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Polímeros

versão impressa ISSN 0104-1428versão On-line ISSN 1678-5169

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KUNST, Sandra Raquel et al. Effect of concentrations of plasticizers on the sol-gel properties developed from alkoxides precursors. Polímeros [online]. 2017, vol.27, n.4, pp.346-352. ISSN 0104-1428.  https://doi.org/10.1590/0104-1428.12916.

Coatings developed through sol-gel method is presented as an interesting replacement to chromium coating. Sol-gel method present advantages as high purity and excellent distribution of the components. The objective of this work is to synthesize and characterize a film obtained by sol-gel route. The film was prepared with 3-(trimethoxysilylpropyl) methacrylate (TMSPMA), tetraethoxysilane (TEOS) and cerium nitrate, using water and ethanol as solvents. Polyethyleneglycol (PEG) plasticizer was added at four different concentrations. The sol was characterized by techniques of viscosity, thermogravimetric analysis (TGA), X-ray diffraction (XRD) nuclear magnetic resonance spectroscopy (NMR) and Fourier transform infrared spectroscopy (FT-IR). The results showed that tetrafunctional alkoxides condensation was retarded by the plasticizer, forming a compact film. The film with 20 g.L-1 of PEG showed the best electrochemical behavior.

Palavras-chave : sol-gel; hybrid film; TEOS; TMSPMA; PEG.

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