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## Journal of the Brazilian Society of Mechanical Sciences and Engineering

*Print version* ISSN 1678-5878

### J. Braz. Soc. Mech. Sci. & Eng. vol.34 no.3 Rio de Janeiro July/Sept. 2012

#### http://dx.doi.org/10.1590/S1678-58782012000300008

**TECHNICAL PAPERS RHEOLOGY AND NON-NEWTONIAN FLUID MECHANICS**

**Determining the viscous behavior of non-Newtonian fluids in a flume using a laminar sheet flow model and Ultrasonic Velocity Profiling (UVP) system**

**Rainer Haldenwang ^{I}; Reinhardt Kotzé^{II}; Raj Chhabra^{III}**

^{I}Cape Peninsula University of Technology, Civil Engineering, 8000 Cape Town, South Africa, haldenwangr@cput.ac.za

^{II}Cape Peninsula University of Technology, Civil Engineering, 8000 Cape Town, South Africa, kotzer@cput.ac.za

^{III}Indian Institute of Technology Kanpur, Department of Chemical Engineering, Kanpur, India, chhabra@iitk.ac.in

**ABSTRACT**

The flow of non-Newtonian fluids in rectangular open channels has received renewed interest over the past number of years especially as large flumes are being used to transport tailings in countries like Chile. The effect of yield stress on the flow behavior is complex and not yet fully understood. The Ultrasonic Velocity Profiling (UVP) technique has been used to construct velocity profiles of non-Newtonian fluids flowing in a 10 m by 300 mm wide tilting flume. The contour maps were integrated to show that the velocity profiles were indeed correct. The thin film flow models available in the literature have been tested in terms of flow depth and Reynolds number. The measured profiles also show the influence of the side walls on the general flow features as the distance from the centre increases. The results reported herein span the laminar, transition and turbulent flow regions. As far as can be ascertained, it is the first time that this technique has been used to measure velocity profiles in opaque non-Newtonian fluids for open channel flow. It is shown here that, under appropriate conditions, the velocity profile and flow depth can be used to obtain the viscous properties of the fluids tested. Excellent correspondence between the rheological parameters inferred from the velocity profile measurements and that from the tube viscometry was obtained.

**Keywords:** open channel, ultrasound velocity profiling, sheet flow, non-Newtonian fluid, rheology

** Introduction**

In recent years, there has been a renewed interest in studying the flow behavior of non-Newtonian fluids in open channels and flumes. Interest in such studies stems from both theoretical and pragmatic considerations. For instance, satisfactory understanding of thin film flow is germane to ensuring uniform product quality in scores of coating applications like in food and paper making applications. Further relevant applications are found in personal care products like in tailoring the rheological properties of creams, lotions and sun screens for their satisfactory end use (Laba, 1993). On the other hand, open channel or free surface flows are frequently encountered in the mining industry where flumes or launders are used routinely to transport mineral slurries and mine tailings for their disposal (Fuentes, 2004; Fernandez et al., 2010; Alderman and Haldenwang, 2007). Further applications abound in the lava and geological flows. Finally, this model configuration also has potential of being relevant in the evaluation of rheological characteristics, especially steady shear stress– shear rate of time-independent fluids, e.g., see (Chhabra and Richardson, 2008; Astarita et al., 1964). The bulk of the literature on this subject has been summarized recently (Haldenwang et al., 2010) and therefore only the key points are recapitulated here.

The currently available body of knowledge on this subject is conveniently classified into three sub-categories. The earliest analyses are based on the assumption of one-dimensional, laminar, fully developed flow on an inclined plane surface. In spite of their idealized nature, this class of solutions has often served as a convenient tool to extract the value of the rheological parameters simply from inclination versus flow rate data. While this has proved to be a useful rheological information tool, the limits of the validity of the one-dimensionality, etc. are not yet known (De Kee et al., 1990). The second sub-category of studies in this field endeavors to develop friction factor-Reynolds number plots akin to the Moody plot for different kinds of purely viscous non-Newtonian fluid models such as the power-law, Bingham plastic and Herschel-Bulkley model, etc. While the laminar flow is amenable to theoretical analysis based on the assumptions of one-dimensional, steady flow, extension to the flow conditions beyond the laminar flow regime is often based on dimensional considerations aided by experimental observations (Chhabra and Richardson, 2008; Haldenwang et al., 2010 and Kozicki and Tiu, 1967, 1986). Similarly, owing to the thin film approximation inherent in such studies, it is not always justified to overlook the influence of the morphology of the solid surface (Haeri and Hashemaabadi, 2009).

