SciELO - Scientific Electronic Library Online

 
vol.9 número6Kinetic Analysis of the Gas-Phase Reactions of Methyl Vinyl Ketone with the OH Radical in the Presence of NOxA Chemoenzymatic Synthesis of the Sex Pheromone of Lasioderma serricorne F. índice de autoresíndice de materiabúsqueda de artículos
Home Pagelista alfabética de revistas  

Servicios Personalizados

Articulo

Indicadores

Links relacionados

Compartir


Journal of the Brazilian Chemical Society

versión impresa ISSN 0103-5053

J. Braz. Chem. Soc. v.9 n.6 São Paulo nov./dic. 1998

http://dx.doi.org/10.1590/S0103-50531998000600008 

Article

 

Synthesis and Structural Characterization of [Ir4(m-CO)(CO)7{m4-h3-Ph2PC(H)C(Ph)PCBut}(m-PPh2)]: Alkyne-Phosphaalkyne Coupling and Formation of a Novel 2-phosphabutadienylphosphine Ligand

 

Maria Helena Araujoa,b, Peter B. Hitchcockb, John F. Nixon*b, and Maria D. Vargas*a

aInstituto de Química, Universidade Estadual de Campinas, C.P. 6154, 13081-970 Campinas - SP, Brazil

bSchool of Chemistry, Physics and Environmental Science, University of Sussex, Brighton, BN1 9QJ, UK

Received: August 26, 1998

 

 

A reação de [Ir4(m-H)(CO)9(Ph2PCºCPh)(m-PPh2)] 1 com PºCBut em CH2Cl2 a 35 °C por 4 h leva à formação do composto inédito [Ir4(m-CO)(CO)7{m4-h3-Ph2PC(H)C(Ph)PCBut}(m-PPh2)] 2, que contem a cadeia 2-fosfabutadienilfosfina. O composto 2 forma-se também quando [Ir4(CO)10(Ph2PCºCPh)(PPh2H)] 3 é aquecido na presença de PºCBut, em thf, a 40 °C, por 48 h. Essas duas reações também produzem pequenas quantidades de [Ir4(m-CO)(CO)7(m3-h2-HCCPh)(m-PPh2)2] 4, porque as velocidades das transformações de 1 e de 3 em 4 e das reações desses compostos com PºCBut são semelhantes. O composto 2 foi caracterizado por dados analíticos e espectroscópicos, espectrometria de massas usando fonte de FAB e experimentos de RMN de 1H, 31P, 13C, 2D 31P-1H HETCOR, diferença de nOe e DEPT que levaram à sua formulação e estabeleceram que havia ocorrido o acoplamento entre o ligante Ph2PCºCPh e o PºCBut e a migração do hidreto para o Ca do Ph2PCºCPh. Entretanto, esses dados não permitiram decidir se a clivagem da ligação P-Csp do Ph2PCºCPh havia ocorrido e nem definir o modo de interação da cadeia organofosforada. A estrutura molecular do composto 2, determinada por uma análise de difração de raios-X, mostrou que o cluster exibe um arranjo metálico na forma de uma borboleta e que a cadeia organofosforada, corretamente formulada por dados espectroscópicos, interage com o poliedro metálico através de quatro ligações s.

 

Reaction of [Ir4(m-H)(CO)9(Ph2PCºCPh)(m-PPh2)] 1 with PºCBut in CH2Cl2, at 35 °C, for 4 h yields the novel compound [Ir4(m-CO)(CO)7{m4-h3-Ph2PC(H)C(Ph)PCBut}(m-PPh2)] 2, which contains the 2-phosphabutadienylphosphine chain. Compound 2 is also formed upon thermolysis of [Ir4(CO)10(Ph2PCºCPh)(PPh2H)] 3 in the presence of PºCBut in thf, at 40 °C, for 48 h. Small amounts of [Ir4(m-CO)(CO)7(m3-h2-HCCPh)(m-PPh2)2] 4 are always obtained from both reactions, because of the competing rates of the transformations of 1 and 3 into 4 and of their reactions with PºCBut. Compound 2 was characterized by analytical and spectroscopic studies such as FAB ms, 1H, 31P, 13C, 2D 31P-1H HETCOR, nOe difference and DEPT NMR experiments, which led to its formulation and established the coupling between the coordinated Ph2PCºCPh and PºCBut and the migration of the hydride to the Ca of the Ph2PCºCPh ligand. However, it was impossible to establish unambiguously if cleavage of the P-Csp bond of the Ph2PCºCPh ligand had occurred and the mode of interaction of the organophosphorus chain. An X-ray diffraction study of compound 2 established a butterfly arrangement of iridium atoms with the new ligand interacting with the metal framework via four s bonds and the PPh2 phosphorus lone pair.

