Resumo em Inglês:

In this paper we present the impedance spectroscopy of ternary solid solutions of BiFeO3, TbFeO3 and PbTiO3, prepared by solid-state reaction method. The preliminary structural studies were carried out by x-ray diffraction technique, showing the formation of polycrystalline sample with ABO3 type of perovskite structure with hexagonal symmetry for Bi0.8Tb0.1Pb0.1Fe0.9Ti0.1O3system at room temperature. Dielectric and impedance study of this ceramic has been characterized in the temperature range 175 - 325 0C and frequency range 100 Hz - 1 MHz. The maximum ferroelectric transition temperature (Tc) of this system was in the range 210 - 225 0C with the dielectric constant having maximum value ~2480 at 1 kHz. The complex impedance graph exhibited one impedance semicircle arc at all reported temperatures, which indicates that the impedance response is a Cole-Cole type relaxation. Single semicircle indicate that the grain effect of the bulk in ceramic. The bulk resistance of the material decreases with increasing temperature showing negative temperature showing a typical semiconducting property, i.e. negative temperature coefficient of resistance (NTCR) behavior.

Resumo em Inglês:

Titanium nitride (TiN) coatings are widely used in machining because of its mechanical characteristics which modify the surface of the substrate increasing the capacity of load support and reduction of friction, while a coating as diamond-like carbon (DLC), which also has interesting mechanical properties, needs better attention. In this sense, the development of new coatings such as DLC is as important as wear analysis techniques. This work discusses the methods available to assess abrasive wear of coatings. For this, it has been used the data of the crater volume formed in ball cratering test and compared the difference between the specific wear coefficients of substrate and coating (ks and kc). These coefficients depend of the methods used for data analyses, thus, it has been used four equations to calculate ks and kc. Moreover, profilometry (pf) has been used to calculate the volumes, and thus ks and kc. Also, the roughness of the coatings, the thickness, the images corresponding to the crater formed, the coefficient of friction, the data obtained in wear tests due to the volume removed and, in the end, a comparison between ks and kc by different methods of data analyzes are presented.

Resumo em Inglês:

In this paper, we tried to describe a different method for producing BiI and BiOI thin films, which is chemical bath deposition on glass substrates. Structural and optical properties of BiI and BiOI thin films were examined using X-ray diffraction (XRD), scanning electron microscope (SEM), and UV-VIS measurements. Film thicknesses of the films were measured by Atomic Force Microscope (AFM). Chemical analysis by EDX was performed with an EDX spectrometer attached to SEM. Various concentrations of bismuth and iodine solutions were tested to determine optimum parameters for BiI and BiOI production. Structures of the films were changed with the concentrations of the compounds in the bath. Some properties of the films, such as transmittance, reflectivity and refractive index were also changed with the change of concentrations in the chemical bath. When the concentration of the bismuth and iodine, which was added to the bath, was 10-1 M, the dominant character observed in the structure was tetragonal BiOI, whereas when 10-2 M bismuth and iodine were added, monoclinic BiI structure was observed with (205) and (31-1) in planes. The mixed phase of BiI and BiOI was also observed with 10-2 M concentration. The refractive index and optical band gap (Eg) were changed with deposition concentration, which were 1.41-1.86 and 3.37-3.67 eV, respectively. The lowest film thickness was measured as 98 nm at 0.1 M concentration. The EDX results were almost equal to the stoichiometric ratio of BiI and BiOI compounds.

Resumo em Inglês:

In this work the hydrothermal synthesis of ZSM-12 zeolite was performed, varying the MTEACl/SiO2 ratio, where the synthesis temperature was 140 ºC and the crystallization time was 144 hours. The catalysts were characterized by XRD, FTIR and TG. TiO2/ZSM-12 catalysts were used with titanium ions concentrations of 5, 10 and 15%. The oxidative desulfurization (ODS) reactions were performed using a model mixture containing n-heptane as solvent and thiophene as sulfur compound, H2O2 as an oxidizing agent, and acetonitrile as an extractor solvent at reaction temperatures of 30, 50 and 70 ºC. The obtained results shows that TiO2/ZSM-12 with 15% of Ti catalyst has a better performance in the ODS reaction converting thiophene at about 60%.

