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Theoretical study of c-GaN/GaAs single heterojunction solar cells

ABSTRACT

In this work a theoretical study of electrical behavior for a c-GaN/GaAs heterostructure as a photovoltaic device through a two-dimensional (2D) finite element numerical simulation is presented for a first time. I-V curves and electrical parameters like short circuit current (Isc), open circuit voltage (Voc), fill factor (FF) and efficiency (η) were obtained for n-i-p and n-p heterostructures with different thicknesses and doping of the layers by modeling heterostructures with characteristics parameters of this materials previously reported. As a result, an increment on Isc was observed by extending the thickness of i-GaAs layer from 12 mA/cm2 for thinner heterostructures to a maximum of ~32 mA/cm2 for heterostructures with i-GaAs layer >3000 nm and a decrease in Voc and FF in the range from ~1.06 V and 0.89 for n-p heterostructures to 0.75 V and 0.7 respectively for thicker i-GaAs layers allowing estimate maximum efficiencies between 23 and 25% for n-i-p and n-p configurations, respectively. This study allows demonstrating the potential of this type of heterostructures for solar cells applications, considering the possibility of using p-doping GaAs substrates for photovoltaics based in GaN.

Keywords:
GaN/GaAs; heterostructures; TCAD modeling; I-V curves; solar cell

1. INTRODUCTION

At the last years, gallium nitride (GaN) has been considered a valuable material for development of photonic devices, due to its wide direct bandgap (3.2-3.4 eV), high absorption coefficient (105 cm-1 at the band edge) and radiation damage resistance [1[1] KANG, M.S., LEE, C.H., PARK, J.B., et al., “Gallium nitride nanostructures for light-emitting diode applications”, Nano Energy, v. 1, n. 3, pp. 391–400, 2012.,2[2] HARIMA, H., “Properties of GaN and related compounds studied by means of Raman scattering”, Journal of Physics Condensed Matter, v. 14, n. 38, pp. R967–R993, 2002.]. On photovoltaic matters, GaN has been suitable to get InGaN alloys and to design III-nitride multi-junction solar cell structures for greatest efficiency [3[3] BHUIYAN, A.G., SUGITA, K., HASHIMOTO, A., YAMAMOTO, A. “InGaN solar cells: Present state of the art and important challenges”, IEEE Journal of Photovoltaics, v. 2, n. 3, pp. 276–293, Jul. 2012.]. However, the experimental results have showed low conversion efficiency due to some challenges in fabrication of GaN films (such as p-type doping control [4[4] PERLIN, P., SUSKI, T., TEISSEYRE, H., et al., “Towards the identification of the dominant donor in GaN”, Physical Review Letters, v.75, n. 2, pp. 296–299, Jul. 1995.] and the lack of a suitable substrate [5[5] LIU, L., EDGAR, J.H. “Substrates for gallium nitride epitaxy”, Materials Science and Engineering R, v. 37, n. 3, pp. 61–127, 2002.]) and InGaN films (degradation of epitaxial quality at high In compositions [6[6] WU, M.H., CHANG, S.P., CHANG, S.J., et al., “Characteristics of GaN/InGaN double-heterostructure photovoltaic cells”, International Journal of Photoenergy. v. 2012, pp. 206174/1-5, 2012.]). At this point, gallium arsenide (GaAs) is an option that offers the possibility to evade both problems: p-GaN film and substrate. Nevertheless, there are some challenges in development of this heterostructures due to strain and defects originated on the interface by a large lattice constant mismatch between GaN and GaAs (~20% for cubic GaN [5[5] LIU, L., EDGAR, J.H. “Substrates for gallium nitride epitaxy”, Materials Science and Engineering R, v. 37, n. 3, pp. 61–127, 2002.]) and the mix of cubic and hexagonal phases in GaN [7[7] ZAINAL, N., NOVIKOV, S. V., AKIMOV, A. V., et al., “Hexagonal (wurtzite) GaN inclusions as a defect in cubic (zinc-blende) GaN”, Physica B: Condensed Matter, v. 407, n. 15, pp. 2964–2966, 2012.]. Although several studies have reported structural characterization of GaN/GaAs heterojunctions with cubic (c-GaN) or hexagonal GaN (h-GaN) layers growth over GaAs substrates [8[8] LIU, H.F., CHEN, H., LI, Z.Q., et al., “MBE growth and Raman studies of cubic and hexagonal GaN films on (001)-oriented GaAs substrates”, Journal of Crystal Growth, v. 218, pp. 191–196, 2000.9[9] MÖREKE, J., UREN, M.J., NOVIKOV, S.V., et al. “Investigation of the GaN-on-GaAs interface for vertical power device applications”, Journal of Applied Physics, v. 116, pp. 014502/1-6, 2014.], with photovoltaic purposes there is not reports.

