On-line version ISSN 0104-6632
Braz. J. Chem. Eng. vol. 14 no. 3 São Paulo Sept. 1997
THE EFFECT OF THE PHYSICAL PROPERTIES OF PARTICLES OF BULK-BLENDED FERTILIZERS ON SEGREGATION BY CONING
G.A. da Silva
Escola Politécnica da USP - Departamento de Engenharia Química - Av. Prof. Luciano Gualberto - travessa 3,
380 05508-900 São Paulo SP - Brazil - Phone: (011) 818-5613 - Fax: (011) 211-3020 - E-mail: firstname.lastname@example.org
(Received: April 14, 1997; Accepted: June 16, 1997)
Abstract: Bulk blending is a way to produce compound fertilizers in which the different nutrients are present in different particles. Due to the heterogeneous composition of bulk blends, particle segregation, when it occurs, is a serious problem to the fertilizer producer, as well as to the farmer.
Free fall is one of the main types of particle movement to promote segregation. The physical properties of the particles that potentially affect the tendency to segregate the most are size, density and shape. The main objective of this work is to study the influence of size and density of particles and distance of fall on segregation due to free fall. It was found that particle size is the most important physical characteristic to affect segregation; the greater the difference in particle size, the greater the segregation. Free fall is an important mechanical factor affecting segregation; the greater the distance of fall, the greater the segregation. No evidence of the influence of particle density on segregation was found.
Keywords: Bulk-blended, compound fertilizers, segregation by coning.
Particle segregation is the separation of particles having similar characteristics in the same region of a system of particulated solids. Generally, it occurs in all industrial processes in which solid particles are handled. Some examples are coal, ores, sand, cement, detergents, polimers, fertilizers, pharmaceutical compounds, cereals, etc.
In the particular case of the fertilizer industry, most of the final product is distributed as mixed granular fertilizers - fertilizers in granular form, containing at least two (usually three) of the primary nutrients (N, P, K). Mixed fertilizers may be either
- compound fertilizers - obtained by chemical processing and comprising granules of a similar composition;
- blended fertilizers - obtained by dry mixing of granular fertilizer materials and comprising granules of a heterogenous composition.
Segregation occurs in the handling of both types of mixed fertilizers, but it is a troublesome problem for blended fertilizers, due to their non-uniformity of composition. The lack of homogeneity may create problems for the blender in two ways: the product may fail to conform its guaranteed analysis and irregular field distribution causing spotty crop growth resulting in the dissatisfaction of the farmer.
The present paper is intended to contribute to an understanding of the segregation phenomenon in bulk-blended fertilizers.
For segregation to occur, two conditions are necessary:
- relative movement between particles;
- differences in one or more particle characteristics, which are sensitive to particle movement.
These characteristics are usually called segregation-inducing characteristics or properties.
The main segregation-inducing properties are particle size, particle density and particle shape (Hoffmeister et al., 1964; Johanson, 1978; Williams, 1976 and 1990). Angle of repose, particle resilience and friction coefficient have also been related to segregation (Williams, 1976 and Carson and Marinelli, 1994). Hoffmeister et al. (1964) and Williams (1990) point to particle size as the most important physical property to induce segregation.
The handling procedures that cause relative movement among particles and may induce segregation are
- free fall or coning - as occurs when the particulate system is allowed to drop in to a conical sloping pile;
- ballistic (Hoffmeister et al., 1964) or trajectory action (Williams, 1976) - as occurs when particles are projected horizontally, for example, as in the projection of fertilizer particles by fan-type spreaders;
- vibration - as occurs when particles are subjected to vibrational energy (Hoffmeister et al., 1964; Williams, 1976 and 1990; Harris and Hildon, 1970 and Harwood, 1977).
It has been pointed out that coning is the most frequent and significant cause of segregation in fertilizer handling (Hoffemeister et al., 1964). It occurs in industrial operations as bag filling, feeding and discharging of bins, hoppers, etc.
The coning segregation modelling is hard due to the high number and complexity of the mechanical interactions to which the particles are exposed.
The movement of a particle submitted to coning comprises a maximum of three steps:
- free fall in the air until the particle reaches the pile;
- movement on the lateral surface of the pile; and
- movement in the horizontal plan of the pile base.
