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Journal of the Brazilian Chemical Society

versión impresa ISSN 0103-5053

Resumen

SANTOS, Cláudio C. dos; LIMA, Mary Anne S.; BRAZ FILHO, Raimundo  y  SILVEIRA, Edilberto R.. Diterpenes from Erythroxylum barbatum. J. Braz. Chem. Soc. [online]. 2006, vol.17, n.7, pp. 1304-1308. ISSN 0103-5053.  http://dx.doi.org/10.1590/S0103-50532006000700016.

Two new diterpenes ent-rosan-1-one-5a,15x,16-triol (1) and ent-11a-acetoxy-devadarane-15x,16-diol (2) were isolated from roots of Erythroxylum barbatum, in addition to the known diterpenes ent-devadarane-15x,16-diol (erythroxydiol X, 3) and procesterol. Investigation of the trunk heartwood furnished the ent-devadarane-11a,15x,16-triol (erythroxytriol Q, 4), ent-devadarane-7b,15x,16-triol (hydroxydevadarool, 5), b-sitosterol and its glucoside. Structural characterization, including the relative stereochemistry of all compounds, was established on the basis of spectroscopic methods, particularly 1D and 2D NMR, and comparison with data from literature.

Palabras llave : Erythroxylum barbatum; diterpenes; ent-rosan-1-one-5a,15x,16-triol; ent-11a-acetoxy-devadarane-15x,16-diol.

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