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Communication • J. Braz. Chem. Soc. 12 (5) • Oct 2001 • https://doi.org/10.1590/S0103-50532001000500005   copy

1,5-Induction in reactions between 2-alkoxy-(2-tributylstannylethylidene)cyclohexanes and aldehydes

Authorship SCIMAGO INSTITUTIONS RANKINGS

2-Methoxy(2-tributylstannylethylidene)cyclohexane 16 undergoes stereoselective transmetalation on treatment with tin(IV) chloride to generate the allyltin trichloride 19 which reacts with aldehydes to give the (Z)-(3-hydroxyalkylidene)-2-methoxycyclohexanes 17a-g with excellent 1,5-stereocontrol.

allylstannane; stereocontrol

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