Abstract Age delimitation integrated with aeromagnetometric and aerogammaspectrometric survey advances the understanding of ophiolite evolution in the Brasiliano Orogen. We focused on the Bossoroca ophiolite, because oceanic crustal and mantle rocks contain zircon in metasomatic chloritite. A metadiorite and a metavolcanoclastic rock were also studied to delimit relationship between ophiolite and island-arc infrastructure and superstructure. Zircon crystals were dated by laser ablation inductively coupled plasma emission spectroscopy. Ages of zircon from Campestre metavolcanoclastic rock are 920-840 (peak 842) Ma, Bossoroca chloritite 900-800 (peak 868 Ma) and Capivaras metadiorite 698 Ma. Ages 920-800 Ma correspond to processes in the oceanic crust, whereas 698 Ma was a late magmatic intrusion (Capivaras metadiorite) into the island-arc infrastructure. Aeromagnetometric and aerogammaspectrometric data delimit the occurrence and structure of the ophiolite. These are major multiproxy markers of geotectonic processes early in the Brasiliano Orogen.

Abstract Collisional granites of the Araçuaí Orogen, southeastern Brazil, record petrological and geochronological evidence for multiple crustal melting during the orogeny evolution. U-Pb zircon data indicate that these granites crystallized at 586 ± 2 M.y. High-grade metamorphism (M1) involved partial melting by fluid-absent reactions that produced the first generation of garnet in temperatures of approx. 750°C. Preservation of the mineral assemblage A1 (garnet-biotite-plagioclase-K-feldspar-quartz-ilmenite-melt) indicates that most of the generated melt was lost from these rocks at or near peak metamorphic conditions. A second metamorphic event (M2) is characterized by growth of a second generation of garnet in preserved A2 assemblage (garnet-sillimanite-biotite-plagioclase-K-feldspar-quartz-ilmenite-melt). Mineral equilibria modeling constrains conditions of M2 metamorphism to 713-729 °C and 6.2-7.3 kbar. Retrograde assemblage (A3) records equilibrium conditions at 610-660 °C. The Hf isotope composition indicates significant crustal contribution to the genesis of the collisional granites. The elevated geotherms in thickened crust provide enough heat for the M1 event at 562 ± 2 M.y. Subsequent heating probably associated to the transfer of mantle heat to the crust during the extensional thinning and gravitational collapse of the orogen lead to the M2 event at 526 ± 4 M.y. This event is concomitant to the emplacement of the post-collisional magmas in the orogen.

Abstract The Moeda Formation (Caraça Group, base of Minas Supergroup) registers the initial rift stages of the Minas Basin in the Quadrilátero Ferrífero, Southern São Francisco craton, SE-Brazil. We present stratigraphic and U-Pb detrital zircon dating analyses of the Moeda Formation that contribute to the comprehension of its sedimentary evolution in the southernmost Gandarela and Ouro Fino synclines (Central-Eastern Quadrilátero Ferrifero). The Moeda Formation sequence consists of a basal proximal alluvial fan with clast-supported conglomerates, grading upward into an alluvial floodplain with quartz arenites, and upper massive sandstones from distal fluvial fans. Because the Moeda Formation is normally limited by similar lithologies at both its base (Nova Lima Group, Rio das Velhas Supergroup) and top (Batatal Formation, uppermost Caraça Group) and stratigraphic inversion has occurred in the study area, U-Pb detrital zircon dating was also extended to these units to differentiate them stratigraphically. The youngest clusters of detrital zircon ages in the Nova Lima Group and Moeda and Batatal formations were 2716, 2777 and 2786 Ma, respectively. Based on our data and relevant literature, the depositional age of the Moeda Formation was interpreted as between 2716 and 2520 Ma with the Mesoarchean continental crust, the Rio das Velhas Supergroup and the Archean TTG complexes as its main source areas.

Abstract The isotopic and geochemical evolution of tourmaline constrain the processes of paleo-oceanic lithosphere in ophiolites. The Brasiliano Orogen is a major structure of South America and requires characterization for the understanding of Gondwana supercontinent evolution. We made a pioneering investigation of tourmaline from a tourmalinite in the Ibaré ophiolite by integrating field work with chemical analyses of tourmaline by electron microprobe (EPMA) and δ11B determinations via laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS). Remarkably massive tourmalinite (>90 vol.% tourmaline, some chlorite) enclosed in serpentinite has homogeneous dravite in chemical and isotopic composition (δ11B = +3.5 to +5.2‰). These results indicate a geotectonic environment in the altered oceanic crust for the origin of the tourmalinite. This first δ11B characterization of tourmaline from tourmalinite sets limits to the evolution of the Neoproterozoic to Cambrian Brasiliano Orogen and Gondwana evolution.

