kp
|
4.226×107exp(-3910/T) |
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
ki
|
1.63×106exp(-12020/T) |
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
ktherm
|
2.19×105exp(-13800/T) |
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
kdim
|
188.97exp(-1947/T) |
Belincanta-Ximenes et al.[2626 Belincanta-Ximenes, J., Mesa, P. V. R., Lona, L. M. F., Vivaldo-Lima, E., McManus, N. T., & Penlidis, A. (2007). Simulation of styrene polymerization by monomolecular and bimolecular nitroxide-mediated radical processes over a range of reaction conditions. Macromolecular Theory and Simulations, 16(2), 194-208. http://dx.doi.org/10.1002/mats.200600063. http://dx.doi.org/10.1002/mats.200600063...
]
|
ka
|
8.06×105exp(-4694,51/T) |
Seeliger and Matyjaszewski[2727 Seeliger, F., & Matyjaszewski, K. (2009). Temperature effect on activation rate constants in ATRP: new mechanistic insights into the activation process. Macromolecules, 42(16), 6050-6055. http://dx.doi.org/10.1021/ma9010507. http://dx.doi.org/10.1021/ma9010507...
]
|
kda
|
3.860×109exp(-2245/T) |
Matyjaszewski[2828 Matyjaszewski, K., Paik, H., Zhou, P., & Diamanti, S. J. (2001). Determination of activation and deactivation rate constants of model compounds in atom transfer radical polymerization 1. Macromolecules, 34(15), 5125-5131. http://dx.doi.org/10.1021/ma010185+. http://dx.doi.org/10.1021/ma010185+...
]
|
kt0
|
3.820×109exp(-958/T) |
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
kt
|
kt0×exp(-2×(A1X + A2X[2] + A3X[3])) |
Hui and Hamielec[2929 Hui, A. W., & Hamielec, A. E. (1972). Thermal polymerization of styrene at high conversions and temperatures. an experimental study. Journal of Applied Polymer Science, 16(3), 749-769. http://dx.doi.org/10.1002/app.1972.070160319. http://dx.doi.org/10.1002/app.1972.07016...
]
|
ktc
|
0.99kt
|
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
ktd
|
0.01kt
|
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
kt,p
|
109
|
Fischer and Paul[3030 Fischer, H., & Paul, H. (1987). Rate constants for some prototype radical reactions in liquids by kinetic electron spin resonance. Accounts of Chemical Research, 20(5), 200-206. http://dx.doi.org/10.1021/ar00137a007. http://dx.doi.org/10.1021/ar00137a007...
]
|
ktr,M
|
2.310×106exp(-6377/T) |
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
ktr,D
|
150 |
Fu et al.[2525 Fu, Y., Mirzaei, A., Cunningham, M. F., & Hutchinson, R. A. (2017). Atom-transfer radical batch and semibatch polymerization of styrene. Macromolecular Reaction Engineering, 1(4), 425-439. http://dx.doi.org/10.1002/mren.200700010. http://dx.doi.org/10.1002/mren.200700010...
]
|
A1
|
2.57 - (5.05×10-3T) |
Hui and Hamielec[2929 Hui, A. W., & Hamielec, A. E. (1972). Thermal polymerization of styrene at high conversions and temperatures. an experimental study. Journal of Applied Polymer Science, 16(3), 749-769. http://dx.doi.org/10.1002/app.1972.070160319. http://dx.doi.org/10.1002/app.1972.07016...
]
|
A2
|
9.56 - (1.76×10-2T) |
Hui and Hamielec[2929 Hui, A. W., & Hamielec, A. E. (1972). Thermal polymerization of styrene at high conversions and temperatures. an experimental study. Journal of Applied Polymer Science, 16(3), 749-769. http://dx.doi.org/10.1002/app.1972.070160319. http://dx.doi.org/10.1002/app.1972.07016...
]
|
A3
|
-3.03 + (7.85×10-3T) |
Hui and Hamielec[2929 Hui, A. W., & Hamielec, A. E. (1972). Thermal polymerization of styrene at high conversions and temperatures. an experimental study. Journal of Applied Polymer Science, 16(3), 749-769. http://dx.doi.org/10.1002/app.1972.070160319. http://dx.doi.org/10.1002/app.1972.07016...
]
|