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Interaction of molten salts in the systems SiO2-Al2O3

Interação de sais fundidos no sistema SiO2-Al2O3

The aim of this study was to realize and evaluate laboratory corrosion tests for a solution of problems such as wear of refractory materials at processing of aluminum, for example. The static crucible corrosion tests were carried out in laboratory resistive furnace at 850 °C during 2 h air atmosphere. Two standards of alumina-silica shaped refractory bricks were used as a corroding material. Pure sodium chloride and potassium chloride were applied as a corrosive media. The results of tests were evaluated by macroscopic, microscopic, chemical and semiquantitative EDX analysis. Sodium chloride shows more significant penetration and chemical interaction in penetrated area. EDX analysis confirms creation of the reaction layer between chlorides and elements of refractory lining. The products of reactions penetrate more deeply into A lining. K ions penetrate into the grains of the lining more intense than Na ions.

chloride melts; static crucible corrosion test; alumina-silica refractory bricks


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