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Optical and Electrical Properties of (002)-Oriented ZnO Films Prepared on Amorphous Substrates by Sol-Gel Spin-Coating

Abstract

Zinc oxide (ZnO) films were prepared on amorphous quartz substrates by sol-gel spin-coating using Zn(CH3COO)2•2H2O precursor. Isopropanol, ethanol and 2-methoxyethanol were used as solvents. The film drying temperature was kept constant at 200 ºC and the annealing temperature was varied from 400 to 800 ºC. Highly transparent and (002)-oriented hexagonal wurtzite-type ZnO films were obtained using isopropanol solvent. The ZnO films prepared at Tanneal = 600 ºC showed the highest (002) preferential orientation, however it was not the significant feature to achieve low resistivity. The uniform and (002)-oriented ZnO films prepared at Tanneal = 400 ºC display the highest transmittance (>93% in the visible region) and the lowest resistivity (7.1 Ω•cm).

Keywords:
Zinc oxide films; Oriented films; Transparent and conductive films


1. Introduction

Cost-effective transparent conductive oxide (TCO) films are increasingly demanded for a number of electronic devices such as solar cells, flat panel displays and light-emitting diodes11 Xu WZ, Ye ZZ, Zeng YJ, Zhu LP, Zhao BH, Jiang L, et al. ZnO light-emitting diode grown by plasma-assisted metal organic chemical vapor deposition. Applied Physics Letters. 2006;88(17):173506.. So far, tin-doped indium oxide (ITO) is the most common TCO owing to its superior electrical conductivity and optical transmission. However, the success of ITO is limited by the high cost, toxicity and scarcity of indium22 Zheng K, Guo Q, Wang EG. A buffer layer for ZnO film growth on sapphire. Surface Science. 2008;602(14):2600-2603.

3 Elangonvan E, Ramamurthi K. A study on low cost-high conducting fluorine and antimony-doped tin oxide thin films. Applied Surface Science. 2005;249(1-4):183-196.
-44 Musat V, Teixeira B, Fortunato E, Monteiro RCC, Vilarinho P. Al-doped ZnO thin films by sol-gel method. Surface and Coatings Technology. 2004;180-181:659-662.. In search of alternative materials, ZnO has attracted much attention because of its relatively low cost, wide band gap of 3.37 eV, large exciton binding energy (60 meV) and distinctive surface effect (1.53 eV surface band bending)55 Chen CY, Retamal JR, Wu IW, Lien DH, Chen MW, Ding Y, et al. Probing surface band bending of surface-engineered metal oxide nanowires. ACS Nano. 2012;6(11):9366-9372.. Thus, ZnO thin films have been prepared by a large number of techniques such as chemical bath deposition66 Kurbanov SS, Jeon HC, Shaymardanov ZS, Rakhimov RY, Kang TW. Photoluminescence from porous textured ZnO films grown by chemical bath deposition. Journal of Luminescence. 2016;170(Pt 1):168-173., sputtering77 Treharne RE, Durose K. Fluorine doped ZnO thin films by RF magnetron sputtering. Thin Solid Films. 2011;519(21):7579-7582., SILAR88 Ravichandran K, Rajkumar PV, Sakthivel B, Swaminathan K, Chinnapa L. Role of precursor material and annealing ambience on the physical properties of SILAR deposited ZnO films. Ceramics International. 2014;40(8, Part A):12375-12382., spray pyrolysis99 Muruganantham G, Ravichandran K, Saravanakumar K, Swaminathan K, Begum NJ, Sakthivel B. Effect of solvent volumen on the physical properties of sprayed fluorine-doped zinc oxide thin films. Crystal Research and Technology. 2012;47(4):429-436., chemical vapor deposition (CVD)1010 Anusha M, Arivuoli D. High intense violet luminescence in fluorine doped zinc oxide (FZO) thin films deposited by aerosol assisted CVD. Journal of Alloys and Compounds. 2013;580:131-136. and sol-gel1111 Tsay CY, Hsu WT. Sol-gel derived undoped and boron-doped ZnO semiconductor thin films: Preparation and characterization. Ceramics International. 2013;39(7):7425-7432.. Among these, sol-gel spin-coating has received increasing attention because it is a simple and cost-effective process for the preparation of uniform oxide films with adequate control of their morphology, structure and stoichiometry1212 Mahroug A, Boudjadar S, Hamrit S, Guerbous L. Structural, optical and photocurrent properties of undoped and Al-doped ZnO thin films deposited by sol-gel spin coating technique. Materials Letters. 2014;134:248-251.. The electrical conductivity and optical properties of ZnO thin films have been associated with the increase of (002)-orientation degree of its hexagonal-wurtzite crystal structure22 Zheng K, Guo Q, Wang EG. A buffer layer for ZnO film growth on sapphire. Surface Science. 2008;602(14):2600-2603.,1313 Jensen JM, Oelkers AB, Toivola R, Johnson DC. X-ray reflectivity characterization of ZnO/Al2O3 multilayers prepared by atomic layer deposition. Chemistry of Materials. 2002;14(5):2276-2282.-1414 Ku CS, Lee HY, Huang JM, Lin CM. Epitaxial growth of ZnO films at extremely low temperature by atomic layer deposition with interrupted flow. Materials Chemistry and Physics. 2010;120(2-3):236-239.. Transparent and conductive (002)-oriented ZnO films have been prepared by sol-gel spin-coating, however, the use of single crystal substrates and doping elements have been required1515 Sahal M, Hartiti B, Ridah A, Mollar M, Marí B. Structural, electrical and optical properties of ZnO thin films deposited by sol-gel method. Microelectronics Journal. 2008;39(12):1425-1428.

