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AGRICULTURAL TRACTOR ENGINE PERFORMANCE AND EMISSIONS USING BIODIESEL-ETHANOL BLENDS

ABSTRACT

To meet environmental standards and sustainability policies, diesel-biodiesel-ethanol blends have been investigated as partial replacements for diesel. This study aimed to evaluate the emissions and performance of a diesel engine using a blend of biodiesel and ethanol. Four blends of biodiesel (7, 10, 15, and 20%) and four blends of ethanol (0, 1, 3, and 5%) were used. The power remained stable with the addition of biodiesel but decreased with the addition of ethanol for all blends. The power was reduced from 76 to 74 kW when the ethanol content increased from 0 to 5%. The addition of 1% ethanol increased the maximum torque linearly from 372 to 378 kW. A slight increase in the specific consumption was observed with the use of biodiesel and ethanol in the blend. An increase in the ethanol fraction from 0 to 5% reduced nitrogen oxide emissions, especially at high loads. Ethanol caused a decrease of up to 42% in nitrogen oxide. At high loads, a reduction in carbon monoxide emissions was observed with an increase in the blends of ethanol and biodiesel. Blends of biodiesel and ethanol with concentrations of 20% biodiesel and 5% ethanol are alternatives to diesel in agricultural tractor engines.

biodiesel blend; ethanol blend; emission; performance; diesel engine

INTRODUCTION

Increasing industrialization has increased the demand for fossil fuels, causing reserves of these fuels to drain at an alarming rate worldwide (Atmanli et al., 2015Atmanli A, Ileri E, Yuksel B, Yilmaz N (2015) Extensive analyses of diesel–vegetable oil–n-butanol ternary blends in a diesel engine. Applied Energy 145: 155-162. https://doi.org/10.1016/j.apenergy.2015.01.071
https://doi.org/10.1016/j.apenergy.2015....
; Odibi et al., 2019Odibi C, Babaie M, Zare A, Nabi MN, Bodisco TA, Brown RJ (2019) Exergy analysis of a diesel engine with waste cooking biodiesel and triacetin. Energy Conversion and Management 198: 111912 https://doi.org/10.1016/j.enconman.2019.111912
https://doi.org/10.1016/j.enconman.2019....
; Yesilyurt et al., 2020Yesilyurt MK, Cesur C, Aslan V, Yilbasi Z (2020) The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potencial feedstock and is usage in compression ignition engine. Renewable and Sustainable Energy Reviews 119: 109574 https://doi.org/10.1016/j.rser.2019.109574
https://doi.org/10.1016/j.rser.2019.1095...
). In addition, fossil fuels cause air pollution and global warming. Therefore, studies have aimed to develop new technologies that effectively use resources (Atmanli et al., 2016Atmanli A, Ileri E, Yilmaz N (2016) Optimization of diesel–butanol–vegetable oil blend ratios based on engine operating parameters. Energy 96: 569-580. https://doi.org/10.1016/j.energy.2015.12.091
https://doi.org/10.1016/j.energy.2015.12...
; Aydın, 2020Aydın S (2020) Detailed evaluation of combustion, performance and emissions of ethyl proxitol and methyl proxitol-safflower biodiesel blends in a power generator diesel engine. Fuel 270: 117492. https://doi.org/10.1016/j.fuel.2020.117492
https://doi.org/10.1016/j.fuel.2020.1174...
; Uyumaz, 2020Uyumaz A (2020) Experimental evaluation of linseed oil biodiesel/diesel fuel blends on combustion, performance and emission characteristics in a DI diesel engine. Fuel 267:117150. https://doi.org/10.1016/j.fuel.2020.117150
https://doi.org/10.1016/j.fuel.2020.1171...
).