Keywords: iridium cluster, phosphaalkyne, alkyne, coupling reaction

 

 

Introduction

There are relatively few examples of alkyne-alkyne coupling reactions at polynuclear carbonyl clusters1, one example being the reaction between [Ir4(m-H)(CO)9- (Ph2PCºCPh)(m-PPh2)] and HCºCPh, which led to [Ir4(CO)7(m4-h3-PhCC(H)CCPh)(m-PPh2)3]2. The coordination chemistry of phosphaalkynes, PºCR, has been of great interest and its similarity to alkynes has been discussed previously, and various publications and reviews have been written3. Published examples of codimerization between a phosphaalkyne and an alkyne are relatively few. For example, the reaction between [Co2(Cp2)- (Me3SiCCSiMe3)] and PºCBut resulted in the desired h4-1-phosphacyclobutadiene complex [Co(Cp)(h4-PC(But)C (SiMe3)C((SiMe3)] and the reaction of [Zr(Cp2)(PMe3)(h2-PCBut)] with alkynes led to the 1-phospha-3-zircona cyclopentadiene complexes4. The only published attempt to couple similar molecules on a cluster compound involved the reaction between [Fe3(CO)9 Se(PBut)-(ButCºCH)] and PºCBut with led to the unexpected [Fe3(CO)7Se(PBut)(ButC=CH)(m3-P-C(=C=O) (But)] compound5. Although a number of 2-phosphabutadienes are known6, none have previously been obtained by the alkyne-phosphaalkyne coupling route. We recently reported that [Ir4(m-H)(CO)9(Ph2PCºCPh)(m-PPh2)] 1 containing a terminally bound diphenylphosphino-acetylene undergoes a facile rearrangement into [Ir4(m-CO)(CO)7(m3-h2-HCCPh)(m-PPh2)2] 4 which was proposed to occur via CO loss, P-Csp bond cleavage and hydride migration to the a-carbon of the acetylide fragment7. Cluster coordinated acetylides have been shown to undergo nucleophilic attack of alkynes at the a-carbon8,9 and, in an attempt to trap the proposed hydrido-acetylido intermediate in the transformation of 1 into 4, this reaction was carried out in the presence of PºCBut. We report herein the first example of a phosphaalkyne-alkyne coupling reaction in the coordination sphere of a cluster compound, and describe the synthesis and characterization of [Ir4(m-CO)(CO)7{m4-h3-Ph2PC(H) C(Ph)PCBut}(m-PPh2)] 2, which contains the 2-phosphabutadienylphosphine chain. A preliminary communication of this work has appeared elsewhere10.

 

Results and Discussion

The reaction of the orange compound [Ir4(m-H)(CO)9(Ph2PCºCPh)(m-PPh2)] 1 with PºCBut in CH2Cl2, at 35 °C, for 4 h resulted in a dark brown solution, from which the brown compound [Ir4(m-CO)(CO)7{m4-h3-Ph2PC(H)C(Ph)PCBut}(m-PPh2)] 2 was isolated in up to 48% yield, after purification by TLC, besides unreacted 1 and small amounts of [Ir4(m-CO)(CO)7(m3-h2-HCCPh)(m-PPh2)2] 4. Formation of 2 in 10% yield was also observed when [Ir4(CO)10(Ph2PCºCPh)(PPh2H)] 3 was heated with PºCBut in thf at 40 °C for 48 h. In both cases, heating for longer periods of time only resulted in additional formation of 4 and decomposition. Small amounts of compound 4 were unavoidably obtained, because of the competing rates of the two reactions illustrated in Scheme 1.

 

 

The reaction of 4 with PºCBut was also investigated. All attempts led to an immediate color change from orange to dark brown, but in situ 31P{1H} NMR showed no phosphorus signals, which indicated that the reaction had occurred, but the product underwent decomposition. Similar behavior was observed when the reaction of 4 with PR3 was investigated11.

