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Brazilian Journal of Chemical Engineering

Print version ISSN 0104-6632

Braz. J. Chem. Eng. vol.30 no.1 São Paulo Jan./Mar. 2013

http://dx.doi.org/10.1590/S0104-66322013000100018 

FLUID DYNAMICS; HEAT AND MASS TRANSFER; AND OTHER TOPICS

 

Mathematical modeling of supercritical fluid extraction of oil from canola and sesame seeds

 

 

B. HonarvarI, *; S. A. SajadianII; M. KhorramII; A. SamimiII

IChemical Engineering Department, Science & Research Branch, Phone: + 989173145175, Fax: + 987116247155, Islamic Azad University, Fars, Shiraz, Iran
IIChemical Engineering Department, University of Sistan and Baluchestan, Zahedan, Iran

 

 


ABSTRACT

Mathematical modeling of supercritical fluid extraction of oil from canola and sesame seeds with a two-phase model was performed in this work. A model based on differential mass balance was used to correlate the experimental data. Different adsorption isotherm models (Henry, Freundlich and Brunauer, Emmet and Teller (BET)) were used to describe the equilibrium state. Three model parameters such as effective diffusivity (Deff), mass transfer coefficient (Kf) and axial dispersion coefficient (Dax) of the bed were used as fitting parameters. The experimental data for yields were obtained at pressures of 10-20 MPa, temperatures of 313-333 K and solvent flow rates of 2-4 g/min. From the results, a nonlinear adsorption isotherm exhibited better agreement with experimental data of yield than a linear model in the range of studied conditions.

Keywords: Mathematical modeling; Interaction solute-solid; Isotherm; BET; Freundlich.


 

 

INTRODUCTION

Mathematical models are powerful and useful tools for design and scale up of SCFE processes and, since the laboratory scale up to pilot and industrial scales and the cost evaluation of processes cannot be done without mathematical modeling, several attempts at mathematical modeling of supercritical fluid extraction processes have been proposed. Three different approaches have been proposed for SFE mathematical modeling. The first approach is based on the use of an empirical kinetic equation to describe experimental data (Naik et al., 1989; Ngueyn et al., 1991; Subra et al., 1998; Silva et al., 2008). These empirical relations are useful when there is no information about equilibrium relations and mass transfer mechanisms. Their advantage is their simplicity, but these models are not adequate for scaling up. Other authors have proposed models based on analogies to heat and mass transfer (Bartle et al., 1990; Reverchon et al., 1993; Esquivel et al., 1999; Barroso et al., 2011). The single sphere model assumes that the solute is extracted from a particulate bed composed of porous and inert spheres having the same size; the model showed that intraparticle mass transfer was the controlling factor for the process and that mass transfer resistance on the fluid is zero. Another approach to SFE modeling is based on differential mass balance, such as the "broken and intact cells" model. Sovová (1994) presented a general model that divides the extraction curve into two main periods. The initial period occurs while the extraction rate is constant. It is controlled by the solubility between solute and solvent (phase equilibrium) and external mass transfer. The second part considers that internal diffusion controls only the extraction of less accessible oil and occurs during this period. Goto et al. (1996) applied the shrinking core model to describe extraction of ginger root with supercritical fluid. This model assumes that the solute is condensed within pores in solid particles and a sharp boundary develops between an oil-rich core in the porous particle and an extracted outer region where the core shrinks as the extraction proceeds. Goodarznia and Ekani (1998) proposed an unsteady state mass balance for solute in a single particle coupled with a fluid phase balance on a differential section of the bed. Internal diffusivity, mass transfer coefficient to the bulk phase and the effect of axial dispersion in the fixed bed are parameters of the model. The extraction of triglycerides from used frying oil with liquid and supercritical ethane has been studied in a semi-batch system at different operating conditions by Rincon et al. (2011) and kinetics and selectivity of supercritical carbon dioxide (SC CO2) extraction of Helichrysum italicum flowers were analyzed at different operating conditions by Ivanovic et al. (2001). Rosmarinus officinalis (rosemary) extracts were obtained in a supercritical pilot-scale plant based on experimental information available in the literature for analytical or low-scale processes under different operating conditions by Garcia-Risco (2011).

The scope of this study was the supercritical fluid extraction oil of canola and sesame seeds oil performed under some different operating conditions. The experimental results were used to develop a model of the extraction process. Many researchers have considered the Henry isotherm because the Henry relation is simple and linear (Goto et al., 1996; Reverchon, 1997; Gooderznia and Ekani, 1998; Reverchon, 2001; Carvalho et al., 2012). Goto et al. (1998) proposed a Brunauer, Emmet and Teller (BET)-type equilibrium relationship for SFE processes where the solute interacts with the solid matrix. Fatemi et al. (2008) applied different isotherms (Henry, Langmuir, Freundlich and Toth) to describe the interaction between solute-solid in the extraction of valerenic acid from Valeriana officinalis L. Ghoreishi et al. (2001) employed the Freundlich isotherm for the modeling of supercritical extraction of mannitol from pane tree leaf. In this work, linear (Henry) and nonlinear adsorption (BET, Freundlich) were used to describe the interaction between oil and seed. This model takes into account mass transfer, solute-fluid interaction (solubility) and solute-solid interaction (adsorption). At equilibrium, the distribution of solute between the solid phase and the supercritical phase is determined by the adsorption isotherm. The adsorption isotherm of oil in the supercritical fluid was modeled by using the different isotherms, such as a single parameter equilibrium relation (Henry), two-parameter relations (BET, Langmuir and Freundlich) and three-parameter relations (Langmuir-Freundlich and Toth).