It is worthwhile to reiterate here that the assumptions of uniform, steady and one-dimensional flow are inherent in most of the experimental studies. The last sub-class of analyses endeavors to relax one or more of these assumptions such as non-uniform, but steady flows have been considered by Wilson and Taylor (1996). The effect of the sidewalls has been investigated by Huang and Garcia (1998) among others. Similarly, Cantelli (2009) has considered the 2-dimensional flow in a trapezoidal cross-section flume. He also reported limited velocity measurements using tracer particles across the cross-section of the flume. Suffice it to say here that naturally all these sub-classes of studies are not mutually exclusive. It is also somewhat surprising that in spite of such an overwhelming significance of this flow configuration, very little prior information is available regarding the prevailing detailed velocity distributions in these flows. Such measurements are not only significant in their own right, but more importantly are also needed to substantiate and/or to refute the velocity distribution predictions obtained from the governing field equations, e.g., see De Kee et al. (1990), based on the assumptions of one dimensional, steady, laminar and fully developed flow. This work endeavors to fill this gap. In particular, reported herein are the extensive experimental results on the velocity profiles using Ultrasonic Velocity Profiling (UVP) technique for these two types of non-Newtonian fluids, namely, shear-thinning (power-law) and Bingham plastic fluids.

** Theoretical Considerations**

De Kee et al. (1990) considered the one-dimensional, laminar, steady and fully developed gravity driven flow of time-independent non-Newtonian fluids down (Fig. 1) an inclined plane which is very wide in the other two directions. They approximated the steady shear rheological behavior by the well-known Herschel-Bulkley fluid model written in simple shearing motion as:

On the other hand, the application of the Cauchy's momentum equations yields the following linear dependence of the shear stress on the x-coordinate as:

The maximum shear stress occurs at the wall and is given by:

Owing to the presence of the yield stress, τ_{y}, it is fair to anticipate that there would be a plug-like region near the free surface, as shown schematically in Fig. 1. If this region extends up to x = x_{0}, the velocity of the plug will be constant in the region 0 __<__ x __<__ x_{0}. Beyond x __>__ x_{0}, the velocity will progressively decrease from the plug velocity to a zero value at the wall due to the no-slip condition. By combining these equations, De Kee et al. (1990) derived the following formulae for the point velocities as well as the average velocity.

The average velocity is given as follows:

In the present work, the nature of the flow was delineated by evaluating the Reynolds number proposed by Haldenwang et al. (2002) and Haldenwang and Slatter (2006) as written here for the flow of Herschel-Bulkley model fluids:

Note that Eq. (7) includes the limiting cases of power-law fluid (τ_{y} = 0), Bingham plastic fluid (n = 1) and Newtonian fluids (n = 1 and τ_{y} = 0). In this work, the limit of the laminar flow region where transition starts was deemed to occur at a point where the data began to deviate from the 16/Re line on the Moody Diagram. The hydraulic radius R_{h} for a rectangular channel is evaluated as follows:

It is also appropriate to mention here that the standard dimensional considerations will yield a Reynolds number:

and an Oldroyd number:

It is readily seen that the Reynolds number, Re_{H}, given by Eq. (7) combines these two parameters into one as:

where **C** is a numerical constant. A similar composite Reynolds number has also been found to be successful in reconciling the drag data of falling spheres in visco-plastic fluids (Chhabra, 2006).

**Experimental Methods and Materials**

**UVP-PD method for in-line rheological characterization**

Ultrasonic Velocity Profiling (UVP) for mechanical measurement of flowing fluids was initially developed by Takeda (1986; 1995; 1999), albeit initially this technique was used in medical science measuring blood flow by means of Doppler sonography way back in the 1960's, as described by Kuttruff (1991). UVP is accepted as an important tool for measuring flow profiles in opaque liquids in research and engineering and it has been previously applied in complex geometries such as stirred tanks (Bouillard et al., 2001; Ein-Mozaffari and Upreti, 2009), contractions (Ouriev and Windhab, 2003; Kotzé et al., 2011), liquid metal target of neutron spallation source configuration (Takeda and Kikura, 2002), cylindrical hydrocyclone (Bergström and Vomhoff, 2004) as well as diaphragm valves (Kotzé et al., 2011). This highly versatile technique can also be used to determine fluid properties such as concentration profiles (Sad Chemloul et al., 2009), solid particle velocity as well as rheological properties.