Based on this, the present work proposes a theoretical study by a two-dimensional (2D) finite element numerical simulation of a n-i-p GaN/GaAs heterostructure using cubic GaN (c-GaN) to estimate its electrical behavior, efficiency potential and feasibility of such a heterojunction for application in photovoltaic devices. In order to obtain a realistic prediction of photoelectrical behavior on simulated devices, wavelength dependent refractive index and absorption coefficient for GaN and GaAs are modeled; beside this, a set of characteristic parameters and physical models for recombination, mobility, and bandgap narrowing are implemented in this study. The importance of this research lies in being the first photovoltaic cell proposal that addresses the use of these materials in a single heterojunction.

2. MATERIALS AND METHODS

Photovoltaic cells based on n-GaN/i-GaAs/p-GaAs heterostructures were modeled under different configurations by Silvaco Atlas TCAD Software. First, we explore the thickness effect of the layers whereas the doping was fixed at 1x1018, 1x1012 and 1x1019 atoms/cm-3 for n-, i-, and p-type layers, respectively, as shown in Figure 1a. And next, we fixed the doping of i-GaAs and p-GaAs layers and the thickness of the n-GaN layer at 300 nm; we changed the doping level in n-GaN layer for different thicknesses on i-GaAs and p-GaAs layers as shown in Figure 1b.

Figure 1
GaN/GaAs heterostructures simulated. (a) Thicknesses variation of the three layers, (b) variation on doping of n-GaN layer and thicknesses of i-GaAs and p-GaAs layers.

Modeling parameters for GaN and GaAs layers used in this simulations are summarized in Table 1. Wavelengh-dependent refractive index (n) and absorption coefficient (α) of GaN, were calculated with III-V compounds Adachi's model [10[10] PIPREK, J., Nitride semiconductor devices. Principles and simulation, 1 ed., Weinheim, WILEY-VCH Verlag GmbH & Co. KGaA, 2007.] and the equation proposed by Brown et al. [11[11] BROWN, G.F., AGER, J.W., WALUKIEWICZ, W., WU, J., “Finite element simulations of compositionally graded InGaN solar cells”, Solar Energy Materials and Solar Cells, v. 94, n. 3, pp. 478–483, 2010.], respectively:

(1) n ( E ) = A ( E p h E g ) −2 { 2 1 + E p h E g 1 E p h E g } + B
(2) α ( c m 1 ) = 10 5 C ( E p h E g ) + D ( E p h E g ) 2
Table 1
Physical parameters for GaAs and c-GaN used for the device simulation (T=300 K).

Where Eg is the bandgap, Eph the incident photon energy and parameters for GaN: A=9.31, B=3.03, C=3.52517 and D=-0.65710. For GaAs, complex refractive index offering by Silvaco Atlas library was used [12[12] SILVACO INC., Atlas User's Manual, Santa Clara, CA, 2014.].