16 Basak D, Amin G, Mallik B, Paul GK, Sen SK. Photoconductive UV detectors on sol-gel-synthesized ZnO films. Journal of Crystal Growth. 2003;256(2-1):73-77.
-1717 Sharma R, Sehrawat K, Mehra RM. Epitaxial growth of highly transparent and conducting Sc-doped ZnO films on c-plane sapphire by sol-gel process without buffer. Current Applied Physics. 2010;10(1):164-170.. In addition, undoped and (002)-oriented ZnO films grown on amorphous substrates by sol-gel have also been reported to show relatively attractive electrical and optical properties1818 Fujihara S, Sasaki C, Kimura T. Crystallization behavior and origin of c-axis orientation in sol-gel-derived ZnO:Li thin films on glass substrates. Applied Surface Science. 2001;180(3-4):341-350.,1919 Lee JH, Ko KH, Park BO. Electrical and optical properties of ZnO transparent conducting films by the sol-gel method. Journal of Crystal Growth. 2003;247(1-2):119-125.. In this study, it is shown that the (002)-orientation is not the significant feature to achieve low resistivity in ZnO films prepared by sol-gel spin-coating on amorphous substrates.

2. Experimental

Zinc oxide precursor solutions were prepared from zinc acetate dihydrate (Zn(CH3COO)2•2H2O, Sigma-Aldrich, purity ≥ 98%) as metal source, monoethanolamine (C2H7NO, Sgima-Aldrich, purity ≥ 99.0%) as a stabilizer, and three different alcohols; isopropanol (C3H8O, Sigma-Aldrich, purity 99.5% ), 2-methoxyethanol (C3H8O2, Sigma-Aldrich, purity ≥ 99.5%), and ethanol (C2H6O, Reactivos Analíticos, purity 99.7%), as solvents. First, the stabilizer agent and separately individual solvent were mixed by magnetic stirring at 50 ºC for 10 min. Then, the metal precursor was dissolved in the previous mixture at 60 ºC for 2 h to obtain 0.5 mol·L-1 Zn(CH3COO)2•2H2O solutions. The stabilizer to metal source molar ratio was kept constant at 1 (RMEA = 1). Regardless of solvent, the resultant solutions were clear without any precipitates. The resultant solutions were aged for 24 h at room temperature before the film preparation. ZnO films were prepared on quartz substrates 25 mm × 25 mm × 1 mm in size. Previous to film preparation, the quartz substrates were sequentially cleaned with acetone, ethanol and deionized water by using ultrasonic bath. Then, the substrates were blown dried using dry air. Appropriate spin-coating parameters to prepare the films were as follows: 300 rpm for 5 s and then 3000 rpm for 30 s. Films thus prepared were dried at 200 ºC for 10 min in air by using a horizontal-tubular furnace. Multi-layers films were prepared by sequentially repeating the spin-coating and drying steps for 5 times. Annealing treatment of multi-layer films was performed from 400 to 800 ºC for 2 h in air. The heating rate was kept at 10 ºC/min. The film surface morphology was examined by using a field emission scanning electron microscope (FESEM; JEOL JSM-6071F). The crystalline structure of films was investigated by X-ray diffraction (XRD; BRUKER D8 Advanced) coupled with grazing geometry