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Materials Research

Print version ISSN 1516-1439

Mat. Res. vol.16 no.3 São Carlos May/June 2013  Epub Mar 08, 2013

http://dx.doi.org/10.1590/S1516-14392013005000035 

The effect of TTNT nanotubes on hydrogen sorption using MgH2

 

 

Mariana Coutinho Brum; Paula Mendes Jardim; Monique Osorio Talarico da Conceição*; Dilson Silva dos Santos

Programa de Engenharia Metalúrgica e de Materiais - PEMM, Instituto Alberto Luiz Coimbra de Pós-Graduação e Pesquisa de Engenharia - COPPE, Universidade Federal do Rio de Janeiro - UFRJ, Rio de Janeiro, RJ, Brasil

 

 


ABSTRACT

Nanotubes are promising materials to be used with magnesium hydride, as catalysts, in order to enhance hydrogen sorption. A study was performed on the hydrogen absorption/desorption properties of MgH2 with the addition of TTNT (TiTanate NanoTubes). The MgH2-TTNT composite was prepared by ball milling and the influence of the TTNT amount (1.0 and 5.0 wt. (%)) on the hydrogen capacity was evaluated. The milling of pure MgH2 was performed for 24 hours and afterwards the MgH2-TTNT composite was milled for 20 minutes. Transmission Electronic Microscopy (TEM) and Scanning Electron Microscopy (SEM) were used to evaluate the nanotube synthesis and show the particle morphology of the MgH2-TTNT composite, respectively. The Differential Scanning Calorimetry (DSC) examination provided some evidence with the shifting of the peaks obtained when the amount of TTNT is increased. The hydrogen absorption/desorption kinetics tests showed that the TTNT nanotubes can enhance hydrogen sorption effectively and the total hydrogen capacity obtained was 6.5 wt. (%).

Keywords: hydrogen storage materials, magnesium hydride, mechanical milling, nanotubes


 

 

1. Introduction

Mg is an abundant metal and has a high capacity to store hydrogen (~7.6 wt. (%)) and for these reasons it is very attractive to be used in hydrogen storage. However, there are limitations in practical applications due to the low absorption/desorption kinetics and high service temperature. The development of a nanocatalyst that combined with magnesium hydride can help to overcome such limitations is much studied nowadays. Nanotubes have been studied1,2 for the past decade and showed to be effective catalysts for hydrogen storage using magnesium3-8. However, most of the studies reveal the use of carbon-based nanotubes and not much has been investigated on the use of nanotube made from titanium oxide. The investigation of the hydrogen absorption/desorption properties of MgH2 with the addition of TTNT (TiTanate NanoTubes) has been performed in the present work.

 

2. Experimental

The TTNT nanotubes were synthesized via alkaline hydrothermal route using commercial TiO2 powder as a starting material dispersed in NaOH 10 M. The mixture was stirred for 24 hours at 120 ºC and washed with water in order to remove the unreacted NaOH9. Transmission electron microscopy (TEM) images of the synthesized product were recorded by using a JEOL 2010 equipment. The MgH2 powder supplied by Sigma-Aldrich was ball milled with tungsten carbide balls under H2 atmosphere for 24 hours at 300 rpm using a Fritsch P-6 planetary mill. After that, the MgH2 was milled for 20 minutes more with 1 and 5 wt. (%) of TTNT. The samples were handled in a glove box under argon atmosphere. The hydride phase stability was examined by using a differential scanning calorimeter (DSC- Setaram) under argon atmosphere. The kinetics tests were performed by an automatic Sievert's type apparatus designed by PCT-Pro 2000. The MgH2-TTNT morphology was analyzed by using scanning electron microscopy (SEM - JEOL JSM 6460LV). The hydrogen absorption and desorption measurements were performed at 10 bar and 0.1 bar of hydrogen pressure, respectively, at 350 ºC.

 

3. Results and Discussion

The TTNT sample showed extensive formation of nanotubes (Figure 1a). TTNT nanotubes were open-ended tubes as shown in Figure 1b with multiple 3-5 walls and diameter around 10 nm.