Abstract Orthogneisses associated with metavolcanosedimentary successions related to the 1000 - 920 Ma Cariris Velhos event occur mainly in a ca. 700 km-long sigmoidal-shaped belt that crosscuts the Transversal Zone of the Borborema Province and extends to the fold belts located in its southern or external zone (part of the Riacho do Pontal and Sergipano orogens). Despite its importance, the tectonic setting and the role of those rocks in the geological evolution of the Borborema Province are contentious and not yet well understood. New zircon U-Pb SHRIMP data on an augen-gneiss sill of the Afeição Suite intruding mica-schists mapped as part of the Santa Filomena Complex yielded a Concordia Age of 974 ± 11 Ma, indicating that at least part of the metasedimentary rocks in the internal zone of the Riacho do Pontal Orogen are Tonian or older and possibly related to the Cariris Velhos event. Hf-in-zircon isotope data are presented for the first time for Cariris Velhos-related ortho-derived rocks of the Afeição Suite. Analyzed samples yielded εHf(t) in a narrow range between -1.51 and +2.41, with associated TDMHf of 1.6-1.4 Ga, similar to previously obtained Nd isotope data with εNd(t) = -1.0 to +3.1 and TDMNd of 1.5-1.2 Ga. A possible scenario to explain both the geochemical features and the moderately juvenile to slightly evolved, near-chondritic Hf and Nd isotope signatures is a continental arc setting, where fractionated melts produced in the supra-subduction zone mantle wedge carrying a Tonian juvenile signature became contaminated with discrete amounts of Archean-Paleoproterozoic continental crust during ascent, producing Mesoproterozoic model ages which represent the mixture of those two end-members.

Abstract The Quadrilátero Ferrífero metallogenetic province is located in the southernmost portion of the São Francisco craton, SE Brazil. The Tamanduá and Cambotas ridges stand out topographically in the northeastern portion of Quadrilátero Ferrífero and show NE-SW and N-S directions, respectively. Those ridges involve metasedimentary rocks of the Tamanduá Group bounded by a fault system. Due to stratigraphic and structural complexities, there is little consensus about the maximum sedimentation age and the stratigraphic position in which Tamanduá Group sediments were deposited. In this work, we took advantage of the excellent exposures in the Tamanduá and Cambotas ridges to present detailed stratigraphic observations combined with U-Pb zircon geochronological data from samples of different stratigraphic levels of Tamanduá Group. Furthermore, we provide U-Pb data from samples of the intrusive Pedra Formosa Suite that cut the whole Tamanduá sequence in the study area. Our observations showed that the Tamanduá Group represents a rift-sag basin-fill succession developed along the eastern border of the São Francisco paleoplate. The basal metaconglomerate and metasandstone package grades upward into marine metasandstone and phyllite. Detrital zircon obtained from the basal unit, Antônio dos Santos Formation, reveals maximum depositional ages between ca. 1981 and 1770 Ma. The upper succession, Cambotas Formation, shows a maximum depositional age from 1769 to 1740 Ma. The Pedra Formosa Suite shows zircons that crystallized at ca. 1740 Ma. The stratigraphic framework and the Orosirian-Statherian ages suggest a correlation with the first rifting event within the São Francisco paleoplate, the precursor of Paleo- to Mesoproterozoic Espinhaço basin.

ABSTRACT In the Southeastern Quadrilátero Ferrífero, a package of metapelitic rocks previously attributed to the Archean Rio das Velhas Supergroup crops out in Piranga locality. This study presents the mineral chemistry and U-Pb-Hf zircon geochronology on foliated staurolite-garnet mica schists. Garnet and staurolite index minerals are syn- to post-kinematic towards the main schistosity. Garnet porphyroblasts display well-developed compositional zoning of Mg-Fe-Mn-Ca, with increase of almandine and pyrope and decrease of spessartine towards the rim, implying in prograde metamorphic pattern. Estimates of P-T values for the metamorphic peak resulted in temperatures between 630 to 650ºC and pressure around 7 kbar. Pseudosections show well-defined stability fields in amphibolite facies, with a metamorphic path displaying progressive increase in P-T conditions. Maximum depositional age of 1,875 ± 51 Ma is established for the Piranga mica schists pointing to a depositional history that is younger than those previously described. Metamorphic Cambrian ages characterize the strong influence of deformational processes related to the final stages of Brasiliano Orogeny in the Southeastern Quadrilátero Ferrífero.