using an incident X-ray beam from 0.5º to 3.0º. For transmission electron microscopy (TEM; JEOL JEM ARM 200CF) observations, the films were removed from the quartz substrate and then, the collected flakes were dispersed in isopropanol using an ultrasonic bath. A sample of the suspension was then taken and deposited on Cu grid (Tedpella). The optical transmittance of films was measured by UV-vis spectroscopy (Perkin Elmer Lambda 35) in the wavelength range of 200 - 800 nm at room temperature. Photoluminescence, PL characteristics, at room temperature, were measured employing a He:Cd laser (λ = 325 nm) as excitation source, a double monochromator (1403-SPEX) and a photomultiplier detector (RCA-C310334). The uncoated quartz substrate was used as a blank reference for base line determination. The sheet resistance, R of films was measured by the four-point method at room temperature on three different locations for every sample using a KEITHLEY 2601A source/meter instrument. The film resistivity was calculated from ρ = R × t, where "t" is the film thickness and "R" is the sheet resistance.

3. Results and discussion

Figure 1 (a) shows the effect of solvent type on the XRD patterns of ZnO films prepared at Tanneal = 600 ºC. All films are polycrystalline in nature with well-defined diffraction peaks corresponding to the (100), (002), (101), (102), (110), (103), (112) and (201) planes of the hexagonal wurtzite-type crystal structure of ZnO (JCPDS card 36-1451)1212 Mahroug A, Boudjadar S, Hamrit S, Guerbous L. Structural, optical and photocurrent properties of undoped and Al-doped ZnO thin films deposited by sol-gel spin coating technique. Materials Letters. 2014;134:248-251.. In particular, the ZnO films prepared with isopropanol and ethanol solvents exhibit high intensity of the (002) diffraction peak as demanded for optoelectronic film applications11 Xu WZ, Ye ZZ, Zeng YJ, Zhu LP, Zhao BH, Jiang L, et al. ZnO light-emitting diode grown by plasma-assisted metal organic chemical vapor deposition. Applied Physics Letters. 2006;88(17):173506.,22 Zheng K, Guo Q, Wang EG. A buffer layer for ZnO film growth on sapphire. Surface Science. 2008;602(14):2600-2603.. Isopropanol and ethanol are preferred as solvents in materials processing because of their less toxic nature for human and environment than 2-methoxyetanol2020 Al-Hardan NH, Jalar A, Abdul Hamind MA, Keng LK, Shamsudin R, Majlis BY. The room-temperature sensing performance of ZnO nanorods for 2-methoxyethanol solvent. Sensors and Actuators B: Chemical. 2014;203:223-228.. Figure 1 (b) shows the effect of annealing temperature on the XRD patterns of ZnO films prepared with isopropanol. As annealing temperature increases from 400 to 600 ºC, a remarkable high (002) diffraction intensity is observed indicating c-oriented ZnO films.

Figure 1
(a) Effect of solvent type on the XRD patterns of ZnO films prepared at Tanneal = 600 ºC (b) Effect of annealing temperature on the XRD patterns of ZnO films prepared with isopropanol.