Beside this, a set of physical models was implemented to obtain a realistic prediction of electrical behavior on simulated devices, including bandgap narrowing effect, Shockley-Read-Hall recombination model (SRH), Auger recombination model, Fermi-Dirac statistics and modified Caughey-Thomas model for mobility, similar to others reports [13[13] DEL ÁNGEL-LARA, A., ALONSO-RODRÍGUEZ, M., HERNÁNDEZ-QUIROZ, T., et al., “Effects of Capping and Intrinsic Layers on Current Density in PIN and NIP GaN/InGaN/GaN Solar Cells”, Energy and Environment Focus, v. 2, n. 4, pp. 315–319, 2013.16[16] NACER, S., AISSAT, A., “Simulation of InGaN p-i-n double heterojunction solar cells with linearly graded layers”, Optik, v. 126, n. 23, pp. 3594–3597, 2015.]. Photovoltaics characteristics were measured under AM1.5 spectrum with 1 sun concentration.

After simulation of cells, characteristic parameters [17[17] SZE, S.M., NG, K.K., Physics of Semiconductor Devices, 3 ed., Hoboken, NJ, John Wiley & Sons, Inc., 2007.] were extracted for every device. From I-V curves, short circuit current (Isc) and open circuit voltage (Voc) were obtained; then, power curves were calculated to obtain the maximum delivered power (Pmp) and fill factor (FF), where:

(3) F F = p m p V o c I S C

Finally, the ratio between generated electric energy and the incident light power (Pin) was calculated to determine the energy conversion efficiency of the cell (η) by:

(4) η = V OC I S C F F P i n

3. RESULTS

In order to analyze the behavior of energy bands in n-GaN/i-GaAs and i-GaAs/p-GaAs interfaces, Figure 2 shows the energy band diagram of three heterostructures with different thickness on i-GaAs layer. For n-GaN/i-GaAs interface, no discontinuities were observed between the valence band (Ec) and conduction band (Ev) in the three heterostructures; this can be attributed to the proximity of electron affinity for GaN and GaAs, as this prevents the bending of the bands at the interface of the heterojunction and allows a good fit between them, which contributes to good electrical conduction within the heterostructure; this feature observed in the GaN/GaAs heterojunctions can be considered an advantage over some other GaN-based hetero-structures previously reported where there have been marked discontinuities in their energy bands [14[14] NAWAZ, M., AHMAD, A., “A TCAD-based modeling of GaN/InGaN/Si solar cells”, Semiconductor Science and Technology, v. 27, pp. 035019/1-9, 2012.16[16] NACER, S., AISSAT, A., “Simulation of InGaN p-i-n double heterojunction solar cells with linearly graded layers”, Optik, v. 126, n. 23, pp. 3594–3597, 2015.].

Figure 2
Energy band diagram for samples with i-GaAs layer thickness of 200 nm (red line), 800 nm (blue line) and 2000 nm (black line); with n-GaN=300 nm and p-GaAs=2 μm.

Current-voltage (I-V) curves were obtained and grouped by p-GaAs layer thickness; Figure 3 shows IV curves for different heterostructures with thickness of 200 nm (3a) and 350 μm (3b) for p-GaAs layer, while n-GaN layer is fixed at 300 nm and i-GaAs is varied at different thickness. For I-V curves with p-GaAs=200 nm, maximum voltage was 0.98 V for n-p type heterostructure; however, with the increase of i-GaAs layer thickness, this was decreasing to 0.76 V for the heterostructure with the thicker i-GaAs layer of the group. By contrast, for current density a marked increase was observed with increasing the thickness of i-GaAs layer between 0 and 600 nm, which was subsequently decreasing to reach a maximum current density that remained of ~ 32 mA/cm2 for the last four heterostructures (2500 to 8000 nm). In the I-V curves with p-GaAs=350 μm, higher values for voltage and current density in n-p type heterostructure were observed. The maximum value of voltage was ~ 1.06 V corresponding to n-p type heterostructure; while for the current density, the maximum values were located in ~32.5 mA/cm2 by heterostructures with the thicker i-GaAs layer.