Resumo em Inglês:

Coprecipitation synthesis of nanocrystalline india-stabilized zirconia with high surface area and codoping with MoO3, WO3, TaO2.5, or NbO2.5 is reported. The concentration of codopants was defined by the charge-compensating mechanism. Ethanol washing followed by azeotropic distillation and freeze drying were compared as dehydration techniques for the gels. As determined by XRD and Raman scattering, 9 mol% of InO1.5 plus charge-compensating dopants is sufficient to completely stabilize the high-temperature tetragonal phase of zirconia. The effect of alloying hexavalent and pentavalent oxides was secondary compared to the InO1.5 concentration in the retention of the tetragonal structure. Improved specific surface area of 106.1 m2 g‒1 and crystallite size between 8 and 9 nm were achieved through ethanol washing and subsequent azeotropic distillation even after calcination at 600 ºC. This result is attributed to the effect of the incorporation of ethoxy and butoxy groups after the treatment of the gels in organic medium, as detected by FT-IR spectroscopy and DSC/TG.

Resumo em Inglês:

Experimental dental resins composed of triethyleneglycol dimethacrylate, urethane dimethacrylate, ethoxylated bisphenol-A-dimethacrylate and bisphenol A glycidyl methacrylate containing an organoclay as filler were prepared by photopolymerization. The addition of organoclay fillers results in slower polymerization rates (0.59 and 0.24 mol L-1 min-1, for the formulations without and with 15% of organoclay, respectively) and lower degrees of conversion (0.50 and 0.35 for the formulations without and with 15% of organoclay), as determined by photocalorimetry. The influence of the organoclay on the thermal and mechanical properties of the resins was evaluated using thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA) techniques. The (tan δ) and E´ curves indicate the formation of more rigid materials and the damping curve data indicates more homogeneous materials. An increase of storage modulus, E’, was observed for composites with the higher organoclay filler contents. These effects are due to the higher viscosity of the systems with organoclay, resulting in a lower mobility of the radicals during the propagation step of polymerization, as well as to the scattering of the incident photopolymerizing radiation, which lowers the amount of initiation centres.

Resumo em Inglês:

Adding ZnO reduces sintering temperature of yttria stabilized zirconia. Adding up to 0.5 wt% of ZnO is possible to densify to 8 mol% yttria stabilized zirconia (TZ8Y) to 95% of relative density at 1300 °C, besides, the electrical conductivity increases about 30% at 800 °C when compared to pure TZ8Y with the same relative density and average grain size. These results show that TZ8Y co-doped with ZnO can be a potential electrolyte to solid oxide fuel cells and electrolyzer cells.

Resumo em Inglês:

In this study, we investigate the oxidation behavior of copper at temperatures below 300 °C and its mechanism. A methodology to slow down the oxidation rate is then proposed based on the observed mechanism. The oxides formed after oxidation at low temperatures have fine crystal sizes; the rate constants reach 2×10-15 m2/s and 6×10-14 m2/s at 200 °C and 300 °C, respectively. A passivation treatment at 600 °C in nitrogen produces a thin oxide layer composed of relatively large Cu2O crystals. The presence of such a layer slows down the oxidation rate constants by an order of magnitude. This study demonstrates that the oxidation of copper at low temperatures is controlled by the grain boundary diffusion. Increasing the crystal size in the surface oxide reduces the oxidation rate significantly.

Resumo em Inglês:

In the present study, PHB film was prepared by thermo-compression molding and PHB nanofibers mat was produced through electrospinning process. The nanofibers morphology was confirmed by SEM. The film and nanofibers crystallinity degree was estimated by different methods. FTIR and WAXD indicated that PHB film is more crystalline than PHB nanofibers. However, DSC analysis suggested that a PHB nanofibers phase change might occur while the temperature rises. SAXS indicated that PHB film and nanofibers have low electron density contrast between the alternating crystalline and amorphous layers. The influence of nanofiber morphology on the mechanical, surface and thermal properties was also shown in TG analysis, tensile tests and contact angle measurements.

Resumo em Inglês:

Self compacting concrete (SCC) requires a large quantity of fine materials compared to common concrete. In this work waste glass powder was used to replace (50%) of filler required. Two types of SCC were manufactured, a control SCC type (CTL) using cement and limestone filler and another with glass powder replacing 50% of the filler. Mechanical and durability properties, namely, compressive strength, resistivity, chloride ion penetration, carbonation, capillary water absorption and oxygen permeability were assessed on both SCC types. It could be concluded that waste glass powder can be used successfully in SCC improving chloride penetration and water absorption by capillarity and maintaining strength levels. The potential risk of alkali-silica observed on mortar was mitigated when incorporating glass powder.

