |
C10H15Br2ClO |
Naylor et al. (1983)Naylor, S., Hanke, F.J., Manes, L.V., Crews, P., 1983. Chemical and biological aspects of marine monoterpenes. Fortschritte der Chemie Organischer Naturstoffe/Prog. Chem. Org. Nat. Prod. 44, 189-241.
|
10 |
47.972 |
18.36 |
360; 362; 364 |
329 (M+−Cl) 294(M+−Cl2) 284 (M+−Br2) 247 (M+−BrCl) 213 (M+−BrCl2) 167 (M+−Br2Cl) 133 (M+−Br2Cl2) |
77(40) 91(50) 105 (30) 117(50) 133(100) 167(80) 213(40) 247(15) 284(20) 294(15) 329 (5) |
C10H14Br2Cl2
|
Coll et al. (1988)Coll, J.C., Skelton, B.W., White, A.H., Wright, A.D., 1988. Tropical marine algae. II. The structure determination of new halogenated monoterpenes from Plocamium hamatum (Rhodophyta, Gigartinales, Plocamiaceae). Aust. J. Chem. 41, 1743-1753.
|