If a particle of diameter D and density r is dropped from a height h in free fall, the kinetic energy it has when it reaches the pile is proportional to rD3h.
Johanson (1978) analysed the impact of the particles on the pile. He found that when the kinetic energy is sufficiently high, the impact can produce a crater on the top of the pile and the more resilient ones are caught in the crater. The particles with low kinetic energy and low resilience will bounce out to the pile.
Brown in Drahun and Bridgwater (1983) considers that the primary factor is the collisions between particles flowing onto the heap and those forming at the surface. As a consequence, small particle velocities will vary with in a wide spectrum, whereas the larger ones will vary with in a narrow interval.
Mathée (1967/1968) considers two kinds of motion on a slope: sliding and rolling. To evaluate the segregation he developed two models for each motion, using the conservation of energy. The parameter used to estimate segregation was l - the horizontal distance travelled by the particle after the slope. The equations obtained were
- for sliding only:
- for rolling only:
H = vertical distance between the point where the particle starts its motion slope down and the horizontal plane;
a = angle of the slope;
m = coefficient of friction
r = particle radius;
f = coefficient of rolling friction.
When there is only sliding, parameter l is independent of the size of the particle. Segregation would take place only for mixtures of components having different coefficients of friction. In the case of rolling only, it was found that segregation is also dependent on particle size.
Syskov and Lyan in Drahun and Bridgwater (1983) considered that the particles rolled down the inclined slope and that segregation was caused mainly by the roughness of the free surface.
The above studies indicate that particle size and density shall be the most important physical properties to induce coning segregation.
This paper describes an experimental study of the influence of particle size and density differences on the coning segregation of binary mixtures of fertilizers.
Two series of experiments were carried out in which the purpose was to evaluate the coning segregation of binary mixtures of particles of different sizes (serie I) and different densities (serie II).
The apparatus used was designed by Hoffmeister et al. (1964). The design was based on the segregation pattern observed in the quantitative measurement of segregation in conical piles. The observations show that compositions in a pile appeared to be constant along radial lines from the center of the bases of the pile. The apparatus is shown in Figure 1.
Figure 1: Apparatus for determination of the index of segregation.
The apparatus comprised a box 25 cm high, 35 cm long and 5 cm wide. The walls were transparent, colorless acrilic; the front wall was removable and the back wall was slotted to permit insertion of eight aluminum vanes at 10 degree intervals, attached to an acrilic plate.
The tests consisted of forming a section of a conical pile by pouring 450 g of a binary mixture (225 g of each component) into the box through a funnel located at a height h from the bottom of the box, forming a section of a conical pile. The vanes were then inserted in the slots by cutting the conical pile section in nine 10-degree angular segments. The apparatus was turned on its vaned plate, the removable wall was removed and the fraction of the mixture in each of the nine angular segments was removed. The two components (A and B) of each fraction were separated and weighed.
The materials used were three commercial granular fertilizers, each of which was separated into three granulometric fractions, giving a total of nine materials, as follows:
- DAP (diammonium phosphate) - particle density 1.43 g/cm3;
- MAP (monoammonium phosphate) - particle density 1.61 g/cm3; and
- KCl - particle density 1.94 g/cm3.
- -6+8 - passed through a USS#6 sieve (3.353 mm) and retained in a USS #8 sieve (2.380 mm), with an apparent diameter of 2.87 mm;
- -10+12 - passed through a USS#10 sieve (2.000 mm) and retained in a USS #12 sieve (1.679 mm), with an apparent diameter of 1.84 mm; and
- -14+16 - passed through a USS#14 sieve (1.410 mm) and retained in a USS #16 sieve (1.191 mm), with an apparent diameter of 1.30 mm.
Using the nine materials (three different densities and three different particle sizes) two sets of binary mixtures were prepared:
- set I - mixtures of materials with the same density and two different particle sizes;
- set II - mixtures of materials with different densities and the same particle sizes.
Table 1 gives the composition of the eighteen binary mixtures used in the tests.
Each of the eighteen binary mixtures was tested for two fall heights: 30 cm and 50 cm. Each test condition was repeated five times.
In order to measure the segregation attained in each test, the author devised an index of segregation (IS) described elsewhere in the literature (Silva, 1995).
