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High performance concrete applied to storage system buildings at low temperatures

Abstract

According to some estimates, world's population growth is expected about 50% over the next 50 years. Thus, one of the greatest challenges faced by Engineering is to find effective options to food storage and conservation. Some researchers have investigated how to design durable buildings for storing and conserving food. Nowadays, developing concrete with mechanical resistance for room temperatures is a parameter that can be achieved easily. On the other hand, associating it to low temperature of approximately 35 °C negative requires less empiricism, being necessary a suitable dosage method and a careful selection of the material constituents. This ongoing study involves these parameters. The presented concrete was analyzed through non-destructive tests that examines the material properties periodically and verifies its physical integrity. Concrete with and without incorporated air were studied. The results demonstrated that both are resistant to freezing.

concrete; high-performance; food conservation


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High performance concrete applied to storage system buildings at low temperatures

Sandra Maria de Lima* * e–mail: lima@ccivil.cefetmt.br ; Luiz Vicente Vareda; Jefferson Benedicto Libardi Liborio

Department of Structural Engineering, School of Engineering of São Carlos, University of São Paulo, Av. Trabalhador Sãocarlense, 400, Centro, 13566–590, São Carlos – SP, Brazil

ABSTRACT

According to some estimates, world's population growth is expected about 50% over the next 50 years. Thus, one of the greatest challenges faced by Engineering is to find effective options to food storage and conservation. Some researchers have investigated how to design durable buildings for storing and conserving food. Nowadays, developing concrete with mechanical resistance for room temperatures is a parameter that can be achieved easily. On the other hand, associating it to low temperature of approximately 35 °C negative requires less empiricism, being necessary a suitable dosage method and a careful selection of the material constituents. This ongoing study involves these parameters. The presented concrete was analyzed through non–destructive tests that examines the material properties periodically and verifies its physical integrity. Concrete with and without incorporated air were studied. The results demonstrated that both are resistant to freezing.

Keywords: concrete, high–performance, food conservation

1. Introduction

Employing refrigeration/cooling and freezing processes for food conservation is an essential feature about answering population growth demands. These processes allow suitable storage as well as a world–wide exchange of perishable foodstuffs. In addition, stocks can be controlled during and after harvest periods.

Lots of industrial sectors have used refrigeration/cooling technology during the food transportation to make high quality products available to the domestic and international market. In order to help this kind of business, concrete material was proposed as an alternative for preserving food systems at temperatures up to –35 °C.

For these industries, deterioration on their installations frequently causes considerable damage. However, maintenance itself represents the lowest expense. Actually, the circumstances around it bring the highest costs. One of them is factory downtime, when there is waste of time and workforce. Another one is the embargoes imposed during inspections, when any inadequate cleanliness conditions are detected on the installations.

Developing this concrete involved designing scientifically a material resistant to severe environment conditions, mainly low temperatures and use demands (i.e. equipment carrying, storage, chemical attack). At the same time, this material must be more cost–effective in comparison to other alternative constructions. Some positive features should be cost reduction for concrete producing and a significant durability of the building material.

2. Literature Review

2.1. The effect of low temperatures on concrete

The resulting problem to expose concrete to low temperatures is that being a porous material, concrete is able to store water. As this liquid volume increases during freezing process and the exceeding volume moves through the concrete capillaries, the pressure increases in the walls.

Powers1 and Powers and Helmuth2 performed a series of experiments which allowed understanding freezing action in concrete. They reported two phenomena as being the cause of deterioration in this material when it is exposed to low temperatures: 1) the generation of hydraulic pressure and 2) the diffusion of water–gel and capillary water.

When the water contained in the concrete capillaries solidifies, it causes hydraulic pressure. This takes place due to the volume water increase and makes the exceeding amount moving to the capillaries or to the innermost cavities. This migratory movement provokes pressure in the capillary walls, which will become deformed if this pressure surpasses the material resistance. Then, if the migratory flow will not be enough to relieve the pressure, even the capillary filled with ice will crack. This phenomenon is named hydraulic pressure generation.