Abstract The Quadrilátero Ferrífero is an important mineral province located in Southern São Francisco craton, SE Brazil. Its prominent feature is the Gandarela syncline that was formed as part of the regional deformation event in the southernmost part of the craton at ca. 2,000 Ma. The syncline exposes several economically important units of Rio das Velhas and Minas supergroups, widely known for their gold and iron ore mineral deposits. This work focused on the upper Minas Supergroup — Cercadinho Formation and Sabará Group in the Gandarela syncline. We showed detail stratigraphic surveys combined with U-Pb detrital zircon analysis. Data reveal the development of high- to low-density turbidity systems. The first one is related to the deposition of Cercadinho Formation that marks the siliciclastic infilling of the Minas basin. For the Sabará Group, a fine turbidite system of foredeep depocenter is inferred. The detrital zircon analysis indicates that their sediments were derived from Archean, Rhyacian, and Orosirian exhumed terrains, besides granitoids positioned to the south and east of Quadrilátero Ferrífero. We proposed the age of 2,036 ± 25 Ma as the maximum age of deposition of Sabará Group, whose sedimentation occurs in the first stages of Minas accretionary orogeny.

ABSTRACT: In the Itacambira-Monte Azul block (BIMA) the Archean rocks are represented by tonalite-trondhjemite-granodiorite (TTGs) of the Porteirinha Complex and by potassic granitoids of the Rio Itacambiruçu Suite that crop out at the Pedra do Urubu (PUp), Rio Gorutuba (RGp), Barrocão (BAp) and Lagoa Nova (LNp) plutons. This work presents new data for the PUp, RGp and BAp. The petrographic and lithochemical analyses allowed the subdivision of the Rio Itacambiruçu Suite in two groups of granitoids: a medium potassium group, represented by the PUp and RGp, and a high potassium group, in which the BAp rocks are inserted. The geochronological data showed different ages for the medium and high potassium groups, with crystallization ages at ca. 2.92 Ga and 2.65 Ga, respectively. Despite the differences observed between these two groups, the chemical signatures of these rocks are compatible with the signature of biotite-granites generated by the reworking of ancient continental crust. Thereby, the data obtained in this work, added to some previously published results, allowed to the identification of two Archean crustal stabilization events recorded in BIMA, one of Mesoarchean age and the other of Neoarchean age. In addition, we propose the lithodemic reclassification of the Rio Itacambiruçu Suite to Rio Itacambiruçu Supersuite.

RESUMO: No Distrito Esmeraldífero de Itabira-Nova Era, sudeste do Brasil, esmeralda gemológica é extraída em minas subterrâneas em depósitos do Tipo Xisto na zona de contato da sequência metavulcanossedimentar arqueana do Complexo Guanhães com granitos anorogênicos paleoproterozoicos da Suite Borrachudos. Depósitos do Tipo Xisto são comumente gerados por reações promovidas por deformação e calor durante metamorfismo regional. A idade da mineralização na região tem sido motivo de debates por décadas: idades variando do Arqueano ao Neoproterozoico são mencionadas na literatura. Na zona mineralizada da mina Piteiras, titanita portadora de alumínio e flúor é encontrada em rochas metamáficas. O conteúdo de flúor foi provavelmente derivado dos granitos e pegmatitos Borrachudos, tal como o berílio para a esmeralda, portanto ambos minerais podem ter sido gerados durante o mesmo evento. Geocronologia U-Pb via ablação a laser associada a espectrometria de massa por plasma acoplado indutivamente laser (LA-ICP-MS) em titanita foi realizada em uma seção delgada de um flogopita-plagioclásio-hornblenda xisto da mina Piteiras. A idade determinada de 576 ± 7 Ma é também a provável idade de geração da esmeralda durante o ciclo Brasiliano, que foi o único evento tectonometamórfico posterior à intrusão dos granitos. Este evento forneceu calor e fluidos necessários para reações entre as rochas portadoras de berílio e de cromo, possibilitando assim a formação de esmeralda.