The (002) preferential orientation of ZnO films was determined by using the Lotgering Factor LF as follows2121 Makiya A, Kusumi Y, Tanaka S, Kato Z, Uchida N, Uematsu K, et al. Grain oriented titania ceramics made in high magnetic field. Journal of the European Ceramic Society. 2007;27(2-3):797-799.:

(1) LF = P - P 0 1 - P 0

where P = I(002)/ΣI(hkl), and P0 = I0(002)/ΣI0(hkl). I and I0 are diffraction intensities of oriented and randomly oriented films, respectively. ΣI(hkl) and ΣI0(hkl) are the sum of all diffraction peak (hkl) intensities in the range of 20º < 2θ < 80º. The LF varies between zero to unity; LF = 0 corresponds to random orientation, and LF = 1 to perfect orientation. Figure 2 shows the LF values for the (002) diffraction peak of ZnO films prepared with isopropanol and 2-methoxyethanol as a function of annealing temperature. Below Tanneal = 600 ºC, ZnO films prepared with isopropanol exhibit higher LF values compared to those obtained with 2-methoxyethanol. Particularly, ZnO films prepared with isopropanol exhibit the highest LF of 0.57 at Tanneal = 600 ºC. At higher temperatures, however, ZnO films show less degree of (002) preferential orientation.

Figure 2
LF values for the (002) diffraction peak of ZnO films prepared with isopropanol and 2-methoxyethanol as function of annealing temperature.

Calculated values of lattice parameters and crystal size are summarized in Table 1. The lattice parameters a and c of the hexagonal structure were calculated by the following formula2222 Yilmaz M, Caldiran Z, Deniz AR, Aydogan S, Gunturkun R, Turut A. Preparation and characterization of sol-gel-derived n-ZnO thin film for Schottky diode application. Applied Physics A. 2015;119(2):547-552.:

(2) d hkl 2 = 4 h 2 + k 2 + hk 3 a 2 + l 2 c 2 - 1
Table 1
Lattice parameters and crystal size of ZnO films prepared at Tanneal = 400, 600 and 800 ºC.

where d is the interplanar distance and h,k,l are the Miller indices. The calculated lattice parameters are very close to those reported in the JCPDS card 36-1451 (a = 3.2498 Å, c = 5.2066 Å).

The mean crystal size was calculated by Scherrer's formula2323 Chen J, Chen D, He J, Zhang S, Chen Z. The microstructure, optical, and electrical properties of sol-gel-derived Sc-doped and Al-Sc co-doped ZnO thin films. Applied Surface Sciences. 2009;255(23):9413-9419.:

(3) D = 0 . 9 λ β cos θ

where D is the crystal size, β the full-width at half maximum of a distinctive peak (rad), θ the Bragg angle and λ = 1.5405 Å (Cu Kα). As indicated in Table 1, the crystal size increases with the annealing temperature.

Figure 3 shows TEM images at different amplifications of scratched sample taken from ZnO films prepared at Tanneal = 400 ºC. Figure 3 (a) reveals that ZnO films consist of equiaxial grains of around 20 nm, which is consistent with the crystal size calculated from the Scherrer's formula. High-resolution observations indicate an interplanar distance of 0.26 nm, in agreement with the (002) plane of ZnO hexagonal structure.

Figure 3
TEM images at different amplifications of scratched sample taken from ZnO films prepared at Tanneal = 400 ºC.

Figure 4 shows SEM images of the surface morphology and cross-section of ZnO films prepared with isopropanol at (a)-(d) Tanneal = 400 ºC, (b)-(e) Tanneal = 600 ºC and (c)-(f) Tanneal = 800 ºC. Films exhibit a granular surface morphology with a grain size notoriously increased from Tanneal = 600 ºC. From cross-section observations, the film thickness was found to be 280, 140 and 320 nm for ZnO films prepared at Tanneal = 400, 600 and 800 ºC, respectively. The relatively thick films obtained at Tanneal = 800 ºC could be related with a remarkable porous morphology suggested from the surface images. As indicated by XRD results, the 140 nm-thick ZnO films showed the highest (002) preferential orientation.

Figure 4
SEM images of the surface morphology and cross-section of ZnO films prepared with isopropanol at (a)-(d) Tanneal = 400 ºC, (b)-(e) Tanneal = 600 ºC and (c)-(f) Tanneal = 800 ºC.

Figure 5 shows the UV-vis transmittance spectra for ZnO films prepared with isopropanol as a function of annealing temperature. All films exhibited transmittance above 85 % in the visible region and a sharp fundamental absorption edge, as it has been previously observed2424 Yoon H, Choi H, Leem JY, Lee SH, Kim JS, Kim JS, Son JS. Optimizing the optical properties of fluorine-doped ZnO thin films deposited by sol-gel spin-coating. Journal of the Korean Physical Society. 2014;65(4):509-514.. In particular, ZnO films obtained at Tanneal = 400 ºC display the highest transmittance (>93%) in the visible region. At Tanneal = 600 and 800 ºC, however, the optical transmittance decreases, which could be attributed to the contribution of larger grain size (see Table 1).

