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Brazilian Journal of Physics

Print version ISSN 0103-9733

Braz. J. Phys. vol.39 no.1a São Paulo Apr. 2009

http://dx.doi.org/10.1590/S0103-97332009000200002 

Nanoparticles of metal and metal oxides: some peculiar synthesis methods, size and shape control, application to catalysts preparation

 

 

François Bozon-VerdurazI, *; Fernand FiévetI; Jean-Yves PiquemalI; Roberta BraynerI; Kaoutar El KaboussI; Yaghoub SoumareI; Guillaume ViauI; Georges ShafeevII

ILaboratoire de Physique et Chimie des Nano-Objets, INSA de Toulouse, 31077 Toulouse cedex 4
IIWave Research Center, General Physics Institute of the Russian Academy of Sciences, Moscow, Russian Federation

 

 


ABSTRACT

One step (direct) and multisteps synthesis methods of metal and oxide nanoparticles are presented including both bottom-up and top-down procedures. Chemical methods involving the polyol process allows to get either isotropic or anisotropic nanoparticles. Nanowires, nanorods and dumbells can be generated either by heterogeneous nucleation or by using a template (mesoporous silica). Top-down procedures are illustrated by laser irradiation of immersed bulk targets (Ag, Au) which generates self-organized nanostructures or colloidal solutions. Laser irradiation of these colloidal solutions modifies the size distribution and the shape of nanoparticles. Bimetallic nanoparticles are generated from mixtures of monometallic colloidal solutions. Surface-mediated methods involving a host support and an invited phase are also presented. They lead to the formation of metal or oxide clusters and nanoparticles. The speciation of these entities is correlated with the observed catalytic performances.

Keywords: polyol process, laser ablation, anisotropy, cobalt, palladium, ruthenium, silver, gold.


 

 

1. INTRODUCTION

Numerous papers and books have been dedicated to the synthesis of nanomaterials and nanostructures [1,2]. The aim of the present paper is (i) to focus on some peculiar synthesis methods developed in our laboratories, pertaining either to chemical (bottom up) or to physical (top down) methods, (ii) to present their ability to control size and shape; (iii) to show some applications related to catalysts preparation. For conciseness, the cited references are not exhaustive and have been mainly chosen to illustrate the synthesis methods presented below, dedicated to the genesis of metal and oxide nanoparticles. Most examples will concern the so-called "zero-dimensional nanostructures", that are nanoparticles in the general sense (with no peculiar direction of anisotropic growth) and "one-dimensional nanostructures" called nanowires and nanorods [1,2]. Indeed, these anisotropic structures are highly interesting since they exhibit properties which differ markedly from those of isotropic nanoparticles. For example, metallic silver nanowires display two plasmon resonances which correspond to longitudinal and transverse collective electron oscillations whereas silver nanospheres only display one resonance. Moreover, the maximum of the longitudinal oscillation depends on the aspect ratio (length/width ratio) of the particle. In the same manner, it is possible to considerably increase the coercive field of ferromagnetic particles, by adding a contribution related to the shape anisotropy [3], which is of outmost importance in the design of magnets. We shall present two classes of procedures: one step (direct) and multisteps. In the latter we focus on supported nanoparticles obtained by either (i) the precursor fixation (anchoring, impregnation , exchange) on the host support, followed by its transformation into the invited phase (oxide or metal) or (ii) the creation of the invited phase in solution before its fixation (immobilization) on the support. These methods are summarized in scheme 1. For conciseness, the photodeposition (photo-assisted reduction), which concerns only semiconductors, will not be treated. Colloïdal oxide solutions (sols) can be obtained by hydrolysis of a precursor in solution - polyol process (route 1) or another one (route 2) - or by laser irradiation of a target immersed in an appropriate solvent (route 3). A supported oxide can be designed via either (i) impregnation of the support by a colloidal solution (route 4) or (ii) calcination of the supported precursor (route 5) obtained from various interaction modes between the support and the precursor solution. Colloidal metal solutions may be obtained by reduction of the precursor in solution via the polyol process (route 6) or by laser irradiation of an immersed metal target (route 7). Supported metals are designed through several pathways: (i) reduction of supported oxides (route 8); (ii) reduction of the precursor via the polyol process in a suspension containing the support (route 9); (iii) impregnation of the support by a colloidal metal solution (route 10). Finally self-organized nanostructures may be designed by laser irradiation of an immersed target (route 11). The results presented in the present work are limited to routes 2, 5, 6, 7, 11.

 

 

2. EXPERIMENTAL SECTION

2.1. Preparation methods

Detailed information concerning the routes presented in scheme 1 are available in the references cited in sections 3 and 4.