The capillary voids in the concrete can have different sizes (Figure 1). The bigger is the dimension of these voids, the higher is the temperature of freezing water they contain. Moreover, the coexistence of water in different physical states as well as its freezing at different temperatures in the concrete brings the depletion of water from the smallest capillaries into the biggest ones. This happens because the highest levels of energy can be found in the smallest capillaries with the greatest saturation degrees.


This phenomenon is called capillary diffusion and it begins in the mass–gel, where the smallest voids are found in the concrete. Initially, the diffusion of water–gel makes contractions. On a second stage, this depletion to the capillaries or cavities causes an increase in the ice crystals inside of them. Then, when there aren't enough voids for storing the excess of water, these ice crystals can provoke deformation.

The air voids found in the cement bulk limit the hydraulic pressure and the ice crystals growth through water–gel diffusion or capillary water, due to the distance between these voids (Lcritic). Powers3 suggests incorporating 6 ± 1% of air incorporated into the concrete in order to protect it from freezing. However, these voids should be near the others so that their diameter is, on average, the distance between its walls. Powers1 also demonstrated that if the ratio water/binder is limited at 0.25, completely hydrated cement bulk will not be damaged by low temperatures because of the stored freezing water elimination from the pores of this cement bulk.

2.2. Assessment of damage to concrete by freezing

Tests exposing concrete to low temperatures must not be destructive because the specimens should be returned to the target temperature environment (i.e. cold chamber) keeping their physical integrity. Determining the natural frequency of the specimens makes this analysis possible.

The natural frequency is the free oscillation rate brought by the application of an outside force, or in other words, the number of times the specimens are moved from the reference point to the displaced point in a period of time.

The test taken to analyze the performance of the specimens from concrete exposed to low temperatures is, therefore, dynamic or related to vibration. The stiffness (elasticity), the capacity of receiving an impact (damping) and the mass from particular specimens are the mechanical parameters that rule a mechanical vibration system. The way these parameters interact defines the mechanical vibration in a certain body.

The natural frequency of any body can be related to its physical integrity, since this is proportional to its stiffness (elasticity). Thus, in this research, the natural frequency will be the parameter used to measure any damage found in the concrete when exposed to low temperatures.

Freezing can cause deformations due to the expansion or contraction of the specimens, depending on the predominant mechanism: generation of hydraulic pressure or diffusion of the water contained in the pore–gel and capillaries, respectively.

The deformations caused by these phenomena were monitored using pairs of mechanical strain gauges fixed on the specimen surface and whose readings were checked through a measuring clock (Tensotast), which fits in the pairs of mechanical strain gauges fixed to the surface of the specimens.

3. Experimental Work

3.1. Method

The following entities set the parameters for the experiment:

a) International Federation for Structural Concrete (fib)4: maximum water/binder ratio = 0.45; minimum resistance class – C30/37; minimum cement consumption – 340 kg/m3; minimum air content – 4%. These specifications correspond to the rank of environmental damage XF4 – freezing and thawing damaging effects, in a saturated condition and in the presence of thawing agents or sea water.

b) Instructions for Structural Concrete (EHE)5: maximum water/binder ratio = 0.50; minimum resistance class – C30; minimum cement consumption 325 kg/m3; minimum air content 4.5%. These specifications correspond to the rank of environmental damage F – freezing and thawing action in the presence of salts and/or deicing chemicals.

c) American Concrete Institute (ACI 318–83): maximum water/binder ratio = 0.45 for features such as kerbs, pipes and handrails and 0.50 for other ones. (Mehta and Monteiro)6.

The previous parameters determined the water/binder ratio employed. Besides this, since a reduced concrete cost was intended, the approximate water/ binder ratio was about 0.40 and 0.45, being the final value of water/binder and ratio 1: m defined from dosage abacus making.

Portland cement CP II E 32 and silica fume (from iron–silicon or metallic silicon suspender manufacturing) constituted the high performance concrete or HPC. The small and coarse aggregates came from São Carlos/SP region: river sand and crushed basaltic with a maximum size of 19 mm, respectively. Policarboxilic superplasticizers (Glenium 51) and air incorporators (IAR) were the additives used.