ABSTRACT: In the Itabira-Nova Era Emerald District, southeast Brazil, gemological emerald is extracted from underground mines found in schist-type deposits at the contact zone of the Archean Metavolcanosedimentary Sequence of the Guanhães Complex and Paleoproterozoic anorogenic granites of the Borrachudos Suite. Schist-type deposits are commonly generated by reactions enhanced by deformation and heat during regional metamorphism. The age of the mineralization in the region has been a matter of debate for decades: Ages ranging from the Archean to the Neoproterozoic are mentioned in the literature. In the mineralized zone from the Piteiras mine fluorine-aluminum-bearing titanite is found in metamafic rocks. The fluorine content was probably derived from the Borrachudos granites and pegmatites like the beryllium for emerald, thus both minerals could have been generated during the same event. U-Pb titanite geochronology via laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was performed on a thin section of a phlogopite-plagioclase-hornblende schist from the Piteiras mine. The determined age of 576 ± 7 Ma is also the probable age for emerald generation during the Brasiliano cycle, which was the only tectonometamorphic event postdating the intrusion of the granites. This event provided heat and fluids necessary for reactions between the Be- and the Cr-bearing rocks, thus enabling the formation of emeralds.

Abstract This paper presents the results of a petrographic and geochronological investigation of the Furquim Quartzite (FQ) to establish its stratigraphic correlation to quartzitic units of the Quadrilátero Ferrífero (QF) province. The Quartzite comprises a ca. 20km long and 1-6km wide ridge overlying discordantly the Archean to Paleoproterozoic gneissic basement and rocks of the Archean Rio das Velhas Supergroup between the city Mariana and the town Furquim, southeast of the QF. Despite the discordant contacts, previous field-based stratigraphic studies considered the Furquim Quartzite as part of the Archean Maquiné Group – top unit of the Rio das Velhas Supergroup. U-Pb zircon geochronology via LA-ICP-MS identified several detrital populations ranging from Paleoproterozoic to Archean age. The youngest population of 2087±19 Ma defines the maximum age for the sedimentation of the precursor sandstone. This age can be correlated to be the age of the youngest zircon population of the Itacolomi Group quartzites in the QF. Thus, in contrast to previous studies, the results indicate that the FQ is an eastern extension of the Itacolomi Group, the youngest unit of the Paleoproterozoic Minas Supergroup.

Introdução: Estudos demonstram que a intervenção coronária percutânea primária realizada fora do horário de rotina está relacionada a pior prognóstico. Nosso objetivo foi avaliar os desfechos da intervenção coronária percutânea primária realizada nos períodos diurno e noturno em um centro cardiológico de referência. Métodos: Estudo de coorte prospectivo, que incluiu 1.108 pacientes consecutivamente atendidos por infarto agudo do miocárdio com supradesnivelamento do segmento ST, divididos nos grupos intervenção coronária percutânea primária diurna (se realizada entre 8 e 20 horas) e intervenção coronária percutânea primária noturna (se realizada entre 20 e 8 horas). Resultados: Incluímos 680 pacientes no grupo diurno e 428 no grupo noturno. As características basais referentes ao perfil demográfico, fatores de risco e classificação Killip foram semelhantes em ambos os grupos, porém o tempo porta-balão foi significativamente maior no grupo noturno (84 ± 66 minutos vs. 102 ± 98 minutos; p < 0,01). Vasos culpados, e fluxos TIMI pré e pós-procedimento não foram diferentes entre os grupos. Não encontramos diferenças significantes em relação à mortalidade hospitalar (7,6% vs. 10,2%; p = 0,16), trombose de stent (2,8% vs. 2,4%; p = 0,69) ou presença de sangramento maior (1,9% vs. 2,1%; p = 0,50). Em 1 ano, a mortalidade também foi semelhante (9,5% vs. 12,6%; p = 0,12). O principal preditor de mortalidade em 1 ano foi a classe III/IV de Killip (OR = 10,02; IC 95% 5,8-17,1; p < 0,01). Conclusões: Pacientes com infarto agudo do miocárdio apresentam taxas de desfechos clínicos semelhantes, independentemente do horário de realização da intervenção coronária percutânea primária. No entanto, o tempo porta-balão é significativamente maior nos pacientes tratados entre 20 e 8 horas.