The proposed index of segregation is calculated from the mass fractions of components A (fAi) and B (fBi) and mixture (fTi) accumulated between angular segments 1 until i:
mAi = mass of component A in the angular segment i;
mBi = mass of component B in the angular segment i;
MAi = SmAi and MBi = SmBi
The definition of the index of segregation is illustrated in Figure 2, where are plotted the mass fractions fA and fB versus fT. Based in Figure 2a the index of segregation (IS) is defined as the ratio between the shadowed area and the quadrangle KLMN area.
The following equation is used to calculate the index of segregation:
Figure 2: Mass fractions of components A and B versus mass fraction of mixture.
|Mixture no.||Component A||Component B||DA/DB||rA/rB|
|Ang. seg.||Mass of components in the binary mixture (g)|
|Run 1||Run 2||Run 3||Run 4||Run 5|
Silva (1995) presents the results of the 180 experiments. Table 2 shows, as an example, the results of the test for a distance of fall of 50 cm, with a binary mixture of the following components:
- component A: KCl (r = 1.94 g/cm3) with a particle diameter of 2.87 cm and
- component B: Kcl (r = 1.94 g/cm3) with a particle diameter of 1.30 cm.
|Test conditions||Run no.|
|material||R = DA/DB||h (cm)||1||2||3||4||5|
|Test conditions||Run no.|
|Part. size (mm)||r = rA/rB||h (cm)||1||2||3||4||5|
Effect of Particle Size
The comparison of the ratios of variance (F) with values in table D (BOX et al., 1978) indicates that the sources of variation, h (F = 14,335) and D (F = 2,604) and the interaction between them (F = 66.07) are highly significant; interaction hxRxr (F = 1.31) is not significant. For all the other sources of variation - r (F = 0.53); hxr (F = 0.42) and Dxr (F = 0.53) - with F < 1, it was found that the inverses of F are not significant either.
These findings lead to the following observations:
- differences in particle size in a mixture is an important factor in inducing coning segregation;
- the fall height is a mechanical factor that has a large influence on the coning segregation induced by particle size differences; and
- in this set of tests it was not possible to detect an influence of particle density on the coning segregation induced by differences in the particle size.
These results are shown in Figure 3, where the index of segregation is plotted against the particle diameters ratio; each line represents one distance of fall. It can be noted that the amount of segregation increases as the diameter ratio and distance of fall increase.
The coincidence of the curves for the three different densities for both distances of fall is clearly shown in Figure 3d. This observation is evidence of the small influence of density on the coning segregation induced by differences in particle size.
Effect of Particle Density
The evidence concerning the effect of particle density on coning segregation may lead to the following question:
"Doesnt the difference in particle density really affect coning segregation or does the influence of difference in particle size hide it?"
The analysis of variance of the results of the set II tests may answer the question. Table 6 shows this analysis.
The comparison of the ratios of variance (F) (or of its inverses when F<1) corresponding to all sources of variation with values in table D (BOX et al., 1978) indicates that none are significant. In this condition two hypotheses arise:
a) no significant segregation was found in the tests with mixtures of particles of different densities, or
b) segregation was found, but all indices of segregation were statistically the same.
Considering that none of the sources of variation were significant, the mean and standard deviation of all indices obtained from the tests were calculated for this set of tests, which results:
mean = 0.008657
standard deviation = 0.007333
Considering that the index of segregation is, by definition, always positive and that the distribution is monocaudal, it results that the probability of the mean being other than zero is 25%. So, either the differences in particle density do not induce coning segregation or they induce a segregation so small that the index of segregation is of the same magnitude as the experimental error.
Figure 4 presents the results of this set of tests as a graph where the index of segregation is plotted against the densities ratio; each line corresponds to a fixed distance of fall.
|Source of variation||Freedom degrees||Sum of squares (x103)||Average squares (x103)||F|
|Distance of fall (h)||1||316.26||316.26||14,335|
|Particle size (D)||2||114.89||57.45||2,604|
|Interaction h x D||2||2.92||1.46||66.07|
|Interaction h x r||2||0.02||0.01||0.42|
|Interaction D x r||4||0.05||0.01||0.53|
|Interaction h x D x r||4||0.12||0.03||1.31|
Figure 3: Index of segregation versus particle diameters ratio.