The Portland cement CP II E 32 was chosen for the HPC subjected to low temperature environments due to the following reasons:

a) The foodstuff storage environments are frequently subjected to rigorous cleaning processes. Some products used during these processes dissolve the calcium hydroxide (CH) present in the concrete, increasing its porosity. However, the pozzolanic reaction makes the concrete more resistant to these chemical attacks.

b) The low heat of hydration of the cement is an advantage to industrial structures with great volumes of concrete, minimizing the effects of plastic retraction;

c) The tricalcic silicate form – C3S facilitates air incorporation in the concrete making the chemical constitution of CP II E 32 convenient for this study. Moreover, as industrial structures like that are usually required at least a month after being built, using cement with a slow speed hydration (although it has a high slag content to consume calcium hydroxide) becomes a better option to the present project.

In order to analyze and define necessary properties for concrete in low temperature environments, two series of specimens were molded. Both were made up from concrete with equal water/binder ratios and 1: m, distinguished by the use or not of incorporating air agent and superplasticizer content.

The 56% mortar content was kept for the specimens and it was determined by the dosage. The consistency was established at k = 100 mm using the slump test. Nine specimens were molded for each series. They were like prisms with a square shaped cross section of 100 x 100 mm and a length of 500 mm.

The curing period lasted 28 days. Two reasons justify this length of time: one is technical and the other is constructive. From the technical point of view, it was intended to eliminate freezing water in the concrete as much as possible. Besides, improving strength could increase the resistance to hydraulic pressure and to the expansion resulted from the specimens freezing. The constructive reason is based on the experience of building systems to store frozen products. According to that, the construction of concrete elements precedes refrigeration/cooling equipment assembling, electrical/mechanical installations and thermal insulation systems. Consequently, it usually takes more than 28 days to finish up all these activities.

Curing was done in a humid chamber. After this period, the specimens were kept in a cold chamber, under a negative temperature of 35 °C. A sample of each specimen contained a thermocouple lodged inside it and fixed during the molding. This action enabled the temperature control of the thermal center from the specimens.

A 60% transversal natural frequency rate was established as the criterion for detecting the specimens rupture.

3.2. Characterization of the materials

The obtained results from the mixture are products of the interaction and synergy found among the components. For this reason, the determination of the properties of the HPC components must be taken meticulously.

With this in mind, the binders, aggregates and additives used to produce the HPC for low temperature environments were studied trying to take advantage of this synergy as much as possible.

By the way, it should be mentioned the Kantro test. Performed according to Liborio7, this test obtained adequate additive contents as well as the compatibility between binders and additives.

Table 1 presents the used binders. By its turn, Figures 2 and 3 illustrate the Kantro tests and their respective graphs, from which maximum contents of superplasticizer and incorporated air additive for the studied concrete were defined.



Concerning the aggregates, grinds and form index were studied. At the same time, the faults in each one were corrected. Table 2 displays data about the coarse and small aggregates employed.

The form index of coarse aggregates was analyzed by determining the volumetric coefficient, which determines the aggregate spherecity, what means the relation between their dimensions. The volumetric coefficient varies from 0.2 to 1. The minimum value describes the elongated aggregate (i.e. the smallest dimension is 1.8 times bigger than the smallest dimension) and the maximum value is equivalent to a spherical aggregate. The volumetric coefficient of the crushed composition (1–19 mm) and the intermediate crushed composition (12.5 mm) was calculated as 0.2. This value of volumetric coefficient characterizes elongated aggregates. In face of that, it was detected the necessity of correcting the properties of the elongated form, which subjected the aggregate to bending (similarly to a bi–supported beam) and to grooves in the material. As a result, the mixing cannot be performed or becomes a difficult process. For solving that, aggregates were doped with silica fume, what strengthens the aggregate surface and makes it behave as a continuously supported beam (Figure 4).


The chosen method for doping aggregates was blending coarse aggregates with silica fume and 10% of mixing water before adding other materials in the concrete dosage.

