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Journal of the Brazilian Chemical Society

versión On-line ISSN 1678-4790


NAHAR, L.; TURNER, A. B.  y  SARKER, S. D.. Synthesis of hydroxy acids of dinorcholane and 5β-cholane. J. Braz. Chem. Soc. [online]. 2009, vol.20, n.1, pp. 88-92. ISSN 1678-4790.

A diastereomeric mixture (55:45) of 3-oxo-23,24-dinorchol-4-en-22-hydroxy acids (4A and 4B) was synthesized from 3-oxo-23,24-dinorchol-4-en-22-al (1) in 3 steps. Similarly, 3-oxo-5β-cholane-24-hydroxy acid (9) was synthesized from 5β-cholane-3α,24-diol (5) in 4 steps. Full spectroscopic data for these compounds are presented.

Palabras clave : 3-oxo-23,24-dinorchol-4-en-22-al; 3-oxo-5β-cholane-24-al; cyanohydrin silyl ether; hydroxy acid; NMR.

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