2.2. Characterization techniques

X-Ray diffraction patterns were obtained with a Panalytical X'Pert Pro diffractometer equipped with an X'celerator detector, generally in the 10°- 110° (2θ) range using Co K radiation (λ = 1.7889 Å). The data were collected at room temperature with a step of 0.017 degrees (2θ) and a time by step equal to 25 s. Transmission electron microscopy (TEM) observations were carried out with a Jeol CXII microscope operating at 100 kV. The sample powder was dispersed in ethanol, one drop of the suspension was deposited on the carbon membrane of the microscope grid and the solvent was evaporated at room temperature. High resolution transmission electron microscopy (HRTEM) was performed with a Jeol JEM 2010F UHR operating at 200 kV. UV-visible-NIR spectra by transmission and diffuse reflectance were recorded at room temperature between 190 and 2500 nm on a Varian Cary 5E spectrometer equipped with a double monochromator. The integrating sphere used for diffuse reflectance measurements was coated with polytetrafluoroethylene (PTFE) and PTFE was used as a reference. Laser ablation in the nanosecond range involved a Cu vapour laser (578 nm) and a Nd: YAG (1064 nm). The morphology of the target was characterized by an Atomic Force Microscope (AFM) operating in the tapping mode. The exposed Ag plate was characterized by specular reflectivity using an Ocean optics spectrometer in the 20-650 nm range. DC magnetic susceptibility was measured on a SQUID magnetometer in the 5 - 300 K range under a magnetic field of 200 Oe.

 

3 DIRECT METHODS FOR THE PREPARATION OF NANOPARTICLES

3.1. Reduction or hydrolysis in polyols: a versatile method to prepare fine metal or oxide particles

The polyol process, developed in our laboratory, is a soft chemistry ("chimie douce") method which allows to prepare oxide or metal nanoparticles with controlled size and shape [4,5]. The polyol acts as a solvent for the metal precursors (high permittivity), a growth medium and a complexing agent in some cases. In addition, it is also a mild reducing agent. This process permits to tune the particle size, shape, composition and structure of particles via the control of the nucleation and growth steps and, in the recent years, it has called a growing attention. With the help of various additives, surfactants (e.g. polyvinylpyrrolidone) and microwave heating, various types of nanoparticles have been synthetized [6-40]. Metals (Ni [6, 7], Co [8,9], Cu [10], Pd [11], Ag [12-14], Pt [15-17], Au, [18, 19] ), alloys [9, 19-25], oxides (MgO, TiO 2, ZnO, SnO 2, Gd 2O 3, Fe oxides and ferrites, hydroxyapatite[26-35], metal-polymer nanocomposites [36], supported metal catalysts [37-40], have been designed.

3.1.1. Isotropic particles

Briefly, the nucleation and growth steps are controlled by the temperature, the composition of the reacting medium (basicity, hydrolysis ratio), the steric (polyol, PVP) or electrostatic (adsorption of acetate ions) stabilization [4,5].

A very important parameter is the hydrolysis ratio, defined as h = nH2O/nmetal (mol/mol). Varying h allows to prepare either metal, (oxy)hydroxide or oxide nanoparticles as indicated in Figure 1 [4,5]. Indeed, for cobalt - based systems, with h = 0 (water coming from the metal precursor is continuously distilled off) leads to sub-micronic (about 0.1 µm) metal nanoparticles, whereas with h 0, either oxide or layered cobalt hydroxyacetate are generated.

 

 

3.1.2. Control of the particle shape

Anisotropic metal nanoparticles are extensively studied because of their unique properties (optical, magnetic) compared to their isotropic counterparts. For example the plasmon spectrum of spherical Ag and Au particles presents one maximum in the visible range whereas shape-anisotropy is able to induce a second maximum at higher wavelength [41]. On the other hand shape-anisotropy may reinforce the values of the coercitive field, allowing to improve significantly the hardness of magnets. Several methods based on the use of solid templates have been described for the preparation of anisotropic particles [1, 2]. For instance, anodic aluminium oxide, nuclear-etched polycarbonate membranes or mesoporous silicas have been largely used. Following this approach, we have developed a very fast and direct procedure for the obtention of metallic silver nanowires embedded in a SBA-15-type hexagonal mesoporous silica (see Figure 2a and 2b) [18]. Another strategy consisted in the use of the system Ag(NO 3)/C 12H 25SH/polyol-toluene/CH3COONa-CH3COOH. The formation of silver nanowires (see Figure 2c) was explained by the in situ precipitation of a lamellar silver thiolate, Ag(SC12H25), acting as a template for the 1D coalescence of isotropic Ag nanoparticles. Heterogeneous nucleation has also proved to be an efficient method for the control of the particle growth. Using Ruthenium as a seed (Ru is more easily reducible than cobalt or nickel), allows to get nickel-cobalt ( figure 3a) or cobalt (figure 3b) nanowires [16, 17]. Note that the addition of a heterogeneous nucleating agent is critical since without Ru, only isotropic polycrystalline sub-micronic particles are obtained (see Figure 3 c).