A way to evaluate the small aggregate angularity may be to consider the angularity number. This is obtained by subtracting 67 from the whole percentage of solid content found in a container filled with aggregates following an established procedure. In addition to this, it is necessary to control the employed particles size with accuracy. Number 67 represents the % of solid volume of the most spherical aggregate while the angularity number measures the % of extra voids in the spherical aggregate. The higher the number, the more angular the aggregate – this number generally ranges from 0 to 11.

The angularity number obtained from criteria proposed by Liborio7 was –1. This shows that the number of voids of the used aggregate is 1% smaller than a spherical aggregate due to the obtained wrapping.

3.3. Dosage

Dosages from two mixtures were prepared: 1) concrete with 6 ± 1% of incorporated air and 2) concrete without incorporated air. They were based on the qualitative analysis of the HPC (for low temperature environments) constituents: binders, additives, additions and aggregates

Ratios 1: m, m defined as the total number of aggregates and water/binder obtained by the dosage abacus (Figure 5) whose determination was a result of the process proposed by Helene and Terzian11 and adapted by Liborio7.


This method consists of dosing three mixtures 1: m which will supply relative data to the cement consumption, water/binder ratio and mechanic resistance. Analyzing these three features in each property makes possible to trace the curves of each one of these parameters, from which the dosage abacus is composed.

Since the materials are the same for the three features, the mortar content is determined for the first dosed mixture and all the other mixtures are produced with the same consistency. In accordance with the application of the concrete, the consistency factor was determined by a slump test (NBR NM 67:1998)12 and this was adopted. During this research it was 100 ± 10 mm.

Two procedures can be adopted for this dosage method: 1) to fix the water/binder ratio or 2) to fix the dosage of additives (superplasticizer and incorporating air). The same superplasticizer and incorporating air content were adopted during the dosage performing.

The choice of the superplasticizer content was made by analyzing the Kantro test, adopting for the initial dosage the saturation point. However, this value must be adjusted to the properties intended for the concrete, such as: consistency, durability and permeability. In face of these questions, it was determined a content of 0.5% for the mixtures without air incorporating agent. Next, for the mixtures with an air incorporator, the superplasticizer content was adapted to obtain the consistency of 100 ± 10 mm and the total volume of air at 6 ± 1%. Then, the contents of 0.25% of superplasticizer and 0.045% of air incorporator were set through several experiments. Finally, incorporated air content was adjusted using the gravimetrical method regulated by NBR 9833:198713.

Besides the analysis of each material, several alternatives regarding the sequence of mixture of the materials were carried out. Thus, the most suitable for this case study can be described according to the following stages, based on studies from Liborio and Castro8:

1) Mixture of coarse aggregates with silica fume and 10% of mixing water, blending for 2 minutes;

2) Addition of the small aggregate, Portland CP II 32 E cement, 70% of mixing water blending for 5 minutes;

3) Addition of the superplasticizer and air incorporator, for concrete with incorporating air and 10% of mixing water, blending for 2 minutes;

4) Addition of 10% of mixing water, blending for 2 minutes.

As we observed, this mixing sequence was suitable for doping coarse aggregates. More than this, it provided enough time for the beginning of the hydration reaction of the Portland cement. After that, superplasticizer and air incorporator were added, leading the additives to the surface of the binders which had already been absorbed in the aggregate walls. This procedure reduces the waste of tensoative volume while it is involved in aggregates not covered with cement paste.

From the data obtained in the dosage, the dosage abacus in Figure 5 was outlined. Based on that, the definitive feature for the concrete without incorporated air and for the concrete with incorporated air was selected.

The specific mass of the concrete without incorporated air was ρ = 2.46 g/cm3 and for the concrete with incorporated air it was ρ = 2.32 g/cm3. The consistency of both concrete tested at low temperatures was the same, although the workability of the concrete with incorporated air was better. This fact can be attributed to the presence of air bubbles that facilitate the mixture, the launching and the densification of the concrete. These characteristics of the concrete with incorporated air were confirmed while molding cylindrical specimens, mainly the prismatic specimens.