Figure 3
I-V curves for n-i-p heterostructures with different thicknesses of i-GaAs and p-GaAs=200 nm (a) and 350 μm (b); fixing n-GaN=300 nm.

Furthermore from I-V curves, the short circuit current (Isc) and open circuit voltage (Voc) was extracted for all heterostructures; Isc as a function of i-GaAs layer thickness is shown in Figure 4 for different heterostructures in stage I of theoretical analysis. For different thicknesses of the p-GaAs layer it was initially observed a marked increase by extending the thickness of i-GaAs layer, to a maximum value, which lasted until the 8000 nm. Additionally, slightly higher Isc values were observed with increasing thickness of the p-GaAs; however, for the thicknesses of 10 and 350 μm this shift disappeared. Increased Isc for different thicknesses of p-GaAs was more remarkable for the thickness of i-GaAs between 0 and 1000 nm, as from 1200 nm, the Isc peaked and the shift due to the thickness of the p-GaAs layer was diminished. Moreover, a similar behavior of Isc for different thicknesses of the n-GaN layer (300 nm, 200 nm and 500 nm), where a maximum Isc at ~32 mA/cm2 around 3000 nm for all three thicknesses was observed. In addition, the influence of doping in n-GaN layer was analyzed for heterostructures simulated in stage II (Figure 5), where a maximum Isc of ~ 32 mA/cm2 was observed, but this time around 2500 nm of i-GaAs layer thickness. These results establish that the thickness and doping of n-GaN layer not greatly influence the behavior of Isc in these hetero-structures.

Figure 4
Variation of short circuit current (Isc) by increasing i-GaAs layer thickness for different p-GaAs thicknesses; fixing (a) n-GaN=300 nm, (b) 200 nm and 500 nm.
Figure 5
Variation in short circuit current (Isc) by increasing the thickness of i-GaAs layer using different thicknesses of p-GaAs; fixing n-GaN layer thickness to 300 nm and doping of 1x1018 cm-3, 1x1019 cm-3 and 1x1020 cm-3.

Regarding to Voc (Figure 6), by increasing the thickness of i-GaAs layer a decrease was observed for different thicknesses of p-GaAs; however, although a variation in Voc was found in smaller i-GaAs thicknesses, this remained the same in the case of thicker than 600 nm, even for different thicknesses of the p-GaAs layer. The highest values of Voc were observed at ~ 1.06 V, corresponding to the n-p type heterostructures, even for different thicknesses of the n-GaN layer. In the case of heterostructures simulated during stage II with different doping in the n-GaN layer (Figure 7), no significant changes were observed. Higher values for Voc were again corresponding to the n-p type heterostructures with thicknesses of 2 and 350 μm; which they reached values of ~ 1.05 and 1.06 V, respectively. Just as with the Isc, these results confirm that both, the thickness and doping of the n-GaN layer, not significantly influence the Voc for this kind of heterostructures.

Figure 6
Open circuit voltage (Voc) behavior while the thickness of i-GaAs layer increases for different thickness of p-GaAs; with n-GaN layer set at (a) 300 nm, (b) 200 nm and 500 nm.
Figure 7
Open circuit voltage behavior by increasing i-GaAs layer thickness for different p-GaAs thicknesses and n-GaN layer thickness fixed to 300 nm with doping of 1x1018 cm-3, 1x1019 cm- 3 and 1x1020 cm-3.