In this context, liquid biofuels produced from renewable biomass are attractive (Carneiro et al., 2017Carneiro MLN, Pradelle F, Braga SL, Gomes MSP, Martins ARF, Turkovics F, Pradelle RN (2017) Potential of biofuels from algae: Comparison with fossil fuels, ethanol and biodiesel in Europe and Brazil through life cycle assessment (LCA). Renewable and Sustainable Energy Reviews 73: 632-653. https://doi.org/10.1016/j.rser.2017.01.152
https://doi.org/10.1016/j.rser.2017.01.1...
). Of these, biodiesel is the best option. Biodiesel is an oxygenated, renewable, biodegradable, and ecologically friendly fuel (Yilmaz et al., 2018Yilmaz N, Atmanli A, Vigil FM (2018) Quaternary blends of diesel, biodiesel, higher alcohols and vegetable oil in a compression ignition engine. Fuel 212: 462-469. https://doi.org/10.1016/j.fuel.2017.10.050
https://doi.org/10.1016/j.fuel.2017.10.0...
; Gongora et al., 2022Gongora B, Souza SNM, Bassegio D, Santos RF, Siqueira JAC, Bariccatti RA, Sequinel R (2022) Comparison of emissions and engine performance of safflower and commercial biodiesels. Industrial Crops and Products 179: 114680. https://doi.org/10.1016/j.indcrop.2022.114680
https://doi.org/10.1016/j.indcrop.2022.1...
). It has properties similar to those of mineral diesel, with some advantages over diesel, such as a higher amount of cetane, the presence of oxygen that helps in combustion, and the reduction of greenhouse gas emissions (Guedes et al., 2018Guedes ADM, Braga SL, Pradelle F (2018) Performance and combustion characteristics of a compression ignition engine running on diesel-biodiesel-ethanol (DBE) blends–Part 2: Optimization of injection timing. Fuel 225:174-183. https://doi.org/10.1016/j.fuel.2018.02.120
https://doi.org/10.1016/j.fuel.2018.02.1...
).

Biodiesel is a promising alternative fuel for diesel engines; however, its high viscosity, low volatility, and poor cold flow properties at low temperatures affect its combustion quality, which limits its emissions. High viscosity and low volatility affect fuel atomization, whereas poor cold flow properties lead to the solidification of fatty acid compounds and the formation of crystals at low temperatures (Bhale et al., 2009Bhale PV, Deshpande NV, Thombre SB (2009) Improving the low temperature properties of biodiesel fuel. Renewable energy 34(3): 794-800. https://doi.org/10.1016/j.renene.2008.04.037
https://doi.org/10.1016/j.renene.2008.04...
; Wei et al., 2018Wei L, Cheung CS, Ning Z (2018) Effects of biodiesel-ethanol and biodiesel-butanol blends on the combustion, performance and emissions of a diesel engine. Energy 155: 957-970. https://doi.org/10.1016/j.energy.2018.05.049
https://doi.org/10.1016/j.energy.2018.05...
). However, fuel properties can be improved by blending biodiesel with ethanol. As a renewable alternative fuel with a high oxygen content, blending ethanol with biodiesel can decrease fuel density, viscosity, cold filter plugging point, and freezing (Jin et al., 2019Jin C, Zhang X, Geng Z, Pang X, Wang X, Ji J, Wang W, Liu H (2019) Effects of various co-solvents on the solubility between blends of soybean oil with either methanol or ethanol. Fuel 244: 461-471. https://doi.org/10.1016/j.fuel.2019.01.187
https://doi.org/10.1016/j.fuel.2019.01.1...
; Atmanli & Yilmaz, 2020Atmanli A, Yilmaz N (2020) An experimental assessment on semi-low temperature combustion using waste oil biodiesel/C3-C5 alcohol blends in a diesel engine. Fuel 260: 116357. https://doi.org/10.1016/j.fuel.2019.116357
https://doi.org/10.1016/j.fuel.2019.1163...
; Geng et al., 2021)Geng L, Bi L, Li Q, Chen H, Xie Y (2021) Experimental study on spray characteristics, combustion stability, and emission performance of a CRDI diesel engine operated with biodiesel–ethanol blends. Energy Reports 7: 904-915. https://doi.org/10.1016/j.egyr.2021.01.043
https://doi.org/10.1016/j.egyr.2021.01.0...
.