Compound 2 was formulated on the basis of analytical and spectroscopic data discussed below. The coupling reaction between the Ph2PCCPh ligand and the PCBut molecule, and the hydride migration to the resulting new phosphorus carbon chain were established by 1H, 31P and 13C-NMR spectroscopy. In spite of the detailed spectroscopic studies undertaken, it was impossible to establish unambiguously whether the diphenylphosphino-alkyne had undergone P-Csp bond cleavage and the geometry of the metal polyhedron in 2, therefore an X-ray diffraction study had to be carried out.

Solution characterization of [Ir4(m-CO)(CO)7{m4-h3- Ph2PC(H)C(Ph)PCBut}(m-PPh2)] 2

The solution infrared spectrum of compound 2, between 2200-1600 cm-1, only showed absorptions due to terminal and bridging carbonyl ligands. This result suggested that the triple bond of the Ph2PCºCPh ligand was interacting with the metal framework, because of the absence of the nCºC band at 2172 cm-1 which is observed in both starting materials 1 and 3. In the FAB mass spectrum of 2, a molecular ion at m/z 1568 and sequential loss of eight CO ligands were observed. The mass difference between 1 and 2 clearly indicated the incorporation of one PCBut molecule and loss of a CO group, resulting in a complex having the formula "Ir4H(CO)8(Ph2PCCPh)(PPh2)(PCBut)", with which the elemental analysis agreed perfectly.

The 1H-NMR data for 2 were consistent with the presence of both PPh2 and But groups. The absence of a hydride signal and the presence of a doublet of doublets at d 5.4 (JH-P = 55 and 13 Hz) suggested that the hydride ligand had migrated to one of the carbon atoms of the Ph2PCCPh (Ca or Cb) or of the PCBut (Cg) ligands, because migration of the hydride to one of the phosphorus atoms would have led to a much larger one-bond H-P coupling constant, typically between 300 and 500 Hz12. A nOe difference experiment established to which of the ligands Ph2PCCPh or PCBut the hydride had migrated. This experiment consisted of continuous irradiation of the resonance at d 5.4 (CH), which resulted in a nOe of some of the phenyl proton resonances, but did not affect the But signal [Fig. 1a]. Likewise, when the But resonance at d 1.1 was irradiated, only nOe of some of the phenyl proton resonances was observed [Fig. 1b]. Thus, the spacial proximity of the CH and the phenyl protons indicated that migration of the hydride had occurred either to Ca or Cb of the Ph2PCCPh ligand.

 

 

The 31P{1H} NMR spectrum of 2 showed three sets of pseudo-triplets at d 16.1, 28.0 and 116.5 with JP-P = 5 Hz. The 2D 1H-31P shift correlation spectrum established that the lowest frequency peak could be assigned to the phosphorus atom of the PCBut (PA) group, and the other two resonances at higher frequency were due to the PPh2 groups (PB and PC) [Fig. 2]. This experiment also indicated that the strong P-H coupling of 55 Hz was to the PA nucleus (d 16.1), whilst the 13 Hz P-H coupling was to the PPh2 phosphorus PB (d 28.0). The signal at d 116.5 (PC), was confidently attributed to the bridging phosphido nucleus, on the basis of previous work7. The second PPh2 (PB) appeared at d 28.0 and it is indicative of a phosphine12, however the breaking of the P-Csp bond cannot be excluded, since the m-PPh2 phosphorus nuclei have been shown to span a wide chemical shift range, depending on the distance between the metal atoms they bridge12.

 

 

The coupling of the diphenylphosphinoalkyne with the phosphaalkyne was strongly suggested by the 13C{1H} and 13C-NMR spectra and a DEPT experiment. These experiments made it possible to identify the Cb (Cquat) resonance as a doublet of doublets at d 54.2, with JC-P = 37 and 28 Hz, and the Ca (CH), also as a dd, at d 126.0, JC-P = 57 and 35 Hz, and 1JC-H = 164 Hz. The chemical shifts of Ca and Cb and the P-C and C-H coupling constants are in agreement with those normally observed for sp2 hybridized carbon atoms which are coordinated to organometallic compounds13. In the 13C{1H} NMR spectrum of 2 it was possible to identify all eight CO groups and to assign the bridging CO resonance at d 191.2, which is shifted to high frequency, in comparison with the terminal CO groups14. This result was in agreement with the IR and mass spectra data and the elemental analysis. It was also possible to identify five quaternary carbons and the CH carbon atom of the phenyl groups, in the aromatic carbon region between d 141.7 and 128.3. The two Cquat resonances at d 38.5 and 29.6, were assigned to Cg and C* or vice versa.