|Source of variation||Freedom degrees||Sum of squares (x104)||Average squares (x103)||F|
|Distance of fall (h)||1||6.46||6.46||1.109|
|Particle size (D)||2||8.23||4.12||0.707|
|Interaction h x D||2||9.51||4.76||0.817|
|Interaction h x r||2||8.06||4.03||0.692|
|Interaction D x r||4||27.71||6.93||1,190|
|Interaction h x D x r||4||26.53||6.63||1,140|
It is not possible to identify any tendency for a variation in the index of segregation with the ratio of densities for one of the three diameters. This probably means that the deviations found for any given condition are due to experimental errors. Comparison of indices of segregation calculated for both sets of tests leads to the observation that the figures for set II are smaller than those for set I. This fact, associated with the absence of a tendency towards variation, may lead to the first hypothesis, that no significant segregation is induced by differences in particle density.
Figure 4: Index of segregation versus densities ratio.
It can also be noted from Figure 4 that the indices of segregation for a diameter of 2.87 cm are higher than those for diameters of 1.84 cm and 1.30 cm which, by the way, are statistically the same. Further experiments would be needed to find a critical value of particle diameter, above which segregation induced by difference in particle density would increase.
- The main factor to induce coning segregation is the difference in the particle sizes in the mixture; in other words, particle size is the main physical property to induce coning segregation.
- There is a tendency to increase segregation by increasing the particle size ratio.
- The distance of fall has a large influence on coning segregation induced by differences in particle size: the higher the value of h, the higher the index of segregation.
- There is a synergy between difference in particles size and distance of fall, as far as coning segregation is concerned.
- Particle density does not affect coning segregation induced by difference in particle size.
- Differences in particle density do not induce coning segregation.
D Particle diameter
f Mass fraction
F Ratio of variance
h Distance of free fall
IS Index of segregation
m Mass in angular segment i
M Mass in the pile section
r Particle radius
i Angular segment
A Component A of the mixture
B Component B of the mixture
T Total mixture
a Angle of the slope of a conical pile
m Coefficient of friction
r Particle density
Box, G.E.P.; Hunter, W.G. and Hunter, J.S., Statistics for Experimenters. An Introduction to Design, Data Analysis, and Model Building. John Wiley & Sons (1978).
Campbell, A.P. and Bridgwater, J., The Mixing of Dry Solids by Percolation. Trans. Instn. Chem. Engrs., v. 51, pp. 72-74 (1973). [ Links ]
Carson, J. W. and Marinelli, J., Characterize Bulk Solids to Ensure Smooth Flow. Chemical Engineering, pp. 78-90, April (1994). [ Links ]
Drahun, J.A. and Bridgwater, J., The Mechanisms of Free Surface Segregation. Powder Technology, v. 36, pp. 39-53 (1983). [ Links ]
Harris, J.F.G. and Hildon, A.M., Reducing Segregation in Binary Powder Mixtures with Particular Reference to Oxygenated Washing Powders. Ind. Eng. Chem. Process Des. Develop., v. 9, n. 3, pp. 363-367 (1970). [ Links ]
Harwood, C.F., Powder Segregation Due to Vibration. Powder Technology, v. 16, pp. 51-57 (1977). [ Links ]
Hoffmeister, G.; Watkins, S.C. and Silvergerg, J., Bulk Blending of Fertilizer Material: Effect of Size, Shape and Density on Segregation. Journal of Agricultural and Food Chemistry, v. 12, n. 1, pp. 64-69 (1964). [ Links ]
Johanson, J. R., Particle Segregation... and What to Do about It. Chemical Engineering, Mayp 8, p. 183-188 (1978). [ Links ]
Mathée, H., Segregation Phenomena Relating to Bunkering of Bulk Materials: Theoretical Considerations and Experimental Investigations. Powder Technology, v. 1, pp. 265-271, (1967/1968). [ Links ]
Silva, G.A., Estudo da segregação em fertilizantes. São Paulo, 169 pp. Thesis (Livre Docencia), Escola Politecnica, Universidade de São Paulo, Brazil. (1995). [ Links ]
Williams, J.C., The Segregation of Particulate Material. A Review. Powder Technology, v. 15, pp. 245-251 (1976). [ Links ]
Williams, J.C., Mixing and Segregation in Powder Technology. John Wiley & Sons, pp. 71-90 (1990).