Resumo em Inglês:

The present work aimed to study sugarcane bagasse fibers pre-treated with fungi and using NaOH/ anthraquinone (AQ) in chemical pulping processes for applications in composite materials. Bagasse was decayed with 250 mg of Ceriporiopsis subvermispora inoculum in a 20 L bioreactor. After that, samples were submitted to similar conditions of decaying without inoculum charge. Decayed and undecayed fibers were treated with NaOH 12.5 wt%, 0.15 of AQ and a 12:1 (v/w) liquor:bagasse ratio at 160°C. Then, all obtained fibers were characterized according to their chemical composition. Dried biotreated (decayed) and control (undecayed) fibers were mixed through an extruder process with polypropylene. Later, composite granulates were injected directly in mold with cavities for tensile, flexural and shear tests. Composite materials with 10 and 20 wt% fibers were submitted to static mechanical standard tests and DMA (Dynamic Mechanical Analysis) to evaluate the effect of biotreatment. Biotreatment, cook time (pulping), and fiber content contributed to improvements in the mechanical properties of the composites. The interface between fiber and matrix was increased with the biotreatment and pulping of fibers. Furthermore, DMA results also showed that fiber incorporation into PP improved the modulus, mainly for biotreated fibers/PP composites. The Tg (tan δ data) from composites was dislocated at lower temperatures with respect to neat PP due to the influence of fibers on matrix.

Resumo em Inglês:

Special polymers have been used in the manufacture of storage structures and pipelines avoiding corrosive processes during ethanol fuel transport/storage. Therefore, this work investigated comparatively the effects of the ethanol on the physical-mechanical properties of poly (ether ether ketone) (PEEK) and polyamide 11 (PA-11) based on ageing tests. The WAXD and DSC results demonstrated slight reductions on the crystallinity degree of the aged PEEK, contrariwise to what happened with PA-11, where Xcincreased after ageing. However, the results of thermal, thermomechanical and mechanical analysis (TGA, DMTA, tensile and micro-IITs) demonstrated that PEEK is stable and no significant changes were observed in its elastic modulus (Ey≈ 3.4 GPa, E’ andEit≈ 3.7 GPa) or glass transition temperature. PA-11, conversely, was sensitive to ethanol fuel and expressive changes of its physical-mechanical properties were verified. For both materials, a reasonable correlation between crystallinity and mechanical properties was established.

Resumo em Inglês:

Conventional single superphosphate (SSP) is known as one of the most important and common sources of phosphorus in agriculture. Despite SSP has been widely produced as a fertilizer, a few studies have been done to describe the fundamental aspects of this P-fertilizer, i.e., phase composition, thermal degradation behavior, and solubility kinetics. Therefore, this paper reports on the detailed characterization of SSP powders by correlating their properties with particle size and surface area. Commercial SSP fertilizers were milled under different conditions and the resulting powders were characterized by X-ray diffraction, thermogravimetric analyses, scanning electron microscopy, FT-IR spectroscopy, and solubilization tests. It was observed that short milling times favored the solubilization kinetics, whereas long milling times were deleterious due to agglomeration effects. It was pointed out that agglomeration plays an important role in phosphate availability. These results provided a deeper understanding of SSP powders in microstructural terms, and may be used as a foundation for the development of novel strategies of alternative production of phosphorus fertilizers.

Resumo em Inglês:

This study compares a wound dressing based on bacterial cellulose/collagen (BC/COL) hydrogel in rat dorsum with commercial collagenase ointment and untreated wound. The hydrogel was characterized by Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA), Fourier transformed - Infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). According to the In vivo test and macroscopic evaluation, BC/COL hydrogel showed a better repair of wounds and promoted statistically significant differences of tissue repair between treatments on the 7th day after surgery. Better quality, quantity and orientation evaluation of collagen fibers (p=0.0001) were observed in the BC/COL hydrogel and collagenase ointment groups in relation to the control group. The BC/COL hydrogel promoted better wound healing than collagenase and the control group, therefore, it can be considered a potential wound dressing for skin regeneration.