Researchers have investigated the effects of different proportions of diesel–biodiesel–ethanol ternary fuel blends on the performance and emission characteristics of diesel engines. Shahir et al. (2015)Shahir SA, Masjuki HH, Kalam MA, Imran A, Ashraful AM (2015) Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review. Renewable and Sustainable Energy Reviews 48: 62-78. https://doi.org/10.1016/j.rser.2015.03.049
https://doi.org/10.1016/j.rser.2015.03.0...
observed that the engine power and torque decreased with increasing ethanol proportion in a single-cylinder diesel engine. Tongroon et al. (2019)Tongroon M, Saisirirat P, Suebwong A, Aunchaisri J, Kananont M, Chollacoop N (2019) Combustion and emission characteristics investigation of diesel-ethanol-biodiesel blended fuels in a compression-ignition engine and benefit analysis. Fuel 255: 115728. https://doi.org/10.1016/j.fuel.2019.115728
https://doi.org/10.1016/j.fuel.2019.1157...
observed that NOx emissions increased with increasing ethanol proportions. Wei et al. (2018)Wei L, Cheung CS, Ning Z (2018) Effects of biodiesel-ethanol and biodiesel-butanol blends on the combustion, performance and emissions of a diesel engine. Energy 155: 957-970. https://doi.org/10.1016/j.energy.2018.05.049
https://doi.org/10.1016/j.energy.2018.05...
observed that biodiesel-ethanol blends were more effective in reducing NOx emissions. Yilmaz & Sanchez (2012)Yilmaz N, Sanchez TM (2012) Analysis of operating a diesel engine on biodiesel-ethanol and biodiesel-methanol blends. Energy 46(1): 126-129. https://doi.org/10.1016/j.energy.2011.11.062
https://doi.org/10.1016/j.energy.2011.11...
observed that biodiesel-ethanol reduced NOx emissions while enhancing CO emissions at engine loads below 70%. Although much research has been conducted on biodiesel, diesel, and biodiesel, divergent results have been found in the literature for low and high concentrations of ethanol. Therefore, there is no clear and uniform conclusion regarding the effects of the ethanol addition ratio on NOx emissions.

Based on the abovementioned literature reviews, several studies have been conducted on the blending properties of biodiesel and ethanol. However, few studies have evaluated these blends in agricultural tractor engines, and many have used single-cylinder engines. Therefore, the objective of this study was to evaluate the emissions and engine performance of an agricultural tractor fed with diesel-biodiesel-ethanol blends.

MATERIAL AND METHODS

The test was conducted at the Universidade Estadual do Oeste do Paraná (UNIOESTE) in Cascavel, Paraná, Brazil.

The tractor used was a Ford/New-Holland model 7630 with an auxiliary front-wheel drive (TDA; 4 × 2), manufactured in 1995 with 3196 h of use (Table 1). The tractor had a power socket with a single speed of 540 rpm, a splined shaft with six splines, and a diameter of 35 mm. The original tractor tank was disconnected from the injection system, and an external tank with a capacity of 20 L was used in the tests. In the engine, the tests used diesel type A S500 fuel, pure biodiesel, and anhydrous ethanol (99,6% purity). Biodiesel is produced via the methyl route and is composed of soybean oil (68%), bovine fat (25%), pork fat (5%), and poultry oil (2%).

TABLE 1
Tractor specifications.

A heat pump calorimeter model E2K with values provided in MJ kg–1 enabled the determination of the gross heating value of the fuels. This method has been described by Volpato et al. (2009)Volpato CES, Conde ADP, Barbosa JA, Salvador N (2009) Desempenho de motor diesel quatro tempos alimentado com biodiesel de óleo de soja (B 100). Ciência e Agrotecnologia 33:1125-1130. http://dx.doi.org/10.1590/S141370542009000400025
http://dx.doi.org/10.1590/S1413705420090...
. A pycnometer and four-decimal precision balance (Marte, model Ay220) were used to obtain the density at 20 ºC. These values were within the limit of 850–900 kg m–3, as required by the National Agency of Petroleum, Natural Gas, and Biofuels (ANP, 2008ANP - Agência Nacional do Petróleo, Gás Natural e Biocombustíveis (2008) Number 7 biodiesel standard. In: National Agency of Petroleum. Natural Gas and Biofuels, Brazil.).