For fill factor parameter (FF), Figure 8 shows the results obtained in stage I simulations. Similarly to the Voc, in the FF, by increasing the thickness of i-GaAs layer a decrease of this value was observed; however, in this case it showed an abrupt decrease between the n-p type heterostructure and n-i-p type heterostructure with a thickness of 50 nm on i-GaAs layer and subsequently increased for the thickness of 100 nm. The maximum FF found was ~ 0.89, for n-p type heterostructures; however, for the n-i-p type heterostructures with an i-GaAs thickness less than 2000 nm, values were above 0.80, a value considered acceptable for the proper performance of a solar cell [19[19] GREULICH, J., GLATTHAAR, M., REIN, S., “Fill factor analysis of solar cells' current-voltage curves”, Progress in Photovoltaics: Research and Applications, v. 18, n. 7, pp. 511–515, 2010.]. In the case of i-GaAs thicknesses between 400 and 1500 nm, variation in FF was minimal; however, for thicknesses greater than 2000 nm, this decreased considerably, reaching values below 0.70 for heterostructures with i-GaAs thicknesses of 8000 nm. This may be caused by the increase in recombination of carriers due to excessive thickness of the i-GaAs layer [20[20] HAMEDANI, P.F., TAGHINIA, A., YAZDI, F., ARTIMANI, Z.M., “Study the effect of varying the thickness of intermediate band on the intermediate band solar cells efficiency” In: Energy Procedia of 2nd International Conference on Advances in Energy Engineering (ICAEE), pp. 1496–1502, Bangkok, Thailand, 2012.], which consequently reduces the Voc and the "perpendicularity" of I-V curve. For heterostructures with different layer thicknesses in n-GaN, no differences were observed on FF; reaffirming once again that the thickness of this layer does not impact significantly on the parameters of the cells studied.

Figure 8
Variation of fill factor (FF) relative to the increased i-GaAs layer thickness for different p-GaAs thicknesses; fixing (a) n-GaN=300 nm, (b) 200 nm and 500 nm.

In heterostructures where doping of n-GaN layer was varied (Figure 9), similarly no significant changes occurred between them; however, for the case of heterostructures with 1x1019 cm-3 doping in n-GaN layer, the FF decrease in those with thicknesses of 50 nm was much greater with respect to the other. The minimum FF was obtained in heterostructures with 600 nm of thickness on i-GaAs layer for doping of 1x1018 and 1x1020 cm-3, while for i-GaAs thicknesses greater than 2000 nm this remained around 0.83. These results confirm the impact of Voc in the performance of the heterostructure and the importance in maintaining a symmetrical relationship between Isc and Voc. Finally, for heterostructures with 1x1019 cm-3 doping, the minimum FF was found for the heterostructure with 50 nm of thickness on i-GaAs layer and further a FF of ~ 0.84 was observed for the heterostructure with an i-GaAs layer thickness of 200 nm and p-GaAs of 350 μm, indicating that the relationship between Voc and Isc is more proportional than in other heterostructures and therefore its "perpendicularity" is greater.

Figure 9
Variation of fill factor (FF) relative to the increase in i-GaAs layer thickness for different p-GaAs thicknesses and fixing n-GaN layer thickness to 300 nm and doping at 1x1018 cm-3, 1x1019 cm- 3 and 1x1020 cm-3.

Theoretical efficiency of simulated cells was calculated, the efficiencies obtained in stage I are shown in Figure 10. For a p-GaAs layer thickness lower than 2 μm, an increase in efficiency was observed by increasing the thickness of i-GaAs layer to reach a peak and then a marked decrease was showed; in contrast, for p-GaAs thicknesses of 10 and 350 μm, the maximum efficiency values were obtained for n-p type hetero-structures and as the thickness of i-GaAs layer increased the efficiency decreased. It was also found that for i-GaAs thicknesses greater than 2500 nm, the efficiencies reach similar values regardless the thickness of p-GaAs layer; reaching down to 18% for i-GaAs thicknesses of 8000 nm. As with the parameters discussed above, no significant changes were observed in efficiencies for heterostructures with different thicknesses in the n-GaN layer. Generally, the maximum values of efficiency for simulated heterostructures during stage I, reached values of ~ 25% for n-p and between 21 and 23% for n-i-p types heterostructures. In the case of heterostructures simulated during stage II (Figure 11), a similar pattern was observed, greater efficiencies were found by increasing p-GaAs layer thickness, reaching maximum of ~ 25.5% for n-p type heterostructures; however, no significant variations between different doping of n-GaN layers were observed. This corroborates what had already been observed in the parameters previously reported that both, the change in doping and thickness, do not generate significant changes in the performance of devices based on this type of heterostructures.