 

 

The SEM image on Figure 2a of the MgH2 + 5 wt. (%) TTNT sample showed an agglomerate of small particles with size ranging from several nanometers to micrometers. Based on the EDS result, Ti is present in MgH2 associated to the TTNT and the presence of Au is due to the coating performed during sample preparation (Figure 2b).

 


 

Figure 3 shows the DSC curves for MgH2 after being milled with TTNT catalyst and without the catalyst at a heating rate of 10 K/min. Endothermic peaks were observed for all samples. A peak at 665 K was obtained for the MgH2 + 5 wt. (%) TTNT sample. A similar behavior was observed when the same amount of boron nitride nanotube was used5. During milling high-pressure metastable γ-MgH2 (orthorhombic) was partially formed from β-MgH2 phase. The γ-phase disappears in the first desorption and it is not formed again in the following hydrogenation cycle10. The DSC curve of MgH2 + 1 wt. (%) TTNT sample shows two peaks which correspond to the decomposition of these two hydride phases at different temperatures (676 and 730 K). However, the MgH2 + 5 wt. (%) TTNT sample showed only one peak related to hydrogen decomposition (665 K). Although the DSC curve of this sample showed only one peak, the two hydride phases (β-MgH2 and γ-MgH2) are also present in this sample but the hydride decomposition temperature of each phase are so close that occurs overlapping of these peaks.

 

 

The hydrogen absorption/desorption kinetics of samples were investigated at 350 ºC under an initial pressure of 10 bar for absorption and 0.1 bar for desorption (Figure 4a, b). The sample with a smaller amount of TTNT, MgH2 + 1 wt. (%) TTNT, attained 5.2 wt. (%) of hydrogen in 5 minutes. The MgH2 without catalyst sample attained almost the same capacity but only in 30 minutes at 350 ºC (Figure 4a). This result suggests that the addition of TTNT enhanced the absorption kinetics. However, when more catalyst was added, the MgH2 + 5 wt. (%) TTNT sample, the hydrogen capacity decreased to 4.5 wt. (%) of hydrogen in 5 minutes. The desorption results represented in Figure 4b show the same behavior verified in the absorption ones where the MgH2 + 1 wt. (%) TTNT sample showed the highest hydrogen absorption capacity. However, the increase of the catalyst addition favored the hydrogen desorption kinetics and this result can be correlated to the DSC one since the hydrogen desorption occurs at a lower temperature for the sample containing more catalyst. The comparison between the results obtained for the MgH2 milled without catalyst and the MgH2 with addition of only 1 wt. (%) of TTNT, revealed an enhancement of the hydrogen absorption/desorption kinetics when the catalyst was added. This can be attributed to the fact that the hydrogen diffusion on nanotubes occurs preferably along the nanotube length than in the radial direction1,11. This is based on the fact that the hydrogen molecules penetration is more likely to occur on the channels along the tube than on the walls that are formed by a dense layer of TiO6 octhaedrons1. In the present work, only a small amount of the titante nanotube catalyst, 1 wt. (%), was required to obtain a high adsorption capacity value. For this reason the material could be used as a catalyst and is more effective when compared to the same amount of other catalyst, niobium oxide, used previously in the same conditions and that presented a capacity of only 1.7 wt. (%) in 5 minutes12, in contrast to the value of 6.5 wt. (%) obtained here.

 

4. Conclusions

Titanate nanotubes (TTNT) synthesized using titanium oxide as precursor were used as catalysts to enhance hydrogen sorption. The kinetics tests were conducted with two amounts of TTNT (1 and 5 wt. (%)) at 350 ºC. TTNT nanotubes showed to be a promising catalyst for this purpose since they improved the kinetics and hydrogen capacity when compared to the MgH2 without catalyst from 5.5 wt. (%) to 6.5 wt. (%) when only 1 wt. (%) of TTNT is added, at 350 ºC.

 

Acknowledgements

The authors thank FINEP, CNPq, CAPES, for their financial support.