Figure 5
UV-vis transmittance spectra for ZnO films prepared with isopropanol as a function of annealing temperature.

Figure 6 depicts the room-temperature photoluminescence spectra of ZnO films prepared at Tanneal = 400, 600 and 800 ºC. Two photoluminescence emission bands are evident in these spectra. One asymmetrical band with clear maximum at 438 nm, corresponding to 2.83 eV, is usually associated to interstitial zinc atoms2525 Marimuthu T, Anandhan N, Mahalingam T, Thangamuthu R, Mummoorthi M. Effect of P. Murex on the properties of spin coated ZnO thin films for dye sensitized solar cell applications. Journal of Materials Science: Materials in Electronics. 2015;26(10):7577-7587.. The broad band centered at 560 nm (2.21 eV), for films annealed at 400 and 800 ºC, might be assigned to oxygen vacancies in undoped ZnO2626 Bagnall DM, Chen YF, Shen MY, Zhu Z, Goto T, Yao T. Room temperature excitonic stimulated emission from zinc oxide epilayers grown plasma-assisted MBE. Journal of Crystal Growth. 1998;184-185:605-609.,2727 Allabergenov B, Tursunkulov O, Abidov AI, Choi B, Wook JS, Kim S. Microstructural analysis and optical characteristics of Cu-doped ZnO thin films prepared by DC magnetron sputtering. Journal of Crystal Growth. 2014;401:573-576.. Thus, the intensity of this band suggests that films annealed at 400 ºC may have higher amount of oxygen vacancies compared with the other films. Below 400 nm (375 nm, 3.30 eV), no evidence of the near-band-emission (NBE) was observed2828 Wang L, Giles NC. Temperature dependence of the free-exciton transition energy in zinc oxide by photoluminescence excitation spectroscopy. Journal of Applied Physics. 2003;94(2):973..

Figure 6
Photoluminescence spectra of ZnO films prepared at Tanneal = 400, 600 and 800 ºC.

Electrical resistivity of ZnO films prepared with isopropanol as a function of annealing temperature is shown in Figure 7. The electrical resistivity was found to increase from 7.1 to 1641.7 Ω·cm for Tanneal = 400 - 800 ºC. Previous studies have reported electrical resistivity for ZnO films in the range of 0.1 to 100 Ω·cm 1515 Sahal M, Hartiti B, Ridah A, Mollar M, Marí B. Structural, electrical and optical properties of ZnO thin films deposited by sol-gel method. Microelectronics Journal. 2008;39(12):1425-1428.,2929 Liu Y, Li Y, Zeng H. ZnO-Based Transparent Conductive Thin Films: Doping, Performance, and Processing. Journal of Nanomaterials. 2013;2013(10):1-9.. The appropriate annealing temperature to achieve the smallest resistivity was 400 ºC, which may have relationship with a high amount of oxygen vacancies. Thus, the favorable oriented growth along (002) plane of ZnO films prepared at Tanneal = 600 ºC is not related with low resistivity as suggested in the literature1515 Sahal M, Hartiti B, Ridah A, Mollar M, Marí B. Structural, electrical and optical properties of ZnO thin films deposited by sol-gel method. Microelectronics Journal. 2008;39(12):1425-1428.,1919 Lee JH, Ko KH, Park BO. Electrical and optical properties of ZnO transparent conducting films by the sol-gel method. Journal of Crystal Growth. 2003;247(1-2):119-125.,2929 Liu Y, Li Y, Zeng H. ZnO-Based Transparent Conductive Thin Films: Doping, Performance, and Processing. Journal of Nanomaterials. 2013;2013(10):1-9.. The film porosity might adversely influence the light and conductivity phenomena to hinder the positive effect of (002) preferential orientation in ZnO films. Here, the ZnO films with relatively smooth surface morphology and less degree (002) orientation, prepared at Tanneal = 400 ºC, show the most attractive optical and electrical properties.