On the basis of these results two possible structures A and B were proposed for the new 2-phosphabutadienyl chain, as shown in Scheme 2. In A the coupling between Ph2PCCPh and PCBut would have occurred without cleavage of the Ph2P-C bond, and in B cleavage would have occurred, leading to a m-PPh2 coordinated fragment. The trans-H to phospha-alkene PA arrangement would result in the large 3JH-P = 55 Hz observed.

 

 

The mode of interaction of the proposed 2-phosphabutadienyl fragments A or B to the Ir4 metal frame could only be speculated upon based on the above analytical and spectroscopic data. Because the 13C{1H} NMR data do not suggest interaction of the C=C bond with the metal frame, fragment A would be a potential 7 electron donor to the 55 electron "Ir4(CO)8(PPh2)" fragment, whereas in B it could donate 6 electrons to the 58 electron "Ir4(CO)8(PPh2)2" fragment. Compound 2 would therefore have 62 (A) or 64 (B) valence electrons and, therefore would exhibit a butterfly or a spiked triangle arrangements of metal atoms according to Wade rules15. Similar metal arrangements were previously observed for [Ir4(CO)8(h1-COPh)(m4-h3-PhPC(H)CPh)(m-PPh2)] (62 electrons)16 and [Ir4(m-H)- (CO)9(m4-h3-Ph2PCCPh)(m-PPh2)] (64 electrons) clusters.

Crystal Structure of 2

The molecular structure of 2 in the solid state is shown in Fig. 3, together with the atomic labeling scheme, and confirmed the geometry shown in A. Selected bond distances (Å) and angles (°) are in Table 1. The structure consists of a butterfly arrangement of iridium atoms with metal-metal bond mean value of 2.785 Å. This arrangement of iridium atoms was previously observed for other 62-electron Ir4 clusters for which Ir-Ir bond mean values are comparable e.g. [Ir4(CH3)(CO)8(m4-h3-Ph2PCCPh) (m-PPh2)]17, [2.773 Å], [Ir4(CO)8(m3-h3-Ph2PC(H)CPh)(m-PPh2)- (PCy3)]18, [2.749 Å] and [Ir4(CO)8(h1-COPh) (m4-h3-PhPC(H)CPh)(m-PPh2)]16, [2.788 Å]. Complex 2 possesses seven terminal CO ligands, distributed one on Ir(4) and two on each remaining Ir atoms, and one bridging carbonyl, which spans asymmetrically the shortest edge of the metal framework Ir(2)-Ir(4) [2.704(1) Å, Ir(4)-C(7) 1.95(2) and Ir(2)-C(7) 2.14(2) Å]. The Ir(1)-Ir(4) is the longest edge [2.838(1) Å] and is spanned by an asymmetric phosphido group [Ir(1)-P(3) 2.390(6) and Ir(4)-P(3) 2.265(5) Å] which donates, formally, three electrons to the cluster. The new phosphabutadienyl Ph2PC(H)C (Ph)PCBut ligand donates formally seven electrons to the cluster: two from the P(1)-C(9)=C(10) moiety which is interacting with the metal framework via the phosphorus atom lone pair of the P(1)Ph2 group [Ir(3)-P(1) 2.299(6) Å], five from the 2-phosphaalkenyl P(2)=C(11) moiety, which is essentially sp2 [P(2)=C(11) 1.70(2) Å, C(10)-P(2)=C(11) 125.3(9)° and P(2)=C(11)-C(12) 129(2)°] and interacts with all four iridium atoms via four s bonds [Ir(1)-P(2) 2.352(5), Ir(3)-P(2) 2.277(5), Ir(2)-C(11) 2.25(2) and Ir(4)-C(11) 2.05(2) Å]. The P=C and Ir-P bond distances are comparable with other complexes reported in the literature e.g. [W(CO)5-{(SiMe3)2C=P-C(OEt)=C(H)Ph}]19, [P=C 1.65(10) Å], [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]20, [P=C 1.657(8) Å], [TiCp2(Et2BH)(P=CBut)]21, [1.666(2) Å], [Ir4(CO)8(h1-COCH3)(m4-h3-Ph2P(1)CCPh)(m-PPh2)]17, [Ir-P(1) 2.307(9) Å], [Ir4(m-H)(CO)9(m4-h3-Ph2P(1)CCPh) (m-PPh2)]7, [Ir-P(1) 2.373(9) Å], [Ir4(CO)8(m3-h3-Ph2P(1)C(H)CPh)(m-PPh2)(PCy3)]18, [Ir-P(1) 2.270 Å]. A formal electron count in 2 results in 19 and 17 electrons on Ir(2) and Ir(4), respectively, and 18 electrons on the other two metal atoms. This has been previously observed for other Ir4 clusters such as [Ir4(CO)8(h1-COCH3)-(m4-h3-Ph2PCCPh)(m-PPh2)], [Ir4(CO)8(h1-CH3)(m4-h3-Ph2PCCPh)(m-PPh2)] and [Ir4(CO)8(m3-h3-Ph2P C(H)CPh) (m-PPh2)(PCy3)].