 

MATERIALS AND METHODS

Figure 1 shows the schematic diagram of the extractor apparatus. The extraction experiments were carried out in a bench scale SC-CO2 apparatus.

Carbon dioxide was fed from a gas tank equipped with a condenser to keep CO2 liquefied. A pump was used to pressurize the liquefied carbon dioxide to the desired pressure. In the present work, about 5 g of dried canola seeds and 0.5 g of ethanol (modifier) along with glass beads were loaded into a 60 mL high pressure vessel in which the glass beads were used to prevent flow channeling in the packed bed. The pressurized carbon dioxide was passed through a surge tank before feeding to the packed bed vessel. The surge tank and the extractor were equipped with a jacket through which hot water flows to control the temperature. In this study, the static time was considered to be about 30 minutes by feeding SC-CO2 to the vessel while the outlet back pressure valve was closed. The dynamic conditions began when the flow of solvent through the vessel was allowed by opening the back pressure valve. To prevent the back pressure valve from freezing, it was heated by an electrical resistance. The extracted oil was transferred to liquid dichloromethane solvent in a u-tube separator where the released CO2 gas was metered by a gas flow meter. The temperature of the solvent was kept at below 0C by using an ice and salt bath during the dynamic extraction time. The 99.6% ethanol and 99.9% dichloromethane were provided by Merck; while the 99.9% CO2 was obtained from Eritch Gas Co.

 

MATHEMATICAL MODELING

The experimental data were fitted with a two phase model. The model is based on the differential mass balances in the solid phase and supercritical phase which is suggested by Goodarznia and Ekani (1998) and Silva et al., (2011).

The following simplifying assumptions were made in the model formulations:

1. Temperature gradient and pressure drop through the bed are low enough to consider that the fluid density remains constant.

2. Solute is considered to be single chemical component.

3. The flow regime is axially dispersed.

4. The physical properties of supercritical CO2 are constant.

5. The solvent flow rate was constant along the bed and uniformly distributed, without any radial dispersion.

6. The particle surface is porous.

According to the above assumptions, material balances in a volume element of packed bed column for the fluid and solid phases lead to:

i) Bulk Fluid Phase

 

Based on one of the assumptions of the model, the surface of the particles is porous; the solute dissolves in the fluid phase. So linear (Henry) and nonlinear adsorption (BET, Freundlich) isotherms were tested for interaction between Cs and Cp that obtain by Table 1.

 

 

Equations (1), (2) and the adsorption isotherms were solved subject to the following initial and boundary conditions:

Mathematical model equations coupled with equilibrium relations were solved numerically by the Method of Lines available in MATLAB 7.1.

Model Parameters

1) Mass Transfer Coefficient

The film mass transfer coefficient kf around the particle was estimated using the empirical correlation reported by Tan et al. (1989).

2) Axial Dispersion

The axial dispersion coefficient in the SC phase was approximated by using the correlation given by Tan and Liou (1989).

3) Effective Diffusivity

The equation for the effective diffusivity in the particle was given by Prausnitz et al. (2001):

 

RESULTS AND DISCUSSION

In the present model, the parameters, Deff, Dax, kf and parameters of the equilibrium relations were determined by minimizing the errors:

The adjustable parameters of the model for canola and sesame seeds are presented in Tables 2 and 3, respectively. The solute interactions in the solid matrix have been studied with the proposed equilibrium relationships (Henry, Freundlich and BET) and the average absolute relative deviation (AARD) determined for every isotherm given in Table 1. The BET isotherm model describes better the experimental data than Freundlich and Henry isotherm models, so the BET isotherm was used for mathematical modeling. The parameters of the BET isotherm are K and Cm, where K represents the equilibrium coefficient, and Cm, the monolayer concentration of the solute on the solid. When values of K are large, the solute-solid interactions are strong. This is the case for essential oil extraction from herbs and leaves (Roy et al., 1996) or caffeine extraction from coffee beans (Peker et al., 1992), On the other hand, when the value of K is small, the solute-solid interaction become weaker. It is possible to reach solute concentrations in the fluid phase that are close to solubility (Goto et al., 1998). Since the structure of natural materials is complex, the adsorption equilibrium parameters for canola and sesame are not available. Estimation of an equilibrium relationship might be difficult. To simplify the fitting of model parameters, we assumed that Cm is equal to CS0= (C0/ (1-Ep)). Solubility of canola and sesame oil (Csat) was estimated from experimental data.