Figure 7
Electrical resistivity of ZnO films prepared with isopropanol as a function of annealing temperature.

4. Conclusions

Highly transparent and (002)-oriented hexagonal wurtzite-type ZnO films were prepared on quartz substrates by sol-gel spin-coating using isopropanol solvent and zinc acetate precursor. In particular, ZnO films prepared at Tanneal = 600 ºC showed the highest (002) preferential orientation, however it was not the significant feature to achieve low resistivity. The uniform and (002)-oriented ZnO films prepared at Tanneal = 400 ºC display the highest transmittance (>93% in the visible region) and the lowest resistivity (7.1 Ω·cm).

5. Acknowledgements

This study was partially supported by IPN through the project SIP-20161803. One of the authors G.A. Velázquez-Nevárez gratefully acknowledges the scholarship from CONACYT for doctoral studies.

6. References

  • 1
    Xu WZ, Ye ZZ, Zeng YJ, Zhu LP, Zhao BH, Jiang L, et al. ZnO light-emitting diode grown by plasma-assisted metal organic chemical vapor deposition. Applied Physics Letters 2006;88(17):173506.
  • 2
    Zheng K, Guo Q, Wang EG. A buffer layer for ZnO film growth on sapphire. Surface Science 2008;602(14):2600-2603.
  • 3
    Elangonvan E, Ramamurthi K. A study on low cost-high conducting fluorine and antimony-doped tin oxide thin films. Applied Surface Science 2005;249(1-4):183-196.
  • 4
    Musat V, Teixeira B, Fortunato E, Monteiro RCC, Vilarinho P. Al-doped ZnO thin films by sol-gel method. Surface and Coatings Technology 2004;180-181:659-662.
  • 5
    Chen CY, Retamal JR, Wu IW, Lien DH, Chen MW, Ding Y, et al. Probing surface band bending of surface-engineered metal oxide nanowires. ACS Nano 2012;6(11):9366-9372.
  • 6
    Kurbanov SS, Jeon HC, Shaymardanov ZS, Rakhimov RY, Kang TW. Photoluminescence from porous textured ZnO films grown by chemical bath deposition. Journal of Luminescence 2016;170(Pt 1):168-173.
  • 7
    Treharne RE, Durose K. Fluorine doped ZnO thin films by RF magnetron sputtering. Thin Solid Films 2011;519(21):7579-7582.
  • 8
    Ravichandran K, Rajkumar PV, Sakthivel B, Swaminathan K, Chinnapa L. Role of precursor material and annealing ambience on the physical properties of SILAR deposited ZnO films. Ceramics International 2014;40(8, Part A):12375-12382.
  • 9
    Muruganantham G, Ravichandran K, Saravanakumar K, Swaminathan K, Begum NJ, Sakthivel B. Effect of solvent volumen on the physical properties of sprayed fluorine-doped zinc oxide thin films. Crystal Research and Technology 2012;47(4):429-436.
  • 10
    Anusha M, Arivuoli D. High intense violet luminescence in fluorine doped zinc oxide (FZO) thin films deposited by aerosol assisted CVD. Journal of Alloys and Compounds 2013;580:131-136.
  • 11
    Tsay CY, Hsu WT. Sol-gel derived undoped and boron-doped ZnO semiconductor thin films: Preparation and characterization. Ceramics International 2013;39(7):7425-7432.
  • 12
    Mahroug A, Boudjadar S, Hamrit S, Guerbous L. Structural, optical and photocurrent properties of undoped and Al-doped ZnO thin films deposited by sol-gel spin coating technique. Materials Letters 2014;134:248-251.
  • 13
    Jensen JM, Oelkers AB, Toivola R, Johnson DC. X-ray reflectivity characterization of ZnO/Al2O3 multilayers prepared by atomic layer deposition. Chemistry of Materials 2002;14(5):2276-2282.
  • 14
    Ku CS, Lee HY, Huang JM, Lin CM. Epitaxial growth of ZnO films at extremely low temperature by atomic layer deposition with interrupted flow. Materials Chemistry and Physics 2010;120(2-3):236-239.