 

 

 

 

Although the X-ray diffraction study has confirmed structure A, proposed in Scheme 2 for the novel chain, it is impossible to be sure that P-C bond cleavage was not involved in the process, considering the analogous transformation of [Ru3(m-H)(CO)8(m3-h2-CCBut)(Ph2PCºCPh)] into [Ru3(CO)8{m3-h4-Ph2PC(Ph)C(H)CC(But)}]22. In this case, the alkyne-alkyne condensation and migration of the hydride ligand resulted in a new organic chain, Ph2PC(Ph)C(H)CC(But). It was suggested that a P-Ca bond cleavage had initially occurred, with formation of a m-PPh2 ligand, and after the condensation, insertion of the new carbon chain, "C(Ph)C(H)CC(But)", into the Ru-PPh2 occurred leading to the observed P-Cb(Ph); all these proposed steps had been previously observed.

No information regarding the detailed mechanism of the formation of compound 2 is available, but one can speculate the following steps: (i) CO loss and interaction of the acetylene moiety with an electron poor Ir center with a Ir-Ir bond cleavage, (ii) hydride migration to the Ca of the Ph2PCCPh ligand, and (iii) nucleophilic attack of the Cb at the d+ P of the PCBut ligand with formation of the 2-phosphabutadienylphosphine observed experimentally.

 

Experimental

General procedures

All manipulations and reactions were performed under an atmosphere of argon, unless otherwise specified, using standard Schlenk techniques. CH2Cl2 was dried over CaH2, hexane and thf over sodium wire. Solvents were freshly distilled under N2 from Na/K alloy (hexane and thf) or from CaH2 (CH2Cl2) prior to use. PºCBut, 3 [Ir4(m-H)(CO)9 (Ph2PCºCPh)(m-PPh2)]7, 1 and [Ir4(CO)10(Ph2PCºCPh) (PPh2H)]7, 3 were prepared by literature methods.

Preparative TLC was carried out in air by using ca. 2 mm thickness glass-backed silica plates (20 x 20 cm) prepared from silica gel type GF254 (Fluka) and CH2Cl2-hexane (3:7) as eluent and the compounds were extracted from silica with CH2Cl2.

IR spectra were obtained on a Bomen MB series IR instrument scanning between 2200 and 1600 cm-1, using CaF2 cells. Microanalyses were performed at the Instituto de Química, Unicamp, Brazil. Fast atom bombardment mass spectra (FAB MS) were obtained on a Kratos MS50, operating at 8 keV. Xenon was used as the source of fast atoms. 3-Nitrobenzylalcohol, purchased from Aldrich, and distilled under vacuo, was used as a matrix. CH2Cl2 was used as solvent. All m/z values are referred to 193Ir and were obtained at the University Chemical Laboratories, University of Cambridge, UK. 1H, 13C and 13P-NMR studies were carried out using CDCl3 solutions and a Bruker AMX 500 spectrometer. Standard pulse sequences were used for the NMR experiments23. Chemical shifts are given in ppm using deuterated solvents as lock and reference (1H and 13C, SiMe4; 31P 85 % H3PO4, external) and coupling constants (J) are given in Hz.