 

References

1. Bavykin DV, Lapkin AA, Plucinski PK, Friedrich JM and Walsh FC. Reversible storage of molecular hydrogen by sorption into multilayered TiO2 nanotubes. Journal of Physical Chemistry B. 2005;109:19422. http://dx.doi.org/10.1021/jp0536394        [ Links ]

2. Lim SH , Luo J , Zhong Z, Ji W and Lin J. Room-temperature hydrogen uptake by TiO2 nanotubes. Inorganic Chemistry. 2005;44(12):4124. http://dx.doi.org/10.1021/ic0501723        [ Links ]

3. Chen D, Chen L, Liu S, Ma CX, Chen DM and Wang LB. Microstructure and hydrogen storage property of Mg/MWNTs composites. Journal of Alloys and Compounds. 2004;372(1-2):231. http://dx.doi.org/10.1016/j.jallcom.2003.08.104        [ Links ]

4. Yao X, Wu C, Du A, Zou J, Zhu Z, Wang P et al. Metallic and Carbon Nanotube-Catalyzed Coupling of Hydrogenation in Magnesium. Journal of the American Chemical Society. 2007;129(50):15650. http://dx.doi.org/10.1021/ja0751431        [ Links ]

5. Wu CZ, Wang P, Yao X, Liu C, Chen DM, Lu GQ et al. Effect of carbon/noncarbon addition on hydrogen storage behaviors of magnesium hydride. Journal of Alloys and Compounds. 2006;414:259. http://dx.doi.org/10.1016/j.jallcom.2005.07.021        [ Links ]

6. Wu CZ, Wang P, Yao X, Liu C, Chen DM, Lu GQ et al. Hydrogen storage properties of MgH2/SWNT composite prepared by ball milling. Journal of Alloys and Compounds. 2006;420(1-2):278. http://dx.doi.org/10.1016/j.jallcom.2005.10.028        [ Links ]

7. Skripnyuk VM, Rabkin E, Bendersky LA, Magrez A, Carreño-Morelli E and Estrin Y. Hydrogen storage properties of as-synthesized and severely deformed magnesium - multiwall carbon nanotubes composite. International Journal of Hydrogen Energy. 2010;35(11):5471. http://dx.doi.org/10.1016/j.ijhydene.2010.03.047        [ Links ]

8. Reyhani A, Mortazavi SZ, Mirershadi S, Golikand AN and Moshfegh AZ. H2 adsorption mechanism in Mg modified multi-walled carbon nanotubes for hydrogen storage. International Journal of Hydrogen Energy. 2012:37(2):1919. http://dx.doi.org/10.1016/j.ijhydene.2011.05.085        [ Links ]

9. Morgado Junior E, Abreu MAS, Pravia ORC, Marinkovic BA, Jardim PM, Rizzo FC et al. A study on the structure and thermal stability of titanate nanotubes as a function of sodium content. Solid State Sciences. 2006;8(8):888. http://dx.doi.org/10.1016/j.solidstatesciences.2006.02.039        [ Links ]

10. Wang P, Wang AM, Wang YL, Zhang HF and Hu ZQ. Decomposition behavior of MgH2 prepared by reaction ball-milling. Scripta Materialia. 2000;43(1):83. http://dx.doi.org/10.1016/S1359-6462(00)00370-5        [ Links ]

11. Liu F, Zhang X, Cheng J, Tu J, Kong F, Huang W and Chen C. Preparation of short carbon nanotubes by mechanical ball milling and their hydrogen adsorption behavior. Carbon. 2003;41(13):2527. http://dx.doi.org/10.1016/S0008-6223(03)00302-6        [ Links ]

12. Da Conceição MOT, Brum MC, Dos Santos DS and Dias ML. Hydrogen sorption enhancement by Nb2O5 and Nb catalysts combined with MgH2. Journal of Alloys and Compounds. 2013;550(1):179-184. http://dx.doi.org/10.1016/j.jallcom.2012.09.094        [ Links ]

 

 

Received: January 6, 2013
Revised: January 28, 2013

 

 

* e-mail: monique@metalmat.ufrj.br

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