In the present work, an automatic procedure for turbidimetric determination of sulfate in rainwater, based on the multicommuted flow analysis approach, is proposed. The photometer set-up was developed at the laboratory, and includes: a LED (λ = 420 nm), a long pathlength flow cell (100 mm), and a photodiode. A preconcentration step is included in order to improve sensitivity. After establishing the adequate operational conditions, the proposed procedure presented the following useful features: a linear response ranging from 0.1 mg L-1 up to 2.0 mg L-1 sulfate, a detection limit (3σ criterion) of 0.04 mg L-1 sulfate, a relative standard deviation of 1.5% for 0.5 mg L-1 sulfate solution (n = 7), barium chloride consumptions of 17.0 mg per determination, and waste generation of 7.3 mL per determination. Accuracy assessment was achieved by applying the paired t-test between results obtained using the proposed procedure and ICP-OES and showed that there is no significant difference at 95% confidence level.
sulfate; turbidimetry; multicommuted flow analysis; LED-based photometer; ion exchange resin; rainwater