Figure 10
Variation of energy conversion efficiency (η) by increasing i-GaAs layer for different p-GaAs thicknesses with n-GaN fixed at (a) 300 nm, (b) 200 nm and 500 nm.
Figure 11
Variation in energy conversion efficiency (η) by increasing the i-GaAs layer for different p-GaAs thicknesses; setting the n-GaN doping at 1x1018 cm-3, 1x1019 cm-3 and 1x1020 cm-3; with 300 nm in thickness.

4. DISCUSSION

Although the different results presented in I-V curves, it was possible to observe similar behavior within each group; in both, as the thickness of the intrinsic layer was increased, the voltage was decreased and current density increased, which coincides with some previously works reported for photovoltaic devices based on GaN [14[14] NAWAZ, M., AHMAD, A., “A TCAD-based modeling of GaN/InGaN/Si solar cells”, Semiconductor Science and Technology, v. 27, pp. 035019/1-9, 2012.]. However, although the increase in current density peaked around 32 mA/cm2 for both groups, a marked difference was observed in the increase of current density for heterostructures with i-GaAs layer thicknesses lower than 400 nm for the reduced thickness of p-GaAs. This allows argue that the thickness of the i-GaAs layer has a greater influence on the performance of the heterostructure when the thickness of the substrate (p-GaAs) is lower; however, when much greater thicknesses are used for the p-GaAs layer, the intrinsic layer rather affects the performance of the cell as the voltage is decreased considerably and no significant increase is generated in current density.

By knowing that Isc is related to the collection of carriers, photogeneration and diffusion of carriers in the device [21[21] NELSON, J., The Physics of Solar Cells. 1 ed., London, UK, Imperial College Press, 2003.], it is possible to assume that the observed increase by increasing the thickness of the i-GaAs, is due to an increase in absorption and therefore improved collection device and photogeneration; which it is even more pronounced for thinner p-GaAs thickness. Also, since Voc corresponds to maximum available voltage in the cell produced for a current density I=0, and depends on the saturation current of the cell and the photogenerated current [22[22] WÜRFEL, P., Physics of solar cells: from basic principles to advanced concepts, 1 ed., Weinheim, WILEY-VCH Verlag GmbH & Co. KGaA, 2005.], the decrease observed in the Voc, can be attributed to the decrease of the electric field, due to the increased thickness of i-GaAs layer when n-GaN and p-GaAs layer thicknesses are fixed, which impacts the collection of carriers in the contacts of the cell and the increase in the saturation current due to recombination within the device.

According to previously reported works in n-i-p and p-i-n solar cells, the increase in the thickness of the intrinsic layer increases absorption and efficiency [16[16] NACER, S., AISSAT, A., “Simulation of InGaN p-i-n double heterojunction solar cells with linearly graded layers”, Optik, v. 126, n. 23, pp. 3594–3597, 2015.]; because when the thickness of the i-GaAs increases, this occupies increasingly greater extent the space charge region, and finally the region is located entirely within the intrinsic layer, which achieves a better quantum efficiency internal to the device. The results obtained in this theoretical study show that to locate the space charge within the intrinsic region, it is required a thickness between 1 and 1.5 microns for i-GaAs, which allows to assume that the intrinsic layer thickness must be at most the order of the absorption length, about 1.2 microns according to what was reported by Nawaz & Ahmad [14[14] NAWAZ, M., AHMAD, A., “A TCAD-based modeling of GaN/InGaN/Si solar cells”, Semiconductor Science and Technology, v. 27, pp. 035019/1-9, 2012.]; also, it was observed that increasing excessively the thickness of i-GaAs layer negatively impacts Voc, because the intensity of the internal electric field is reduced and there is an increase in possibilities of recombination of carriers. Therefore, this allows justify why for thicknesses greater than the intrinsic layer, the efficiency peaks that could be attributed to absorption maximum and photogeneration, which subsequently decreases when after that peak only increases recombination and it impacts negatively in device performance.