Soon after the molding, the exposed surface of the specimens was saturated by water and covered by a plastic wrap in order to prevent plastic, autogenous and drying retractions. Concretes were cured in a humid chamber after the unmolding process. The cylindrical specimens were cured by the 1st, 7th and 28th days when they were tested to determine the resistance to compression and the prismatic specimens were cured for 28 days.

The mortar content Mortar content is defined as α = (1+a)/(1+a+p), where α is mortar content, "a" is the ratio of small aggregate and "p" is the ratio of coarse aggregate. was determined at 56%. At this point, mortar can get a cohesive mixture, have a good superficial finish and be easily handled with the materials employed in this study.

Since the early beginnings of the HPC project, some parameters were established: consistency, dosage of additives, binder composition, mortar content, cement consumption, ratio water/binder and ratio 1: m. Then, according to these parameters, the features expected at concrete exposed to low temperatures were defined, as shown in

The results of the compressive strength tests for this concrete are presented in Table 4.

3.4. Tests to determine the natural frequency of vibration

Determining the natural frequency of vibration in concrete specimens was performed according to ASTM C215–9115 (Standard test method is basic transverse, longitudinal and torsional frequencies of concrete specimens) recommendations using the Resonance for Impact method. The equipment necessary for performing the test was a piezoelectric accelerometer (Brüel & Kjaer mark, model 4383), a small hammer and an acquisition and data analysis computerized system, by Vishay manufacturer, model System 6000. The specimens were supported by the nodal points so that they could vibrate freely. Metallic springs with natural frequency lower than the frequency found in the specimens were employed. The vibration caused by hammer impact was measured by the accelerometer, fixed by a magnet on a metallic plate previously glued to the specimens. Signals with an acquisition rate of 10 kHz were recorded.

Piezoelectric accelerometer is generally used to measure vibrations, due to its small size, good sensitivity to measurements and capacity to identify a wide range of vibration frequencies. They are also self–generating signals and they do not need any power supply. Basically, they consist of a base, a piezoelectric crystal and a seismic mass, as shown in Figure 6. The piezoelectric crystal contains molecules with asymmetric electric charge distribution. When pressure is applied, the crystal deforms and a relative movement of positive and negative charges inside of the crystal takes place. As a result, electric charges with opposite signals are produced on the two surfaces of the crystal. Thus, when the crystal is deformed by mechanical force, it generates an electric signal proportional to its deformation.


Inside of the accelerometer, the seismic mass always compresses the crystal. So, during vibration, this compression force can increase or diminish, depending on the intensity and the direction of the vibration, generating a signal (electric charge) that can be related (using calibration) to the seismic mass acceleration. Then, the electric signals the accelerometer are sent to a data acquisition system, converted to acceleration values due to the time, registered and processed in order to obtain the natural frequencies.

Through the processing, the acceleration amplitude signal in the time domain is converted into the frequency domain using the Fast Fourier Transformer algorithm (FFT – Fast Fourier Transformer). This way, acceleration amplitude signal due to time, that is a periodic signal, is written as a sum of the harmonic functions of sine and co–sine. Thus, obtaining the transversal, longitudinal and torsional frequencies depends of an appropriate location of the superficial accelerometer on the specimens.

For this research, eighteen specimens were used: 9 in concrete with incorporated air and 9 in concrete without incorporated air. They were all tested to determine the natural frequency. In each series, eight specimens were kept in a cold chamber. At the same time, one specimen was left at room temperature. Doing that allowed comparing the natural frequencies obtained from concrete exposed to low temperatures and from concrete under normal temperature conditions.

The cooling curve of the specimens is illustrated in Figure 7. The cooling rate was calculated at –0.11 °C/min.


Figure 8 shows the test to determine the natural transversal frequency of the specimens.


The values of the natural frequencies were obtained by reading a Cartesian coordinate system (X, Y), made from a signal conversion system. The abscissa (x–axis) represents the natural frequency and the ordinate (y–axis) the amplitude. Figure 9 displays the corresponding graphs to the initial, intermediate and final readings. It also shows what was observed after the thawing of specimen from each series.