The proposed diesel-biodiesel proportions (7, 10, 15, and 20%) were evaluated without ethanol (E0) and in the proportions of 1, 3, and 5% of anhydrous ethanol. It is suggested in the literature that up to 20% biodiesel (B20) is the most acceptable blend ratio in alternative fuel blends (Atmanli et al., 2016Atmanli A, Ileri E, Yilmaz N (2016) Optimization of diesel–butanol–vegetable oil blend ratios based on engine operating parameters. Energy 96: 569-580. https://doi.org/10.1016/j.energy.2015.12.091
https://doi.org/10.1016/j.energy.2015.12...
; Yilmaz et al., 2022Yilmaz N, Atmanli A, Hall MJ, Vigil FM (2022) Determination of the optimum blend ratio of diesel, waste oil derived biodiesel and 1-pentanol using the response surface method. Energies 15(14): 5144. https://doi.org/10.3390/en15145144
https://doi.org/10.3390/en15145144...
).

For the torque and power measurements, a mobile dynamometer from the Eggers brand, model PT - 170 SE (KL-Maschinenbau GmbH & Co.), was attached to the tractor power socket, whose principle of operation is a magnetic brake by eddy currents (currents of Foucault). For the control and configuration of the dynamometer, this study used the software Eggers PowerControl® v2.1, produced by the same company that built the dynamometer. The equipment was manufactured in Germany and presented data following the DIN standard (Deutsches Institut für Normung or German Institute for Standardization) number 70020.

For the PowerControl® software to make the corrections of power values considering the test conditions, a Thermo-hygro-barometer, brand GREISINGER, model GFTB-100, was used to measure atmospheric pressure, relative humidity, and room temperature. It was also necessary to acquire the real rotation values before each dynamometric test. According to Farias, there may be errors in the rotation values shown on the agricultural tractor displays. A digital infrared tachometer (Peaktech, Model 2790) was used.

Specific consumption was determined using the method described by Heywood (1988)Heywood JB (1988) Internal combustion engine fundamentals. New York, McGraw-Hill. 930p.. The thermal efficiency was determined according to Heywood (1988)Heywood JB (1988) Internal combustion engine fundamentals. New York, McGraw-Hill. 930p., based on the specific consumption and LCV.

Gas emission measurements were performed by applying four levels of manual loads through a dynamometer [25, 50, 75, and 100% of the maximum torque, corresponding to C1, C2, C3, and C4, respectively, and no charge (slow speed)]. NOx and CO emissions were determined using a combustion analyzer from Bacharach (model PCA3-285). At each point, the measurements were performed for three minutes.

The experiment was set up in a 4 × 4 factorial scheme with four blends of biodiesel (7, 10, 15 e, and 20%) and four blends of ethanol (0, 1, 3, and 5%). In the engine performance experiments, an analysis of variance (ANOVA), Tukey’s test with a 5% probability of error, and regression analysis were performed. In relation to the engine pollutant gas emissions, measurements were made only once at the end of the performance tests for each fuel evaluated.

RESULTS AND DISCUSSION

The heating value of the blends decreased with an increase in biodiesel and ethanol. A decrease of 2.56% in the lower heating value was observed when the ethanol content increased from 0 to 5%. The biodiesel blends showed a decrease (1.98%) when the biodiesel content increased from 7 to 20% (Fig. 1A).

FIGURE 1
Lower heating value and specific mass of biodiesel and ethanol blends.

The biodiesel blends increased the specific mass of the blend, whereas an increase in ethanol content had the opposite effect, decreasing the specific mass. The highest specific mass value was found for the mixture with the highest percentage of biodiesel and no ethanol (B20E0) at 850 kg m-3 and the lowest with less biodiesel and more ethanol (B7E5) at 844 kg m-3 (Fig. 1B).