Background: Previous studies have shown that off-hours primary percutaneous coronary interventions are related to a worse prognosis. The objective of this study was to evaluate the outcomes of patients undergoing on- and off-hours primary percutaneous coronary interventions performed at a reference cardiology center. Methods: Prospective cohort study, including 1,108 consecutive patients with ST elevation myocardial infarction divided into primary percutaneous coronary intervention performed during regular working hours group (on-hours: 8:00 am to 8:00 pm) and primary percutaneous coronary intervention during nonregular working hours group (off-hours: 8:00 pm to 8:00 am). Results: The sample included 680 patients in the on-hours group and 428 in the off-hours group. Baseline demographic data, risk factors and Killip classification were similar in both groups, however door-to-balloon time was significantly longer in the off-hours group (84 ± 66 minutes vs. 102 ± 98 minutes; p < 0.01). Culprit vessels, pre- and post-procedure TIMI flows were not different between groups. There were no significant differences for in-hospital mortality (7.6% vs. 10.2%; p = 0.16), stent thrombosis (2.8% vs. 2.4%; p = 0.69) or major bleeding (1.9% vs. 2.1%; p = 0.50). One-year mortality was also similar (9.5% vs. 12.6%; p = 0.12). The main predictor of mortality at 1 year was Killip III/IV (OR, 10.02; 95% CI, 5.8-17.1; p < 0.01). Conclusions: Patients with myocardial infarction have similar in-hospital clinical outcomes regardless of the time primary percutaneous coronary intervention is performed. However, door-to-balloon time is significantly longer in patients treated during off-hours.

Avaliaram-se os efeitos de quatro níveis de concentrado - NC (0, 1, 3 e 5 kg/vaca/dia) e dois de proteína bruta - PB (11 e 13% na matéria seca total) sobre o consumo, a digestibilidade e o desempenho de vacas leiteiras. Utilizaram-se oito vacas mestiças Holandês-Zebu com 520 ± 40 kg, distribuídas em um quadrado latino 8 × 8 em oito períodos de 10 dias para avaliação dos efeitos de tratamento, animal e período. O experimento foi conduzido em pastagem de capim-elefante (Pennisetum purpureum, Schum) na estação chuvosa e os concentrados foram constituídos de fubá de milho, farelo de soja, ureia e mistura mineral. O consumo de matéria seca (MS) não diferiu entre os tratamentos e o consumo do pasto tendeu a diminuir com o aumento de NC. Os consumos de PB e carboidratos não-fibrosos (CNF) aumentaram de acordo com os NC e PB na dieta, enquanto os consumos de nutrientes digestíveis totais, CNF, fibra em detergente neutro (FDN) e extrato etéreo aumentaram somente com aumento de NC. Os coeficientes de digestibilidade (CD) da MS e CNF aumentaram e diminuíram, respectivamente, com o aumento do NC, enquanto o CD da PB aumentou com os NC e PB e o CD da FDN aumentou com o nível de PB na dieta. A produção de leite aumentou somente com os NC. Os constituintes do leite não foram influenciados pelos NC, mas houve aumento do teor de lactose e extrato seco do leite com o aumento da PB na dieta. Vacas em pastagem no período das águas e produzindo 12 kg de leite/dia podem receber dietas contendo 11% de PB e a resposta à suplementação é baixa, variando de 0,63 a 0,22 kg de leite/kg de concentrado, em comparação aos 2,2 kg/kg sugerido pelo NRC 2001 de gado de leite.

The effects of four levels of concentrate - LC (0, 1, 3 and 5 kg/cow/day) and two of crude protein - CP (11 and 13% crude protein in total dry matter) on the intake, digestibility and performance of milking cows were evaluated. Eight crossbred Holstein-Zebu cows with 520 ± 40 kg were distributed in an 8 × 8 Latin square in eight 10-day periods for evaluation of effects of treatment, animal and period. The experiment was conducted on elephant grass (Pennisetum purpureum, Schum) pasture in the rainy season and the concentrates consisted of corn meal, soybean meal, urea and mineral salt. The dry matter (DM) intake was not different among treatments, and the pasture intake tended to decrease with increase in LC. The intakes of CP and non fiber carbohydrates (NFC) increased as a function of increase in LC and CP in the diet, while the intakes of total digestible nutrients, NFC, neutral detergent fiber (NDF) and ether extract increased only with increases in LC. The digestibility coefficients (DC) of DM and NFC increased and decreased, respectively, with increase in LC; the DC of CP increased with LC and CP; and the DC of NDF increased with increase in CP in the diet. The milk production increased only with increased LC. The milk components were not affected by LC, but there was increase in the lactose and dry extract contents in the milk with increase in dietary CP. Cows on pasture during the wet season and producing 12 kg of milk/day can receive diets containing 11% CP and the response to concentrate supplementation is low, varying from 0.63 to 0.22 kg milk/kg of concentrate, compared with 2.2 kg/kg suggested by the NRC 2001 for dairy cattle.