  • 15
    Sahal M, Hartiti B, Ridah A, Mollar M, Marí B. Structural, electrical and optical properties of ZnO thin films deposited by sol-gel method. Microelectronics Journal 2008;39(12):1425-1428.
  • 16
    Basak D, Amin G, Mallik B, Paul GK, Sen SK. Photoconductive UV detectors on sol-gel-synthesized ZnO films. Journal of Crystal Growth 2003;256(2-1):73-77.
  • 17
    Sharma R, Sehrawat K, Mehra RM. Epitaxial growth of highly transparent and conducting Sc-doped ZnO films on c-plane sapphire by sol-gel process without buffer. Current Applied Physics 2010;10(1):164-170.
  • 18
    Fujihara S, Sasaki C, Kimura T. Crystallization behavior and origin of c-axis orientation in sol-gel-derived ZnO:Li thin films on glass substrates. Applied Surface Science 2001;180(3-4):341-350.
  • 19
    Lee JH, Ko KH, Park BO. Electrical and optical properties of ZnO transparent conducting films by the sol-gel method. Journal of Crystal Growth 2003;247(1-2):119-125.
  • 20
    Al-Hardan NH, Jalar A, Abdul Hamind MA, Keng LK, Shamsudin R, Majlis BY. The room-temperature sensing performance of ZnO nanorods for 2-methoxyethanol solvent. Sensors and Actuators B: Chemical 2014;203:223-228.
  • 21
    Makiya A, Kusumi Y, Tanaka S, Kato Z, Uchida N, Uematsu K, et al. Grain oriented titania ceramics made in high magnetic field. Journal of the European Ceramic Society 2007;27(2-3):797-799.
  • 22
    Yilmaz M, Caldiran Z, Deniz AR, Aydogan S, Gunturkun R, Turut A. Preparation and characterization of sol-gel-derived n-ZnO thin film for Schottky diode application. Applied Physics A 2015;119(2):547-552.
  • 23
    Chen J, Chen D, He J, Zhang S, Chen Z. The microstructure, optical, and electrical properties of sol-gel-derived Sc-doped and Al-Sc co-doped ZnO thin films. Applied Surface Sciences 2009;255(23):9413-9419.
  • 24
    Yoon H, Choi H, Leem JY, Lee SH, Kim JS, Kim JS, Son JS. Optimizing the optical properties of fluorine-doped ZnO thin films deposited by sol-gel spin-coating. Journal of the Korean Physical Society 2014;65(4):509-514.
  • 25
    Marimuthu T, Anandhan N, Mahalingam T, Thangamuthu R, Mummoorthi M. Effect of P. Murex on the properties of spin coated ZnO thin films for dye sensitized solar cell applications. Journal of Materials Science: Materials in Electronics 2015;26(10):7577-7587.
  • 26
    Bagnall DM, Chen YF, Shen MY, Zhu Z, Goto T, Yao T. Room temperature excitonic stimulated emission from zinc oxide epilayers grown plasma-assisted MBE. Journal of Crystal Growth 1998;184-185:605-609.
  • 27
    Allabergenov B, Tursunkulov O, Abidov AI, Choi B, Wook JS, Kim S. Microstructural analysis and optical characteristics of Cu-doped ZnO thin films prepared by DC magnetron sputtering. Journal of Crystal Growth 2014;401:573-576.
  • 28
    Wang L, Giles NC. Temperature dependence of the free-exciton transition energy in zinc oxide by photoluminescence excitation spectroscopy. Journal of Applied Physics 2003;94(2):973.
  • 29
    Liu Y, Li Y, Zeng H. ZnO-Based Transparent Conductive Thin Films: Doping, Performance, and Processing. Journal of Nanomaterials 2013;2013(10):1-9.

Publication Dates

  • Publication in this collection
    19 Dec 2016
  • Date of issue
    Dec 2016

History

  • Received
    29 Oct 2016
  • Accepted
    23 Nov 2016
ABM, ABC, ABPol UFSCar - Dep. de Engenharia de Materiais, Rod. Washington Luiz, km 235, 13565-905 - São Carlos - SP- Brasil. Tel (55 16) 3351-9487 - São Carlos - SP - Brazil
E-mail: pessan@ufscar.br