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Article • J. Braz. Chem. Soc. 8 (5) • 1997 • https://doi.org/10.1590/S0103-50531997000500014   copy

Synthesis of a new phenolate-1-methylimidazole hexadentate ligand and the crystal structure of its first vanadyl complex

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The synthesis and X-ray crystal structure of OV IV(Hbbimen)PF6.2H2O H2bbimen = N,N-bis(2-hydroxybenzyl)-N,N-bis (1-methylimidazole-2-yl-methyl) ethylenediamine are reported as a rare V IV O2+ complex containing phenolate and 1-methylimidazole coordinated simultaneously to the metal center.

imidazole-phenolate; VO2+ complex; crystal structure

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