Preparation of [Ir4(CO)8{m4-h3-Ph2PC(H)C(Ph)PCBut} (m-PPh2)] 2

Method 1

An orange solution of [Ir4(m-H)(CO)9(Ph2PCºCPh)(m-PPh2)] 1 (100 mg, 0.08 mmol) and PºCBut (8 mL, 0.08 mmol) in CH2Cl2 (10 mL) was heated at 35 °C for 4 h, after which time a color change from orange to dark brown was observed. The solution was concentrated under vacuo to about 1 mL and the mixture purified by TLC to afford [Ir4(CO)8{m4-h3-Ph2PC(H)C(Ph)PCBut}(m-PPh2)] 2 (60 mg, 48%, Rf 0.30, brown), [Ir4(CO)8{m3-h2-HCCPh)(m-PPh2)2] 4 (15 mg, 12%, Rf 0.55, orange) and starting material 1 (15 mg, 15%, Rf 0.41, orange).

Method 2

To a yellow solution of [Ir4(CO)10(Ph2PCºCPh) (PPh2H)] 3 (53 mg, 0.035 mmol) in thf (10 mL) PºCBut (7 mL, 0.07 mmol) was added and the reaction mixture was heated at 40 °C for 48 h. The resulting brown solution was concentrated under vacuo to about 1 mL. Separation of the mixture by TLC afforded [Ir4(CO)8{m4-h3-Ph2PC(H)C(Ph) PCBut}(m-PPh2)] 2 (5 mg, 10%, Rf 0.58, brown), [Ir4(CO)8 {m3-h2-HCCPh)(m-PPh2)2] 4 (2 mg, 4%, Rf 0.67, orange), and unreacted 3 (27 mg, 50%, Rf 0.62, yellow), along with some decomposition products (base line on the TLC plates).

Reaction of [Ir4(CO)8{m3-h2-HCCPh)(m-PPh2)2] 4 with PºCBut

(a) To a solution of [Ir4(CO)8{m3-h2-HCCPh)- (m-PPh2)2] 4 (27 mg, 0.018 mmol) in CH2Cl2 (10 mL) was added PºCBut (5.2 mL, 0.046 mmol) and the reaction mixture heated at 35 °C for 5 h. After ca. 10 min the color of the solution slowly began to change from orange to brown and after 5 h the solution was dark brown. Purification by preparative TLC afforded unreacted starting material 4 along with decomposition on the base line of the TLC plates.

(b) A solution of 4 (70 mg, 0.047 mmol) and PºCBut (10 mL, 0.095 mmol) in benzene (20 mL) in a closed Schlenk fitted with Young tap, was heated under reflux for 4 h, a slowly color change from orange to dark brown was observed. The solvent was removed under reduced pressure and separation by preparative TLC afforded the starting material 4, along with decomposition products on the base line of the TLC plates.