An increase in ethanol concentration caused a linear reduction in power. On average, the increase in the ethanol content in the blend reduced the power from 76 kW to 74 kW when the ethanol content was increased from 0 to 5% (Fig. 2A and B). Higher values of maximum power rotation were observed for the B7E3 and B10E3 blends. The blend containing 20% biodiesel and 5% ethanol caused a linear reduction in the maximum power rotation (Fig. 2C and D).

FIGURE 2
Regression analysis for maximum power (A and B) and maximum power rotation (C and D) of biodiesel and ethanol blends.

A linear decrease in the maximum torque was observed with an increase in ethanol fraction (1, 3, and 5%). The torque values were lower when 5% ethanol was added to the blend, regardless of the biodiesel blend (Fig. 3A and B). Except for the blend containing 1% ethanol, the biodiesel fractions (7, 10, 15, and 20%) exhibited regular torque behavior in the blends with 0, 3, and 5% ethanol. The addition of 1% ethanol linearly increased the maximum torque from 372 kW to 378 kW with an increase in biodiesel from 7 to 20% (Fig. 3A and B).

FIGURE 3
Regression analysis for maximum torque (A and B) and maximum torque rotation (C and D) of biodiesel and ethanol blends.

The maximum torque rotation covered three levels: 1250, 1300, and 1350 rpm. In general, the maximum torque was measured at a rotation speed of 1300 rpm. The increase in ethanol from 1 to 5% in the blend with 7% biodiesel caused a more evident linear reduction in the maximum torque rotation (Fig. 3A and B).

The increase in biodiesel and ethanol resulted in an evident increase in specific consumption (Fig. 4A and B). Higher specific consumption was observed for the blend B10E3 with 239 g kW-1 h-1 (Fig. 4A). When the ethanol content was increased from 1 to 5%, a slight increase in thermal efficiency was observed from 38.67 to 39.58%. There was little variation in the biodiesel blends, with values between 38.09 to 38.98% (Fig. 4A and B).

FIGURE 4
Regression analysis for specific consummation (A and B) and thermal efficiency (C and D) of biodiesel and ethanol blends.

The increase in ethanol fraction from 0 to 5% decreased the NOx emissions, especially for loads C1, C2, and C3 (Fig. 5A, C, and E). In load C4 and without load, a smaller effect of ethanol was observed, particularly with the addition of 7% biodiesel (Fig. 5I). Evidently, biodiesel tends to increase NOx emissions. In the C2, C2, and C4 loads, there was a tendency for a slight increase in the NOx emissions with an increase in the biodiesel blends (Figs. 5D, F, and H). However, at a high load (C1), an increase in the biodiesel blends did not cause an increase in NOx (Fig. 5B). At the idling speed, the NOx variations due to the blends of biodiesel and ethanol were substantially smaller (Fig. 5I and J). A linear reduction in NOx emissions was verified with the reduction in loads from 952 ppm in load C1 to 305 ppm to 114 ppm in load C4 (Fig. 5).

FIGURE 5
NOx emissions in biodiesel and ethanol blends at different engine loads (A-J).

In load C1, a reduction in CO emissions was observed with an increase in the blends of ethanol and biodiesel. A reduction of 43.47% from 2678 to 1514 ppm was observed when the blend was changed from B0E0 to B10E5 (Fig. 6A and B). On average, for all loads, there was a slight reduction in CO because of the increase in biodiesel and ethanol. There was a linear reduction in CO emissions with a reduction in load, from 1969 ppm in the C1 load to 114 ppm in the C4 load (Fig. 6).

FIGURE 6
CO emissions in biodiesel and ethanol blends at different engine loads (A-J).