The results observed during these tests are shown in Table 5, where the two series can be seen: concrete with incorporated air and without incorporated air. The specimen of each series left outside of the cold chamber is identified by the acronym (CTRL). This procedure makes possible to examine the natural frequency differences found in concrete exposed to low temperatures and to normal temperature conditions.

Figure 10 shows the evolution of the natural frequency for each specimen in a graph.


After natural frequency values became stable, a reading was taken on the thirty–fifth day of low temperature exposure. Next, the specimens were left at room temperature until they recovered thermodynamic balance, that is, reach room temperature. Table 6 shows the natural frequency values of the concrete specimens at room temperature before and after the period they were exposed to low temperatures.

The results in Table 6 are represented graphically in Figure 11.


These results proved that, even under temperatures of –35 °C, the integrity of the specimens from both concrete (with incorporated air and without incorporated air) was preserved.

3.5. Discussion of the results

According to the results concerning the natural transversal frequency for the specimens, made from concrete with incorporated air and without incorporated air, it can be concluded that both demonstrated durability when subjected to –35 °C temperature environments.

However, deformations were registered throughout the freezing period. These deformations were caused by expansions and contractions but they did not damage the concrete. As the tests have demonstrated, concrete elastic properties were preserved until the end of the period, as well as after the specimens thawing.

By interpreting the concrete behavior throughout this test program, it became possible to relate deterioration mechanisms to freezing action, attributed to the generation of hydraulic pressure and the diffusion of water–gel and capillary water, based on the theory proposed by Powers3 and Powers and Helmulth2.

The specimens were constantly exposed to the cooling rate of 0.11 °C/min (the temperature of –35°C), which was considered slow. Moreover, the temperature was less than necessary to freeze water in normal conditions of temperature and pressure. The aforementioned are factors that infer the phenomenon of diffusing water–gel and capillary water to the behavior of the concrete which has been evaluated.

The previous conclusion is supported by the fact that all the specimens contracted initially. Actually, the specimens with incorporated air showed expansion just after the 21st day of exposure while the specimens without incorporated air started expanding on the 7th day.

Therefore, in the beginning, besides the thermal contraction, the depletion of water–gel derived from the diffusion phenomenon, caused the observed contraction. By its turn, the time required for equalizing the free energy of water–gel and the capillary ice can be pointed as a reason for the different contraction period verified in concrete with incorporated air and concrete without incorporated air.

To illustrate, in the concrete with incorporated air, the proximity of the water film absorbed in the gel, with the air voids, made the balance of energy levels being reached in a quicker way, preventing the capillary ice growth and, consequently the paste break–up.

In the concrete without incorporated air, the depletion of water–gel to capillaries smaller than air bubbles results in higher superficial tension. Consequently, there is an increase in the energy level of the capillary ice, what helps its growth, causing the capillary wall deformation.

Even the presence of air voids in the concrete with incorporated air was not enough to stop the ice crystals growing or the hydraulic pressure resulted from the water–gel depletion to the capillaries and air voids. Then, the expansion could not be avoided although this fact has been harmless to the good performance of the concrete when frozen (i.e. the deformations did not affect the specimens stiffness).

In order to suppress any residual deformation (expansion) and to assure that contraction took place from the beginning to the end of the freezing period, two procedures were proposed. The first is the improvement of the voids distribution and it should be applied to concrete with incorporated air. The second, related to concrete without incorporated air, is the mortar reinforcement to increase the tensile strength of the concrete. This last one should be checked, though.

The cooling rate, target temperature and constant temperature condition must be recognized as significant factors in the predominance of the diffusion phenomenon. On the other hand, there are other important aspects that were really effective for preventing damage caused by the generated hydraulic pressure in the concrete studied.