 

 

 

 

The operational conditions for each experiment are given in Tables 2 and 3 for canola and sesame seeds, respectively. The measured yield of oil extraction (Yield) is defined by the following equation:

The Effect of Pressure

Figures 2 and 3 show the effect of the pressure of the extraction on yield for canola and sesame oil, respectively. For both seeds the extraction yield increased with increasing pressure, especially at higher pressures. A faster extraction rate at low extraction times was observed when the pressure increased. As can be seen in Tables 2 and 3, at constant temperature the mass transfer coefficient decreased but the solubility of the oil increased with increasing pressure, so supercritical fluid did not disperse into the seed particle easily. The saturation concentration of oil in the fluid phase (solubility) showed a positive effect on the extraction process. On the contrary, decreasing the mass transfer coefficient showed a negative effect (Esquivel et al., 1999; Papamichail et al., 2001; Fatemi et al., 2008; Louli et al., 2004). The values of the parameters of the model and parameters of the isotherms for every operating condition are listed in Tables 2-3 and Table 4, respectively. The effective diffusivity and film mass transfer coefficients decreased with increasing pressure because with increased pressure, binary diffusivity decreased but the axial dispersion coefficient increased (Fatemi et al., 2008). The results indicate that increasing the operating pressure for canola and sesame from 10 to 20 MPa increases the extraction yield significantly (143.3% and 176.7%, respectively).

 

 

 

 

The Effect of Temperature

The effect of temperature on extraction yield for both seeds at a pressure 20 MPa, particle size of 0.15 mm and CO2 flow rate of 4 gram/sec are shown in Figures 4 and 5. The extraction yield increased with decreasing temperature. The mass transfer coefficient and effective diffusivity increased but solubility of oil decreased with increasing temperature. The increasing temperature causes a decrease in solvent density and an increase in vapor pressure. In addition, under these conditions the change of solvent density is more effective than solute vapor pressure (Kandiah et al.; 1990; Esquivel et al., 1999; Papamichail et al., 2001; Louli et al., 2004). In this case of canola seeds, experimental measurements show that a temperature of 313 K results in a higher extraction yield by 44.25% compared to that obtained at 333 K. The experimental results of sesame show that, upon increasing the temperature from 313 to 333 K, the yield of extraction of oil decreased 63.24%.

 

 

 

 

The Effect of Flow Rate

The effect of CO2 flow rate on the extraction rate using supercritical CO2 was studied at pressure of 20 MPa and temperature of 313 K. Figures (6 and 7) show the effect of CO2 flow rate on the extraction rate from canola and sesame, respectively. The amount of the total oil extracted increased slightly with increasing CO2 flow rate and tend toward the same value at higher CO2 consumption. Increasing the flow rate from 2 to 4 (g/min) caused a rise (41% and 67.58%, respectively) in the yield of oil extraction from canola and sesame. The increasing flow rate generally caused a shorter residence time, but the number of CO2 molecules contacting with the solute and the number of CO2 molecules per unit volume entering the extractor increased, thus increasing inter-molecular interaction between CO2 and solute, increasing the solute dissolution.

 

 

 

 

CONCLUSIONS

The extraction of oil from sesame and canola seeds and mathematical modeling were evaluated. Pressure, temperature and flow rate were selected as the parameters influencing the extraction process. The results indicated that the extraction yield versus time was significantly affected by the pressure; however, temperature and flow rate have slight effect on the extraction rate. The results showed that increasing the pressure from 10 to 20 MPa and the flow rate from 2 to 4 g/min increased the extraction yield and increasing the temperature from 313 to 333 K decreased the extraction yield. The extraction yields of sesame seeds were higher than those of canola seeds at the same operating conditions. The amounts of oil extracted from these two seeds are different. The physical structure of canola seeds is much harder than sesame seeds. A theoretical two-phase model based on differential mass balance within the particle pores and packed bed extractor has been studied. Adjustable parameters of the model were the effective diffusivity (Deff), mass transfer coefficient (Kf) and axial dispersion coefficient (Dax) of the bed. Effective diffusivity and mass transfer coefficient decreased with increasing pressure, decreasing binary diffusivity and increasing the axial dispersion coefficient. The effect of temperature on the adjustable parameters was against the effect of pressure. The results showed that increasing SC-CO2 flow rate caused a decreased axial dispersion coefficient and other parameters did not exhibit significant changes. To describe the distribution of solute between the solid phase and supercritical phase, Henry, Freundlich and BET isotherms were used. The BET isotherm showed good agreement with experimental data and a lower AARD. Cm and K are BET constants determined by fitting with experimental data. Increasing pressure and flow rate led to a reduction of the parameter K, but increasing the temperature caused an enhancement of K (Table 4). We assumed Cm is equal to Cs0. The best conditions of extraction of oil for both seeds were a pressure of 20 MPa, temperature of 313 K and flow rate of 4 g/min.

 

 

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(Submitted: November 14, 2011 ; Revised: April 20, 2012 ; Accepted: April 20, 2012)

 

 

* E-mail: honarvar2@gmail.com

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