Steger (1994) and Muller et al. (1997) developed the so-called Ultrasonic Velocity Profiling with combined Pressure Difference (UVP-PD) method where the measurement of pressure drop was added to the measured velocity profile to obtain rheological data. Based on this idea, Ouriev (2000) developed an in-line UVP-PD system for in-line measurement of the rheology of complex fluids. Birkhofer (2007) and Wiklund (2007) further optimized and/or refined the system. Kotze et al. (2008) successfully employed this method for the flow of highly concentrated opaque mineral suspensions in circular pipes. They reported a good agreement (within 15%) between the rheological parameters extracted from the detailed velocity profiles and those obtained from tube viscometry.

** Flume rig**

The test work was carried out in a 10 m long tilting flume, as detailed elsewhere (Haldenwang 2003; Haldenwang & Slatter, 2006). In brief, it consists of a 10 m by 300 mm wide tilting flume, which can tilt from horizontal by up to 5 degrees. The flume is linked to an in-line tube viscometer with three different diameter tubes, namely, 13 mm, 28 mm and 80 mm respectively. The in-line tube viscometer is fitted with a high and a low range differential pressure sensor to measure the pressure drop in the tubes over a set distance. Each line is also fitted with a magnetic flow meter to measure the flow rate. In addition the density was measured with a mass flow meter and the temperature with a thermocouple. The entry lengths in each pipe were at least 50 diameters to minimize entrance effects. The fluid heights in the flume are measured at two positions with digital depth gauges which are operated manually. The depth measurements were done at two positions between 5 and 6 m from the flume entrance. Haldenwang (2003) determined that the flow at these positions was fully developed. Schematic layouts of the flume and in-line tube viscometer are depicted in Fig. 2. All the data are sent electronically to a data acquisition system linked to a PC for storage and further processing.

**UVP measurements**

The velocity profiles used in this work were obtained using a UVP-DUO-MX from Met-Flow SA, Switzerland. Plain-wave type 4 MHz ultrasound transducers, operating in transmitting and receiving mode, were used. Technical information about the system can be found in Met-Flow SA (2002). The transducers were mounted on the bottom and sidewalls of the flume (as shown in Fig. 3) and were installed in direct contact with the test fluid in order to maximize acoustic energy input. Transducers were also pulled back so that the transducers' focal points were situated at the flume wall interfaces, thus leaving cavities between the transducer surfaces and flume walls. The installation of the ultrasonic transducers is illustrated in Fig. 4. Profiles were only measured over one half of the flume as the flow was assumed to be symmetrical across the flume cross-section.

**Rheological characterization in flow loop**

From the tube viscometer set up, the pressure drop and flow rates data are obtained. The pressure drop is used to calculate the wall shear stress and the flow rate for the corresponding wall shear rate. The wall shear stress is plotted versus the pseudo shear rate on a pseudo shear diagram. Figure 5 shows a pseudo shear diagram obtained using the tube viscometer for CMC 5.26% w/w. All the laminar flow data obtained from the three tubes will be co-linear if there is no wall slip. This data is then transformed with the Rabinowitsch-Mooney transformation method to true shear rate using Eq. (10).

This data, in turn, is fitted to the Herschel-Bulkey fluid model to establish the best values of the model parameters, i.e., n, K, τ_{y} .

**Test fluids**

In this work, aqueous carboxymethyl cellulose (CMC) and bentonite suspensions (densities of 1030 kg/m^{3} for CMC and 1032 kg/m^{3} for bentonite) were used as model test fluids to achieve different types of rheological characteristics. The test fluids were prepared by a gradual addition of the required amount of the polymer or clay in tap water using a mechanical stirrer to produce a homogeneous solution. It is known that bentonite suspensions can exhibit thixotropic behavior under certain conditions depending upon the concentration, type of clay, etc. To minimize this effect, the material was pre-sheared by re-circulating and vigorously mixing the suspension before and during the tests. The rheology was also tested before and after a test. No measurable change was detected in the steady shear stress-shear rate data with time on account of thixotropy of the bentonite suspension or of biological degradation in the case of the CMC solution. The CMC that has been used does not structurally deteriorate during the period of testing (maximum one day) and checking the rheology before and after the test has confirmed this.