 



 

 



 

3.2. Niobia sols prepared by digestion in hydrazine and redispersion in ethanol

Niobia, Nb2O5, is a wide gap semiconductor (Eg = 3.4 eV). Niobia sols prepared by digestion in hydrazine and redispersion in ethanol show a marked quantum size effect ( Eg = 4.2 eV) (Figure 4) [42]. The band gap width has been calculated according to a method previously developed [43]. Briefly the band gap energy increases when the number of interconnected metal-oxygen polyedra decreases. In niobia sols, the particle size is only 4.5 nm instead of 40 nm in bulk niobia. Hence, the pronounced shift towards lower wavelength (higher energy ) observed in the former case is accounted for by the lowest number of interconnected NbOx polyedra.

 

 

3.3. Laser irradiation of immersed solid targets or colloidal solutions

3.3.1. Laser ablation of solid metal target

Laser ablation of bulk metals immersed in liquid media (water or non-aqueous solvents) generates colloïdal solutions [44-46]. The nanoparticle size depends on both the laser fluence and the nature of the liquid. The thickness of the molten layer on the target increases with the laser fluence. The molten layer is transformed into nanoparticles under recoil pressure of the vapor of the surrounding liquid. Thicker melt layer is dispersed into larger nanoparticles. As the vapor pressure depends on the nature of the liquid ( higher boiling temperature means lower vapor pressure at the same temperature), the efficiency of melt dispersion depends on the nature of the liquid. In addition the plasmon frequency strongly depends on the particle shape. Whereas spherical particles show one symmetrical band , ellipsoidal ones or nanorods exhibit two plasmon oscillations, depending on the relative directions of the incident light (transverse and longitudinal) and of the particle axis. It gives rise to a supplementary absorption at lower energy (higher wavelength), leading to an assymetric band or even to the appearance of a separate longitudinal peak [18]. In the present work, elongated Au nanoparticles have been obtained and characterized by their plasmon frequencies.

3.3.2. Laser irradiation of colloidal solutions

Laser irradiation of monometallic colloïdal solutions modifies the size distribution and shape of nanoparticles. Au nanorods synthetized by laser ablation of an immersed gold target may be fragmented by tuning the wavelength of the laser radiation [46]. Similar results have been obtained on goldened NiCo nanorods prepared by electroless deposition of Au on NiCo nanorods obtained by heterogeneous nucleation (section 3.1.2.). Exposure of these nanorods to the radiation of a Nd/YAG laser (fig.5) leads to (i) an increase of absorbance in the 500-560 nm range, indicating an increase of concentration of spherical nanoparticles upon fragmentation, (ii) a gradual decrease of absorbance in the IR region , attesting a decrease of concentration of elongated AuNiCo nanorods.

 

 

In addition, Ag-Au alloys may be obtained by irradiation of a mixture of the monometallic colloidal solutions (figure 6) [48]. Figure 6 presents the plasmon resonance spectra obtained for various values of the exposure time. The initial spectrum presents the plasmon resonance of Ag (410 nm) and Au (550 nm). Upon irradiation of the mixture, appears first an intermediate phase characterized by an intensity decrease and a shift of the bands of pure Ag and Au towards larger wavelengths. Finally these bands disappear with emergence of a new band at 495 nm ascribed to an Ag-Au alloy.

 

 

3.3.3. Laser generation of self-organized nanostructures on solids

Simultaneously with ejection of nanoparticles from a solid target during laser ablation of a solid, laser radiation is capable of generation of dense arrays of self-organized nanostructures. Fig. 7 shows an AFM view of an array of such nanostructures, that are formed under ablation of an Ag target in water with a picosecond laser beam. These nanospikes are formed owing to the hydrodynamic instabilities at the interface melt- vapor of the surrounding liquid; the disparities of size arise from the fluctuations of experimental parameters such as laser fluence and local surface roughness.

 

 

The density of these nanostructures on Ag amounts to 1010 cm-2 [49]; they show the enhanced Raman scattering of organic molecules adsorbed on them (so called Surface Enhanced Raman Scattering, SERS). The estimated enhancement factor is 105 for acridine molecules. Nanostructures can be produced in a similar way on a variety of other metals, e.g., Ta, Al, Ni, etc. Estimation of enhancement factor was performed by comparing the Raman signal of organic molecules adsorbed on the nanospikes with that of a solution of the same organic molecule [49]

 

4. MULTI-STEP METHODS

In this case, the synthesis of nanoparticles includes the participation of a solid support. The surface of the support may be considered as a particular template, and the particles as surface-mediated nanoparticles.