Characterization of 2

Anal. Calcd. for C45H35O8P3Ir4: C, 34.5; H, 2.2. Found: C, 34.7; H, 1.9%. IR (hexane, nCO): 2068 w, 2058 w, 2030vs, 2014w (sh), 2006s, 1985w, 1956s, 1836m cm-1. FAB MS: m/z 1568 (M)+, 1540 (M- CO)+, 1512 (M- 2CO)+, 1484 (M- 3CO)+, 1456 (M- 4CO)+, 1428 (M- 5CO)+, 1400 (M- 6CO)+, 1372 (M- 7CO)+ and 1344 (M- 8CO)+. 1H NMR (500 MHz, CDCl3, 25 °C): d 1.1 (s, 9H, C(CH3)3), 5.4 (dd, 1H, JH-P 55 and 13 Hz), 6.9-7.5 (m, 25H, C6H5). 13C{1H} NMR (125.721 MHz, CDCl3, 25 °C): d 191.2 (d, JC-P 6 Hz, CO), 183.3 (d, JC-P 73 Hz, CO), 175.5 (t, JC-P 35 Hz, CO), 173.8 (d, JC-P 49 Hz, CO), 170.4 (s, CO), 168.0 (d, JC-P 25 Hz, CO), 165.8 (d, JC-P 111 Hz, CO), 161.8 (br, CO), 141.7 (d, JC-P 33 Hz, Cquat., Ph), 138.4 (d, JC-P 30 Hz, Cquat., Ph), 136.0 (d, JC-P 57 Hz, Cquat., Ph), 134.8 (dd, JC-P 21 and 8 Hz, Cquat., Ph), 133.7 (d, JC-P 13 Hz, CH, Ph), 132.6 (d, JC-P 11 Hz, CH, Ph), 132.1 (d, JC-P 13 Hz, CH, Ph), 131.7 (s, CH, Ph), 130.5 (s, CH, Ph), 130.1 (s, Cquat., Ph), 130.0 (s, CH, Ph), 129.6 (t, JC-P 8, CH, Ph), 129.1 (d, JC-P 11 Hz, CH, Ph), 128.6 (d, JC-P 12 Hz, CH, Ph), 128.3 (t, JC-P 11 Hz, CH, Ph), 126.0 (dd, JC-P 57 and 35 Hz, CH), 54.2 (dd, JC-P 37 and 28 Hz, Cquat.), 38.5 (s, Cquat.), 36.6 (d, JC-P 8 Hz, CCH3), 29.6 (s, Cquat.). 31P{1H} NMR (202.404 MHz, CDCl3, 25 °C): d 16.1 (P1, t, JP-P 5 Hz), 28.0 (P2, t, JP-P 5 Hz), 116.5 (P3, t, JP-P 5 Hz).

X-ray structure determination of 2

X-ray quality crystals were grown by slow evaporation of a very concentrated CHCl3 solution of 2. Data were collected at 293 K on an Enraf-Nonius CAD4 diffractometer. Crystal and refinement details are given in Table 2. Non-H atoms were located by heavy atom methods and the structure refined using SHELXS-8624 and refined on F2 with all reflections using SHELXS-9324. Hydrogen atoms were included in rigid mode.

 

 

Atomic coordinates, thermal parameters and a full list of bond lengths and angles have been deposited at the Cambridge Crystallographic Data Centre.

 

Acknowledgements

We acknowledge financial support from the Commission of European Communities, Conselho Nacional de Desenvolvimento Científico e Tecnológico - CNPq (M.H.A, M.D.V) and Fundação de Amparo à Pesquisa do Estado de São Paulo - FAPESP (M.H.A). We thank Dr. Anthony G. Avent for all his help with the NMR experiments.

 

References

1.Sappa, E.; Tiripicchio, A.; Braunstein, P. Chem. Rev. 1983, 83, 203;         [ Links ]Shapley, J.R.; McAteer, C.H.; Churchill, M.R.; Biondi, L.V. Organometallics 1984, 3, 1595;         [ Links ]Riaz, V.; Curtis, M.D.; Rheingold, A.; Haggerty, B.S. Organometallics 1990, 9, 2647;         [ Links ]Matsuzaka, H.; Mizobe, Y.; Nishio, M.; Hidai, M. J. Chem. Soc., Chem. Commun. 1991, 1011.        [ Links ]

2.Pereira, R.M.S. Ph.D. Thesis, Universidade Estadual de Campinas, Brazil, 1996.        [ Links ]

3.Nixon, J.F. Chem. Rev. 1988, 88, 1327;         [ Links ]Chem. Ind. 1993, 404;         [ Links ]Coord. Chem. Rev. 1995, 145, 201;         [ Links ]Chem. Soc. Rev. 1995, 319;         [ Links ]Dillon, K.B.; Mathey, F.; Nixon, J.F. Phosphorus: The Carbon Copy 1998, Ed. John Wiley.        [ Links ]

4.Imhof, W.; Huttner, G. J. Organomet. Chem. 1993, 447, 31.        [ Links ]

5.Binger, P.; Milczarek, R.; Mynott, R.; Regitz, M. J. Organomet. Chem. 1987, 323, C35;         [ Links ]Regitz, M. In Multiple Bond and Low Coordination in Phosphorus Chemistry, Ed. Regitz, M.; Scherer, O.J., Georg Thieme Verlag, Stuttgart, 1990, Chapter 2.        [ Links ]