** Results and Discussion**

**Rheological properties of test fluids**

By examining the nature of the steady shear stress-shear rate data, it turned out that the CMC solution exhibited power-law type behavior with a moderate degree of shear-thinning (K = 0.92 Pa.s^{n }and n = 0.69) and the bentonite suspension exhibits Bingham plastic behavior (τ_{y} = 2.8 Pa, n = 1 and K = 0.008 Pa.s).

** Validation of UVP velocity profile accuracy**

To ascertain whether the velocity profiles were correct the data of the six profiles were collated in a XYZ data file, where X and Y are the spatial coordinates giving the position of the point velocity V. The data was imported into MATLAB® where a velocity contour plot was created. This was integrated using a triangulation algorithm to establish the average velocity which was compared with the value measured by the magnetic flow meter in the flume loop. The contour plot of the 5.26% w/w CMC at Re = 164 is shown in Fig. 6. The difference between the flow rates measured by the flow meter and the integrated contour plot was 6.3%. For the 5.29% v/v bentonite suspension at Re = 438 shown in Fig. 7, the difference between the two values was 6.42%. This inspires confidence in the reliability of the detailed velocity measurements presented here. Tables 1 and 2 summarize the range of experimental conditions encompassed here. The undulations in the isobars are caused by the number of flow profiles that were available. If more data were available these lines would have been smoother.

**Laminar sheet flow of a power law fluid**

An example of a centreline plot for 5.26% w/w CMC at a flow rate of 2.78 l/s and at a flume slope of 1 degree is shown in Fig. 8. Also included here are the predictions of Eqs. (4) and (5). As can be seen there is a good correlation of the prediction with the experimental data. Figure 9 shows how the measured profile deviates from the theoretical profile less than 100 mm away from the centre. Coussot (1994) suggested that in such a flume sheet flow can be assumed if the depth to width ratio is less than 1:10 (for a 300 mm wide flume the flow depth must be less than 30 mm to be sheet flow). The aspect ratio of the present flow is 1:2.5, which is much deeper than the 1:10 suggested by Coussot (1994).

In Fig. 10, the progression of velocity profile measurements in laminar and transitional open channel flow is shown. It can be seen that the sheet flow profile only holds for the laminar flow conditions, as the assumption is also inherent in the derivation of Eqs. (4) and (5). The UVP measurements in transitional flow reach a maximum velocity (peak) and then decrease with increasing flow depth. This is due to the maximum measurable velocity and depth constraint in UVP systems. When using UVP a compromise between the maximum measurable velocity and the maximum measurable depth has to be made, but since this is not possible in open channel flow (as the flow velocity increases, the flow depth increases at the same time), aliasing (or folding) occurs in measurements which results in incorrect velocity estimates (Met Flow SA, 2002). These limitations can be overcome by implementing de-aliasing algorithms that is directly applied to the Doppler phase shift signals (raw data). The algorithm applies phase unwrapping techniques, which corrects erroneous data spikes caused by aliasing; see e.g. Franca and Lemmin (2006). This is currently under investigation.

**Laminar sheet flow of a Bingham plastic fluid**

The centreline velocity profile showing the model predictions and the experimental data for the 5.29% v/v bentonite suspension for a flow rate of 3.27 l/s at a 2 degree slope is shown in Fig. 11. Again the agreement between the two seems to be good. However, the velocity gradients close to the flume surface (0 – 0.01 m) do not agree very well. This is due to the combination of the transducer installation method (see Fig. 4) and high velocity gradient of the Bingham profile. There is an increase in velocity at the surface interface due to influence of the cavity, which distorts the measured velocity profile. Note that this distortion did not occur during the CMC tests, which suggests that the cavities have a more significant influence on plug flows where the velocity gradients are high. It is also interesting to note that for the 5.29% w/w bentonite suspension the deviation of the predicted from the measured profile with distance from the centreline (see Fig. 12) is not so sudden as for CMC (see Fig. 9). This could be ascribed to the formation of the plug which extends towards the side wall. The sheet flow model still holds to about 20 mm from the side wall. The aspect ratio in this instance is 1:21, which is better than the 1:10 set as a limit for the sheet flow by Coussot (1994). In Fig. 13 the progression of velocity from laminar to transition to turbulence is shown. It can be seen that the sheet flow profile only holds for the laminar flow similar to what was discussed for CMC.