Resumo em Inglês:

Friction stir welding was used to produce butt joints on 6 mm thick plates of UNS S32101 lean duplex stainless steel, S32205 duplex stainless steel, and S32750 and S32760 superduplex stainless steels. Fully consolidated joints were achieved, with full penetration, using heat input of 1.37-1.50 kJ/mm. Specimens submitted to tensile testing performed perpendicular to the welding direction showed failure on the base metal, reflecting better mechanical performance of the welded joints. Furthermore, tensile testing along the joints revealed higher yield and tensile strengths in all cases, as well as increased elongation. Microstructural evaluation showed that there was pronounced grain refinement in the welded joints of all the materials studied, achieving grain sizes as small as 1 µm. The differences in the ferrite and austenite grain sizes in the stir zone, such as the degree of grain refinement, could be explained by the combination of dynamic recrystallization of austenite during the welding process and the recrystallization and growth of the ferrite grains, promoted firstly by the severe deformation and secondly by the high temperature inherent to the FSW process. Superduplex stainless steel FSW joints were more able to maintain a balanced microstructure, compared to conventional and lean duplex stainless steels, due to greater homogeneity of recrystallization in the welded joint.

Resumo em Inglês:

Maghnite- H+ is Algerian montmorillonite sheet alumino-silicate clay, exchanged with protons (H+). This solid non-toxic catalyst was successfully used as cationic catalyst for the polymerization of D,L-Lactid at 100°C. Interactions between Maghnite-H+ platelets and the monomer (D,L-Lactide) were studied by solid state 1H, 27Al and 29Si NMR spectroscopy. The results show that, the mechanism of the reaction involves both Brønsted and Lewis acid sites on Maghnite surface.

Resumo em Inglês:

Pectin and starch are edible, non-toxic, biodegradable and obtained from renewable sources. Also, have the benefit to be easily cross-linked producing hydrogels. Reactive extrusion with edible citric acid and cross linking interactions was evaluated on extruded thermoplastic in natura and cationic starch-pectin blends. Materials water susceptibility and mechanical properties were characterised. Reactive extrusion decreased (up to 75% in natura starch) mechanical properties. Also have decreased (up to 32.4%) both starch polymers water absorption, indicating the possibility of increasing materials water barrier properties but had the opposite effect on the pectin-TPS material, probably related to a cationic-anionic cross linking, resulting in a hydrogel polymer. Reactive extrusion also have negatively affected mechanical properties of both starch polymers, however increased pectin-TPS blends stress and strain at rupture.

Resumo em Inglês:

Shipbuilding is going through a period of revitalization, growth and technological advancement. One component of these innovations is to improve welding techniques and materials for optimizing processing time, reducing costs and to improve properties and ship performance. The aim of the present work is to evaluate the welding of microalloyed shipbuilding steel, AH36, using the submerged arc welding (SAW) process with one and two wires. The mechanical properties of the welded joint will be presented using microhardness and Charpy V-notch testing. For metallographic characterization, the base metal and welded joint were etched with 2% Nital and Klemm's I reagent. Scanning electron microscopy, X-ray diffraction and colored etching were used to quantify and verify the presence of martensite and retained austenite, the MA microconstituent. The results obtained from Charpy impact tests and another mechanical test can be correlated with the associated microstructure.

Resumo em Inglês:

The residual stress state of a mechanical component is an important factor in its production planning and in estimates of its lifecycle since it can be responsible for geometric distortions and degradation of fatigue properties. Therefore, the development of reliable methods for non-destructively quantifying these stresses remains in the interest of most manufacturing industries; Barkhausen magnetic noise measurements have been investigated in several applications and remains a viable option. However, its effective implementation has occurred mostly in components with simple geometries and insignificant microstructural gradients; even in these cases, successful industrial adoption of the method depends on previous calibration with samples that are often difficult and costly to prepare and validate. This work aims at investigating the capability of the method of characterizing the residual stress state in a simple but generally useful application: samples of hot-rolled steel sheets collected at two different stages of processing in an industrial mechanical conformation and heat treatment plant. In this analysis Barkhausen noise measurements were compared to X-ray diffraction results, and statistical analysis tools were used to correlate the results.