Since this study is the first presenting an approach to the behavior of a GaN/GaAs heterostructure as photovoltaic device, it is not possible to compare the obtained results with some solar cell of this type previously reported; however we can make a comparison with cells based on GaAs and GaN previously reported separately. For GaN based solar cells, these have recently reported theoretical efficiencies between 18% and 24% [14[14] NAWAZ, M., AHMAD, A., “A TCAD-based modeling of GaN/InGaN/Si solar cells”, Semiconductor Science and Technology, v. 27, pp. 035019/1-9, 2012.16[16] NACER, S., AISSAT, A., “Simulation of InGaN p-i-n double heterojunction solar cells with linearly graded layers”, Optik, v. 126, n. 23, pp. 3594–3597, 2015.] for p-i-n type configuration; and between 18% [11[11] BROWN, G.F., AGER, J.W., WALUKIEWICZ, W., WU, J., “Finite element simulations of compositionally graded InGaN solar cells”, Solar Energy Materials and Solar Cells, v. 94, n. 3, pp. 478–483, 2010.] and 26% [23[23] MESRANE, A., RAHMOUNE, F., MAHRANE, A., OULEBSIR, A., “Design and Simulation of InGaN p-n Junction Solar Cell”, International Journal of Photoenergy, v. 2015, pp. 594858/1-9, 2015.] in p-n type cells; while cells based on GaAs have reported efficiencies between 17% and ~ 24% [24[24] DAS, N.C., “Enhanced solar energy harvesting using top n-contact GaAs solar cell”, Solid-State Electronics, v. 107, pp. 11–14, 2015.]. These values serve as a guideline for considering acceptable the results obtained in this study and allow demonstrating the potential of a GaN/GaAs heterostructure by introducing efficiencies above those previously reported for cells based on GaN and GaAs separately in multijunction devices with the advantage that this study shows this efficiencies for a single heterojunction solar cell.

5. CONCLUSIONS

In this work, we analyzed electrical behavior for a new proposed GaN/GaAs heterostructure based on cubic GaN (c-GaN) as a photovoltaic cell by numerical finite element simulations. We study the photovoltaic response for different heterostructures by obtaining their I-V curves and characteristic parameters, first by varying thickness on the three layers and then fixing the n-GaN layer thickness and varying the doping concentration. Simulated results showed that thickness of i-GaAs layer have the greater influence in device performance for thinner substrates (p-GaAs), and for thicker p-GaAs layer, the increment on intrinsic layer thickness could affect the performance by the increment of recombination inside the heterostructures. We also found that in the case of n-GaN layer, thickness and doping concentration do not generate significant changes in the performance of devices based on this type of heterostructures. However, results shows efficiencies between 23 and 25% for n-i-p and n-p heterostructures and the potential of designing improved heterostructures for c-GaN/GaAs solar cells using GaAs as a substrate.

6. ACKNOWLEDGMENTS

The authors want to thank DGDAIE-UV, DGI-UV, and SENER-CONACYT for their support of this work.

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Publication Dates

  • Publication in this collection
    2017

History

  • Received
    31 Aug 2016
  • Accepted
    10 May 2017
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro, em cooperação com a Associação Brasileira do Hidrogênio, ABH2 Av. Moniz Aragão, 207, 21941-594, Rio de Janeiro, RJ, Brasil, Tel: +55 (21) 3938-8791 - Rio de Janeiro - RJ - Brazil
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