4.1. Fixation of the precursor on the host support, followed by its transformation into the invited phase (oxide or metal)

Supported palladium catalysts have been extensively studied but hydroxyapatite Ca5(OH)(PO4)3 has been much less used as a support. Two examples are presented below.

4.1.1. PdO/hydroxyapatite catalysts

The calcium hydroxyapatite is impregnated by a solution of Pd(NH3)4(NO3)2 before calcination in oxygen at 550 ° C. At low Pd loading, the Pd2+ ions are isolated and their UV-Visible spectrum shows a d-d transition at 430 nm. When increasing the Pd content, the Pd 2+ and oxygen ions form Pd xO y clusters (figure 8) whose absorption edge, determined as in section 3.2. [42, 43], appears at a higher wavelength (about 630 nm) than the d-d transition of isolated Pd 2+ ions and at lower wavelength (higher energy) than bulk PdO, a p-type semiconductor (absorption edge near 1700 nm, not shown). The band at 250 nm is ascribed to a palladium-oxygen charge transfer.

 

 

4.1.2. Cobalt/ Calcium hydroxyapatite systems

The control of CoxOy clusters size allows to draw correlations between spectroscopic, magnetic and catalytic properties in the oxidative dehydrogenation of ethane. Two preparation modes were involved [50, 51]: (i) cation exchange which gives isolated paramagnetic Co2+ ions in strong interaction with the support, resistant to oxidation, (ii) impregnation which generates cobalt species weakly bound to the support and more easily oxidized, giving rise to CoxOy clusters and Co3O4. Isolated Co2+ ions and cooperating cobalt sites are distinguished by UV-Visible-NIR diffuse reflectance spectroscopy (Figure 9a). Cation exchange leads exclusively to isolated octahedral Co2+, characterized by bands at 520, 570 and 640 nm and 1400 nm. Conversely, impregnation generates mainly CoxOy clusters or Co3O4, containing tetrahedral Co2+ (640 and 1200-1500 nm) and octahedral (low spin) Co3+ (bands at 430-495 and 725nm).

 

 

On the other hand, detailed magnetic measurements (by SQUID), not presented here (see ref [50, 51]) have shown the paramagnetic behaviour of isolated Co2+ whereas antiferromagnetic correlations are developed in CoxOy clusters (short-distance correlations) or Co3O4 (long-distance correlations). It must be stressed that a low quantity of Co2+ is exchanged during the impregnation procedure. The nature of Co species (speciation) is summarized on scheme 2.

 

 

Finally, the isolated Co2+ ions show much better performance in the oxidative dehydrogenation of ethane (22% yield in ethylene at 550° C) than CoxOy clusters and Co3O4 [51].

4.2. Creation of the invited phase in solution before its fixation (immobilization) on the support

The immobilization of metal particles (Pd, Ru) on niobia or alumina [52] is performed in two steps. Nanoparticles of Pd and Ru in colloidal solutions are first prepared in polyol medium either by steric stabilization by polyvinyl pyrrolidone(PVP) or by electrostatic stabilization. They are redispersed in dichloromethane containing γ-mercaptopropyltrimethoxysilane (γ-MPS) as indicated on figure 10.

 

 

The γ-MPS possess two functional groups: i) a thiol function (A) allowing the interaction with the metallic surface of the nanoparticle and ii) three ethoxy groups which can be readily hydrolyzed for the grafting onto the support (B). Figure 11 shows the micrographs obtained with Pd and Ru nanoparticles immobilized on niobia or alumina.

 

 

At first sight, one can wonder what is the benefit to use such a sophisticated method. But, this procedure: i) avoids direct metal-support interactions; (ii) offers new possibilities to control the shape, size and structure of colloidal metal particles without change upon heterogeneization and (iii) gives higher productivity for obtaining hex-1-ene from hexadiene [52].

 

5. CONCLUSION

Whereas numerous methods allow to generate isotropic or nearly isotropic nanoparticles, the control of size, composition, structure and of anisotropy is much less straightforward. Heterogeneous nucleation promote nanowires and dumbells. Laser irradiation of immersed targets and of colloidal solutions allows to produce anisotropic particles or to induce selective fragmentation by tuning the laser wavelength. It produces also alloys nanoparticles from mixtures of monometallic colloidal solutions. Surface mediated methods favor the size control of oxide clusters by choosing the precursor, fixation method and loading, which is an incentive to draw correlations between cluster size and catalytic performances. This variety of methods allows to favor the design of the particular size and shape of nanoparticles associated with specific physical (magnetic, spectroscopic) and chemical (catalytic activity and selectivity) properties.

 

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(Received on 1 July, 2008)

 

 

* Electronic address: bozonver@univ-paris-diderot.fr