The power and torque decreased as the proportion of oxygenated compounds (biodiesel and ethanol/bioethanol) in the blend increased. This is possibly due to the low cetane number, calorific value, and higher ignition delay of the blends compared to those of diesel fuel (Xue et al., 2011Xue J, Grift TE, Hansen AC (2011) Effect of biodiesel on engine performances and emissions. Renewable and Sustainable Energy Reviews 15: 1098-1116. https://doi.org/10.1016/j.rser.2010.11.016
https://doi.org/10.1016/j.rser.2010.11.0...
; Shahir et al., 2015Shahir SA, Masjuki HH, Kalam MA, Imran A, Ashraful AM (2015) Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review. Renewable and Sustainable Energy Reviews 48: 62-78. https://doi.org/10.1016/j.rser.2015.03.049
https://doi.org/10.1016/j.rser.2015.03.0...
). Cheenkachorn & Fungtammasan (2009)Cheenkachorn K, Fungtammasan B (2009) Biodiesel as an additive for diesohol. International Journal of Green Energy 6(1): 57-72. https://doi.org/10.1080/15435070802701819
https://doi.org/10.1080/1543507080270181...
observed an 8.7% reduction in power output using biodiesel and ethanol blends compared with diesel. Therefore, using these blends without additives reduces engine power and torque output (Shahir et al., 2015)Shahir SA, Masjuki HH, Kalam MA, Imran A, Ashraful AM (2015) Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review. Renewable and Sustainable Energy Reviews 48: 62-78. https://doi.org/10.1016/j.rser.2015.03.049
https://doi.org/10.1016/j.rser.2015.03.0...
.

In general, the results indicated that increasing the proportions of ethanol and biodiesel in the fuel blend increased the specific consumption. This was expected owing to the reduction in the energy content of the fuel (Klajn et al., 2020Klajn FF, Gurgacz F, Lenz AM, Iacono GEP, de Souza SNM, Ferruzzi Y (2020) Comparison of the emissions and performance of ethanol-added diesel–biodiesel blends in a compression ignition engine with those of pure diesel. Environmental technology 41(4): 511-520. https://doi.org/10.1080/09593330.2018.1504122
https://doi.org/10.1080/09593330.2018.15...
). This behavior is attributed to the heating value per unit mass of ethanol, which is noticeably lower than that of diesel. Therefore, the amount of fuel introduced into the engine cylinder to achieve the desired fuel-energy input must be greater for ethanol. These results agree with those reported previously (Shahir et al., 2015Shahir SA, Masjuki HH, Kalam MA, Imran A, Ashraful AM (2015) Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review. Renewable and Sustainable Energy Reviews 48: 62-78. https://doi.org/10.1016/j.rser.2015.03.049
https://doi.org/10.1016/j.rser.2015.03.0...
; Thiyagarajan et al., 2020Thiyagarajan S, Sonthalia A, Geo VE, Prakash T, Karthickeyan V, Ashok B, Dhinesh B (2020) Effect of manifold injection of methanol/n-pentanol in safflower biodiesel fuelled CI engine. Fuel 261:116378. https://doi.org/10.1016/j.fuel.2019.116378
https://doi.org/10.1016/j.fuel.2019.1163...
; Yesilyurt et al., 2020Yesilyurt MK, Cesur C, Aslan V, Yilbasi Z (2020) The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potencial feedstock and is usage in compression ignition engine. Renewable and Sustainable Energy Reviews 119: 109574 https://doi.org/10.1016/j.rser.2019.109574
https://doi.org/10.1016/j.rser.2019.1095...
). Furthermore, high-specific-mass biodiesels generate less power when higher loads are required. High-density values indicate a higher viscosity, which can lead to greater flow difficulties and lower fuel injection (Kwanchareon et al., 2007Kwanchareon P, Luengnaruemitchai A, Jai-In S (2007) Solubility of a diesel–biodiesel–ethanol blend, its fuel properties, and its emission characteristics from diesel engine. Fuel 86: 1053-1061. https://doi.org/10.1016/j.fuel.2006.09.034
https://doi.org/10.1016/j.fuel.2006.09.0...
).