Resumo em Inglês:

The development of polyester based materials with enhanced properties as well as the use of post- consumer plastics as raw material has been an increasing market demand. This work aims the synthesis and characterization of aromatic polyesters/titanium dioxide nanocomposites from PET and using TiO2 (0, 1, 3 and 5% w/w) as filler by in situ polymerization. The results obtained by DSC, XRD and FTIR analyzes evidenced an interaction between the OH groups on the TiO2 surface with the ester groups of the polymer leading to decrease of the polymer crystallinity and of hydrophilicity. By SEM images was possible to note a homogeneous distribution of the filler into polymer matrix with 1%w/w TiO2 (average particle size of 199 nm), however for larger amounts of filler (3 and 5% TiO2) revealed the aggregates formation. The results showed an improvement of thermal properties and hardness of the nanocomposites containing TiO2 nanoparticles compared to pristine polyester.

Resumo em Inglês:

Rice hull is a residue from agro-industry that can be used to produce nanocellulose. We produced nanocellulose from rice hulls through bleaching (with a 5% NaOH solution followed by a peracetic acid solution) and acid hydrolysis at a mild temperature (45ºC) followed by ultrasonication. We investigated the microstructure, crystallinity and thermal stability of these materials and studied their effects on the properties of starch films. After bleaching, the compact structure around the cellulosic fibers was removed, and the lignin content of the residue decreased from 7.22 to 4.22%. The obtained nanocellulose presented a higher crystallinity (up 70%), higher thermal stability than the raw material and lignin contents below 0.35%. The nanocellulose formed interconnected webs of tiny fibers (< 100 nm in diameter), which decreased the opacity, water vapor permeability and improved the mechanical properties when added as reinforcement in the starch films.

Resumo em Inglês:

In the present work an attempt has been made to synthesize 304L stainless steels alloy powders with nominal compositions 70.00Fe-19.00Cr-11.00Ni (alloy A), 69.00Fe-19.00Cr-11.00Ni- 1.0 Y2O3(alloy B), and 69.00Fe-19.00Cr-11.00Ni- 1.0 TiO2(alloy C), (all in wt.%) by mechanical milling and conventional sintering at 1150°C for 1.0 hour in argon atmosphere. Extensive characterization has been done by SEM, TEM, X-ray diffraction analysis, EDS and particle size analysis at different stages of milling. The minimum crystallite size of powder at final stage of milling was found in the range of 20-25 nm. The bulk hardness values of base and Oxide dispersion strengthened alloys are 2.628 GPa, 4.125 GPa (average) respectively. Wear resistance of TiO2 dispersed alloy C is found to be superior to that of yttria dispersed alloy B and base alloy A. The nanometric oxide (20-25 nm) particles uniformly dispersed in the alloy matrix contribute to superior mechanical properties.

Resumo em Inglês:

The object of this study was to evaluate the flexural strength of glass fiber reinforced polyurethane composites under variable displacement rates. Flexural tests have been conducted at a range of displacement rates included 0.2, 2, 20, 100, 200, 1000 mm/min. Specimens with identical geometry have been used in all the tests. This particular composite has viscoelastic behavior with both elasticity modulus and ultimate flexural strength being strongly dependent of the displacement rate. Results showed that, both the flexural modulus and the ultimate flexural strength are increased with the increasing in the displacement rate.

Resumo em Inglês:

The inhibitory effect of Bauhinia purpurea (Fabaceae) extract was studied in the corrosion of carbon steel in 1.0 mol∙L-1 sulfuric acid solution. This plant was collected from the Brazilian rainforest. The carbon steel protection was observed by varying the extract concentration from 50 to 500 mg∙L-1. Polarization curves revealed that this extract acted as an adsorption inhibitor decreasing both anodic and cathodic density currents. Weight loss measurements showed that the extract remains stable for at least 72 hours. The adsorption process of this extract obeyed the Langmuir adsorption isotherm. Lastly, Arrhenius plot suggested the physical adsorption of the extract.

Resumo em Inglês:

The crystallization degree in semi-crystalline thermoplastics plays an important role in determining the final properties of structural composite material (e.g. toughness, stiffness and solvent resistance). The main purpose of this work is to study different induced degrees of crystallinity in carbon fiber (CF) reinforced polyphenylene sulfide (PPS) composites, by using three different cooling rates during hot compression molding processing (51%, 58% and 62% of crystallinity). In this study, the morphology, thermal and mechanical properties of the produced laminates were investigated and compared. The results showed an increase in the storage modulus (9.8%), Young's modulus (9.2%) and ILSS (14.2%) for the lower cooling rates. Evidences of fiber/interface improvement and crystallites nucleation on the fiber reinforcement surface were also identified.