6.Appel, R. In Multiple Bonds and Low Coordination in Phosphorus Chemistry, Ed. Regitz, M.; Scherer, O.J., Georg Thieme Verlag, Stuttgart, 1990, Chapter 2.        [ Links ]

7.Benvenutti. M.H.A.; Vargas, M.D.; Braga, D.; Grepioni, F.; Mann, B.E.; Naylor, S. Organometallics 1993, 12, 2947 and references therein.        [ Links ]

8.Sappa, E.; Pasquinelli, G.; Tiripicchio, A.; Tiripicchio-Camellini, M. J. Chem. Soc., Soc., Dalton Trans. 1989, 601 and references therein.        [ Links ]

9.Chi, Y.; Hwang, D.-K.; Chen, S.-F.; Liu, L.-K. J. Chem. Soc., Chem. Commun. 1989, 1540;         [ Links ]Chi, Y.; Huttner, G.; Imhof, W. J. Organomet. Chem. 1990, 384, 93.        [ Links ]

10.Benvenutti, M.H.A.; Hitchcock, P.B.; Nixon, J.F.; Vargas, M.D. J. Chem. Soc., Chem. Commun. 1994, 1869.        [ Links ]

11.Araujo, M.H. Ph.D. Thesis, Universidade Estadual de Campinas, Brazil, 1995.        [ Links ]

12. Verkade, J.G.; Mosbo, J.A. in Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis, Ed. Verkade, J.G. and Quin, L.D., 1987, VHC, Chapter 13.        [ Links ]

13.Doherty, S.; Corrigan, J.F.; Carty, A.J.; Sappa, E. Adv. Organomet. Chem. 37, 39.        [ Links ]

14.Mann, B.E.; Pickup, B.T.; Smith, A.K. J. Chem. Soc., Dalton Trans. 1989, 889.        [ Links ]

15.Mingos, D.M.P.; May, A.S. In Structural and Bonding Aspects of Metal Cluster Chemistry, Shriver, D.F.; Kaesz, H.D.; Adams, R.D., eds., VHC, 1990, 16, 4833.        [ Links ]

16.Pereira, R.M.S.; Fijiwara, F.Y.; Vargas, M.D.; Braga, D.; Grepioni, F. Organometallics 1997, 16, 4833.        [ Links ]

17.Vargas, M.D.; Pereira, R.M.S.; Braga, D.; Grepioni, F. J. Chem. Soc., Chem. Commun. 1993, 1008.        [ Links ]

18.Benvenutti. M.H.A.; Vargas, M.D.; Braga, D.; Grepioni, F.; Parisini, E.; Mann, B.E. Organometallics 1993, 12, 2955, and references therein.        [ Links ]

19.Hobbold, M.; Streubel, R.; Benvenutti, M.H.A.; Hitchcock, P.B.; Nixon, J.F. Organometallics 1997, 16, 3726.        [ Links ]

20.Bedford, R.B.; Hill, A.F.; Jones, C.; White, A.J.P.; Wilton-Ely, J.D.E.T. J. Chem. Soc., Dalton Trans. 1997, 139.        [ Links ]

21.Binger, P.; Sandmeyer, F.; Krüger, C.; Jörg, K.; Goddard, R.; Erker, G. Angew. Chem. Int. Ed. Engl. 1994, 33, 197.        [ Links ]

22.Sappa, E.; Pasquinelli, G.; Tiripichio, A.; Camellini, M.T. J. Chem. Soc., Dalton Trans. 1989, 601 and references therein.        [ Links ]

23.Mann, B.E. Adv. Organomet. Chem. 1988, 28, 397 and references therein.        [ Links ]

24.Enraf-Nonius, CAD-4 Software. Version 5.0, 1989. Enraf-Nonius, The Netherlands. Sheldrick, G.M., 1985, SHELXS-86.         [ Links ]Program for the Solution of Crystal Structures. University of Gottingen Germany. Sheldrick, G.M. (1993) SHELXL-93.         [ Links ]Program for Crystal Structure Refinement. University of Gottingen, Germany.         [ Links ]Watkin, D.J. and Pearce, L.J., 1993 CAMERON. An Interactive Graphics Editor. University of Oxford, England.        [ Links ]

 

FAPESP helped in meeting the publication costs of this article