One of these aspects is the amount of frozen water. Powers4 demonstrated that the value 0.25 is the maximum concrete ratio water/binder in which concrete without incorporated air resists freezing. Lang and Ward15, amongst others, also confirmed this assumption. However, the ratio water/binder of 0.42, proposed at this research, was higher than the one suggested by the previous authors. Even the concrete without incorporated air was durable when frozen, showing the efficiency of the hydration process, since it consumed the frozen water. Moreover, the pore refinement was certainly a considerable factor concerning concrete durability when frozen. This is because pore refinement causes an increase in the superficial tension in the water stored or led to these voids, which means a lower temperature of freezing.

Although the pore refinement can be attributed to mineral additions (i.e. active silica), it is important to emphasize that the cement bulk reinforcement was due to the biggest amount of C–S–H produced. This resulted from the pozzolanic reaction activated by these additions – Melo16. This property was also favorable to a longer freezing period.

Progress in concrete technology, made possible by binder assembling, favors the concrete performance even under adverse conditions. This is an unquestionable fact and of great importance for effective performance, due to the difference between the available binders nowadays and in the past. The binders, employed by Powers to develop the presented theories, used to freeze all the stored water (i.e. capillary water and water contained in the cavities in concrete with a water/binder of 0.30 at –15 °C. In 1998, Ukamoto and Uomoto17, by their turn, produced mortars with water/binder of 0.30 at a temperature of –20 °C, and showed that the water just froze in pores bigger than 0.05 μm.

The stiffness (i.e. measured by the natural transversal frequency) in concrete with and without incorporated air exposed to a temperature of –35 °C was preserved. Generated hydraulic pressure, attributed to the movement of capillary water, could be harmful but any damage to the concrete stiffness was registered. This is evidence that the pores were refined. Based on Ukamoto and Uomoto19, it can be concluded that a great amount of the pores in this concrete is smaller than 0.05 μm.

Similarly, the hydraulic pressure phenomenon was minimized by the advanced degree of hydration, reached after a 28 day curing period in a humid chamber. Furthermore, the actions to prevent the plastic, drying and autogenous retractions – as soon as the specimens were taken out from the molds and put in the humid chamber – were essential for the durability of the concrete exposed to low temperatures.

Other factors were relevant to obtain concrete durability at low temperatures. They were important when developing cohesive concrete, little permeable and with some improvement in the interface paste/aggregate zone. These were obtained by a suitable method of dosage and concrete mixing.

4. Conclusions

The result of the experiment of freezing concrete with and without incorporated air showed that both were resistant to environments in these conditions, demonstrating that the concrete is an excellent alternative material to build storage systems and conserve food.

The result of the experiment on freezing concrete with and without incorporated air showed that both were resistant to environments in these conditions. This demonstrated the concrete is an excellent alternative material to build storage and conservation food systems.

The concrete without incorporated air was resistant to the damage caused by freezing described and demonstrated by Powers2 and Powers and Helmuth3. It also showed that the air incorporation is unnecessary as well as the limitation of the ratio w/b (water/binder) at 0.24 in concrete developed according to techniques proposed by Liborio7 and proved by the group of researchers at the Laboratory of Advanced Materials of Cement at the School of Engineering in São Carlos at the University of São Paulo.

Acknowledgments

The authors would like to thank the group of researchers at the Laboratory of Advanced Materials of Cement at the School of Engineering in São Carlos at the University of São Paulo, the University of São Paulo and CNPq – National Counsel of Technological and Scientific Development.

Received: January 25, 2007; Revised: April 4, 2008

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  • Mortar content is defined as α = (1+a)/(1+a+p), where α is mortar content, "a" is the ratio of small aggregate and "p" is the ratio of coarse aggregate.
  • Publication Dates

    • Publication in this collection
      16 July 2008
    • Date of issue
      June 2008

    History

    • Received
      25 Jan 2007
    • Reviewed
      04 Apr 2008
    ABM, ABC, ABPol UFSCar - Dep. de Engenharia de Materiais, Rod. Washington Luiz, km 235, 13565-905 - São Carlos - SP- Brasil. Tel (55 16) 3351-9487 - São Carlos - SP - Brazil
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