Resumo em Inglês:

Dielectric Barrier Discharge (DBD) is a promising technique for producing plasma in atmospheric pressure and is gaining emphasis in several areas, especially in the biomedical and textile industries, among other. This is due to the fact that this plasma does not reach high temperatures, enabling its use on thermally sensitive materials. However, there is still the need for the development of research relating to the field of physical mechanisms of non-thermal plasma. In this work, we studied the behavior of plasma in DBD equipment, varying distance between electrodes. For this study, two distinct characterization techniques were used. The first, the Lissajous Figures method, is effective and precise in the electrical characterization of DBD equipment. The second technique used, Optical Emission Spectroscopy (OES) is an effective tool in the diagnosis of plasma. This tool enables the identification of excited species in plasma. With the data produced, it was possible to identify an appropriate distance for producing plasma with a higher intensity and homogeneity of active species.

Resumo em Inglês:

The twin roll cast Mg-4.5Al-1.0Zn alloy sheets, processed by asymmetric rolling and subsequent annealing were investigated. The asymmetric rolling on Mg-4.5Al-1.0Zn ingot was also studied for comparison in terms of microstructure, texture and mechanical properties of the sheets. The results can be summarized as follows. The rolled sheets show intensively deformed band structures and fine grains due to dynamic recrystallization. After annealing at 375 °C for 1 hr, both the twin roll casted and ingot processed sheets show the fine equiaxed grains with around 9 μm in mean diameter. The twin roll casted magnesium alloy sheet shows superior tensile strength and low elongation compared to the ingot cast one. The results of this work suggest that asymmetric rolling can improve the formability of magnesium alloy and the technique could be extended to enhance the sheet qualities of different alloys in jewelry industry.

Resumo em Inglês:

In this paper, the mechanical, dry shrinkage and frost resistance performance of cement stabilized graded stone with framework and dense structure were investigated. A higher cement content owns a correspondingly better mechanical performance. With the different moisture content, the dry shrinkage and frost resistance performance of cement stabilized graded stone showed a similar improving and deteriorating trend. The specimens (sample 0, 1, 2, 3) , with different moisture content (4%, 5%, 6%, 7%) in a 6% cement content, were measured and analyzed. A sample contained low moisture content has a relatively loose and dry mixtures, which owns a insufficient cement hydration reaction and low strength, finally leads to a weaker dry shrinkage resistance performance. Moreover, the high moisture content sample has a damp and flabby reaction procedure, which has a larger amount of moisture evaporation and further deteriorated dry shrinkage. The moisture content significantly influence the pore parameters of prepared samples, whose trend followed those of dry shrinkage and frost resistance performance. The pore size distribution of these composites shifted toward smaller pore size scope with a proper moisture content. In addition, scanning electron micrographs (SEM) showed that the denser microstructure of prepared cement stabilized graded stones.

Resumo em Inglês:

Mixed matrix membranes are promising options for improving gas separation processes. Zeolitic imidazolate frameworks (ZIFs) have a porous structure similar to conventional zeolites, being capable in principle of separating gases based on their differences in kinetic diameter while offering the advantage of having a partial organic character. This partial organic nature improves the compatibility between the sieve and the polymer, and a combination of the mentioned characteristics makes these hybrid materials interesting for the preparation of mixed matrix gas separation membranes. In this context the present work reports the preparation of Ultem®/ZIF-8 mixed matrix membranes and their permeabilities to pure CO2, N2 and CH4gases. A significant increase in permeability with increase in CO2/N2 selectivity was observed for the mixed matrix systems as compared to the properties of the neat Ultem®. Sorption results allowed to speculate that the ZIF-8 framework is not completely stable dimensionally, what influences the separation process by allowing gases with higher kinetic diameter than its nominal aperture to be sorbed and to diffuse through the crystal. Sorption and diffusion selectivities indicate that the higher separation performance of the mixed matrix membranes is governed by the diffusion process associated with the influence of gas molecule's geometry.

Resumo em Inglês:

A compatibilizer agent was successfully produced by grafting maleic anhydride (MA) to poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) chains on a reactive processing by mechanical mixing, using a mixture of PHBV, MA and dicumyl peroxide (DCP) as initiator. The resulting PHBV grafted MA (PHBV-g-MA) was characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and gel permeation chromatography (GPC), and its properties were compared to neat PHBV. FTIR showed an absorption band at 699 cm-1 for PHBV-g-MA, related to CH group of grafted anhydride ring. The initial thermal degradation temperature of the compatibilizer agent was reduced when compared to neat PHBV. DSC analysis showed that after grafting MA onto PHBV the crystallization temperature was about 20ºC higher than neat PHBV, and the degree of crystallinity was increased. GPC analysis showed that MA when grafted onto PHBV led to a reduction of molecular weight and polydispersity.