**Establishing in-line rheology using UVP and depth in flume**

For open channel flow, it is possible just as for pipe flow to establish the rheological parameters by fitting the theoretical equation, in this case Eqs. (4) and (5) to the experimental data. Only one velocity profile measurement at the centre of the flume and the corresponding flow depth is required. By using a fitting procedure the rheological parameters τ_{y}, K and n can then be varied until the error between the theoretical and the measured profile data is a minimum.

To test this conjecture, two fluids were used. The theoretically optimized and the experimental velocity profiles for 5.26% CMC are depicted in Fig. 14.

In Fig. 15, rheograms using the rheological parameters obtained from the flume are compared with those obtained from the tube viscometer. As can be seen, there is excellent agreement between the two flow curves. In Fig. 16 and Fig. 17, a bentonite suspension at 5.4% w/w concentration was used and similar results were obtained.

Finally, it is appropriate to mention here that the model prediction is very sensitive to flow depth and yield stress, as can be seen in Fig. 18 and Fig. 19. When the value of the yield stress is changed from 2.8 to 2.6 Pa (8% change) the maximum velocity in the profile changes by 26%. This indicates that extreme care needs to be exercised in extracting the values of the rheological parameters from the velocity profiles. Also, it needs to be emphasized here that once the actual velocity profile is available, one can fit any suitable viscosity model simply by replacing Eqs. (4)-(6) by corresponding expressions for the model of choice.

**Conclusions**

The De Kee et al. (1990) model for predicting laminar sheet flow for pseudoplastic and yield pseudoplastic fluids has been validated with velocity profiles created by the non-invasive UVP method. As the tests were conducted in a 300 mm wide flume, the depth to which the sheet flow paradigm could be used was found to be 71.7 mm for CMC and 24.3 mm for bentonite, both in laminar flow at a one degree slope. Further tests are required in order to determine the exact limitations of the theoretical model for laminar sheet flow.

A new non-intrusive method for determining the rheology of a fluid flowing in a flume has been developed (UVP-FD). One velocity profile measured at the centreline with the UVP system and the flow depth is required. By fitting the model to the experimental data and optimizing the rheological parameters a good correlation with the in-line tube viscometer has been achieved. The advantage is that only one velocity profile is required instead of flow curves over a range of flow rates in at least 2 tubes. Complete velocity profiles over the whole flume cross-section were created using six profiles and it should be now possible to determine the wall shear stresses around the perimeter of the flume cross-section. Finally, it needs to be emphasized here that there are situations (like in food industry) where it is not possible to divert the flow into a bypass line (acting as a tube viscometer). On the other hand, UVP is used routinely as a tool to monitor the product quality and therefore, the scheme developed herein is a "non-invasive" tool to extract steady shear rheology of a fluid.

** Acknowledgements**

The financial support of this work from the National Research Foundation (NRF) and the Cape Peninsula University of Technology (CPUT) is acknowledged. We are also grateful to the constructive comments offered by the reviewers of this manuscript.

** Nomenclature**

A | = |

D | = pipe diameter, m |

g | = acceleration due to gravity, m/s^{2} |

h | = depth of fluid in channel, m |

K | = |

L | = pipe length, m |

n | = flow behavior index, dimensionless |

n' | = apparent flow behavior index, dimensionless |

Od | = Oldroyd number, dimensionless |

P | = wetted perimeter, m |

R_{h} | = |

Re | = Reynolds number, dimensionless |

Re_{H } | = Haldenwang Reynolds number, defined by Eq. (7), dimensionless |

V | = average velocity, m/s |

= velocity for 0 x < x< _{0} ,m/s | |

= velocity for x_{0} x < h< ,m/s | |

W | = |

X | = vertical position in flume, m |

X_{0 } | = vertical position of plug interface, m |

Greek Symbols | |

| |

α | = angle of flume from the horizontal, degrees |

β | = numerical constant in Oldroyd number formula |

ρ | = fluid density, kg/m^{3} |

τ_{0} | = wall shear stress, Pa |

τ_{xz} | = shear stress at any level in the fluid, Pa |

τ_{y} | = yield stress, Pa |

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Paper received 6 August 2011

Paper accepted 16 April 2012

Technical Editor: Monica Naccache