Resumo em Inglês:

The aim of this study was to obtaining an adhesive made of dimethacrylate copolymer and clay particles in different concentrations. The samples were prepared by light curing and were evaluated by XRD, FTIR and TGA as well as by measuring flexural strength, elasticity modulus and tensile resistance. The XRD and the mechanical test results indicated that the system with 0.2% clay is exfoliated, while the highest concentrations showed the agglomeration of these clays. FTIR was used to determine the conversion, and showed that use of clays particles are unable to significantly alter the polymerization until 1.0%. However, for the group containing 1.5%, there was a decline in this index. In the thermogravimetric analysis, only the groups with 0.2% of clays showed increased thermal resistance. In conclusion, the incorporation of clay at 0.2% concentration produces a well-dispersed system and can be applied as a dental adhesive.

Resumo em Inglês:

In this work, Al-12.6Si-2Co (wt.%) ternary alloy of near eutectic composition was directionally solidified at a constant temperature gradient (G=7.60 K/mm) in a wide range of growth rates (V=8.35-166.30 µm/s) using by Bridgman type growth apparatus. Flake spacing (λ), microhardness (HV), tensile stress (σ) and electrical resistivity (ρ) were measured from directionally solidified samples. The dependence of flake spacing, microhardness, tensile stress and electrical resistivity on growth rate (V) was also determined by statistical analysis. According to these results, it has been found that for increasing values of V, the values of HV, σ and ρ increase. Variations of electrical resistivity (ρ) for casting Al-Si-Co alloy were also measured at the temperature in range 300−500 K. The enthalpy of fusion (ΔH) for the Al-Si-Co alloy was determined by differential scanning calorimeter (DSC) from heating trace during the transformation from solid to liquid. The results obtained in this work were compared with the previous similar experimental results obtained for binary and ternary alloys.

Resumo em Inglês:

The present paper describes an experimental testing method connected with use of the thermal-voltage-derivative analysis (the ATND method in short) to crystallization recording of the AlSi13Cu2Fe eutectic alloy in aspects of possible prediction of its mechanical properties, basing on dependencies obtained from regression analysis, performed on the basis of temperature and voltage values of characteristic points seen on curves from the ATND method. Results of the experiment have demonstrated a significant relation between values of the characteristic points from the ATND method and the mechanical properties (yield strength R0,2 and hardness HB 10/1000/30). Moreover, obtained dependencies have enabled prediction of the yield strength R0,2 and the hardness HB 10/1000/30 as early as at preparation stage (melting) of the investigated alloy, what allows quick correction of performed modification process.

Resumo em Inglês:

An experimental investigation was conducted using laboratory-processed low carbon Mn-Mo-Nb-Ti-B dual phase steel with additions of 0.2Cr or 0.6%Cr. This study investigates the effect of Cr additions on ferrite recrystallization and austenite formation during continuous annealing in the intercritical temperature range. It was found that moderate additions of Cr (0.2%) accelerates the ferrite recrystallization (nucleation and growth) resulting in coarse ferrite grains. An increase in Cr content up to 0.6% also accelerates the ferrite recrystallization which in addition to the presence of Cr-rich carbides facilitates the austenitization predominantly through the nucleation process resulted in finer austenite grains. Thereby, the higher Cr content increases the volume of homogenized and refined martensite in the final quenched structure.

Resumo em Inglês:

Fluorine-doped tin oxide (SnO2:F) was investigate as the sensitive part of a pH sensor in the extended-gate field effect transistors (EGFET) device, which provided a linear response for pH range from 2 to 12; the sensitivity was 37 mV.pH-1 for experiments performed in absence of light. Neutral pH, leads to a transistor’s electric current remained practically constant, suggesting that pH 7 correspond to the isoelectric point of the SnO2:F samples. For acid and alkaline pH, the power law varied along time and stabilized at about 10 min. UV-vis light did not alter the results. The transistor’s electric current increased with the operating temperature increases. Once that small change in the operating conditions can alter the results, the physical mechanisms underlying the sensing process must be clearly understood. It is essential to monitor transient response and measurements conditions.