The increase in specific consumption can also be explained by the lower heat values of biodiesel and ethanol compared to those of diesel. To compensate for the lower heat values of biodiesel, ethanol, and methanol, additional fuel must be injected to obtain the same power output. Ethanol has a lower stoichiometric air/fuel ratio than biodiesel and diesel fuels; therefore, blending alcohols into biodiesel leads to leaner combustion (Zhu et al., 2010Zhu L, Cheung CS, Zhang WG, Huang Z (2010) Emissions characteristics of a diesel engine operating on biodiesel and biodiesel blended with ethanol and methanol. Science of the Total Environment 408(4): 914-921. https://doi.org/10.1016/j.scitotenv.2009.10.078
https://doi.org/10.1016/j.scitotenv.2009...
).

Several authors have studied binary diesel-biodiesel blends in unmodified engines and reported that NOx emissions increased with the use of esters, which is one of the major problems regarding the use of this biofuel in diesel engines (Masera & Hossain 2023Masera K, Hossain AK (2023) Advancement of biodiesel fuel quality and NOx emission control techniques. Renewable and Sustainable Energy Reviews 178:113235. https://doi.org/10.1016/j.rser.2023.113235
https://doi.org/10.1016/j.rser.2023.1132...
). Randazzo & Sodré (2011)Randazzo ML, Sodré JR (2011) Exhaust emissions from a diesel powered vehicle fuelled by soybean biodiesel blends (B3–B20) with ethanol as an additive (B20E2–B20E5). Fuel 90(1): 98-103. https://doi.org/10.1016/j.fuel.2010.09.010
https://doi.org/10.1016/j.fuel.2010.09.0...
observed a similar behavior, where NOx emissions increased with the use of biodiesel; however, this increase was reduced with the addition of ethanol to the blends, as observed in this study.

The decrease in NOx emissions with high-load biodiesel may be due to the lower cylinder temperature, which in turn may be due to the lower heating value of the fuel (Abedin et al., 2014Abedin MJ, Masjuki HH, Kalam MA, Sanjid A, Rahman SA, Fattah IR (2014) Performance, emissions, and heat losses of palm and jatropha biodiesel blends in a diesel engine. Industrial Crops and Products 59:96-104. https://doi.org/10.1016/j.indcrop.2014.05.001
https://doi.org/10.1016/j.indcrop.2014.0...
). The presence of a large number of oxygen molecules in biodiesel results in complete combustion of the fuel. This led to lower emissions of hydrocarbons (HC) and CO emissions. The temperature of the cylinder is an important factor in the formation of NOx.

A reduction in CO emissions was observed with an increase in ethanol and biodiesel blends. CO emissions are directly linked to the air/fuel ratio because the richer the blend, the higher the percentage of CO produced. Because diesel engines operate on poor blends (more air and less fuel), a high amount of CO in the exhaust indicates excess fuel or a lack of oxygen in the blend. CO emissions are normally below the legal limit values, which is not a reason for special attention; therefore, an analysis of the CO level for poor blends (low loads) is useless. Kwanchareon et al. (2007)Kwanchareon P, Luengnaruemitchai A, Jai-In S (2007) Solubility of a diesel–biodiesel–ethanol blend, its fuel properties, and its emission characteristics from diesel engine. Fuel 86: 1053-1061. https://doi.org/10.1016/j.fuel.2006.09.034
https://doi.org/10.1016/j.fuel.2006.09.0...
also evaluated ternary diesel-biodiesel-ethanol blends and claimed that the addition of oxygenated fuels to diesel resulted in a small effect on low and medium loads but significantly reduced CO emissions at high and full loads, as observed in this study. They pointed out that the impact of this blend on CO emissions varied according to the operating conditions of the engine and considered the results obtained inconclusively.

CONCLUSIONS

The power remained stable with the addition of biodiesel but decreased with the addition of ethanol for all blends. Higher values of maximum power rotation according to the interaction were observed for the blends B7E3 and B10E3. The increase in ethanol in the blend reduced the power from 76 kW to 74 kW when the ethanol content increased from 0 to 5%. A slight increase in the specific consumption was observed with the use of biodiesel and ethanol in the blend. An increase in the ethanol fraction from 0 to 5% reduced NOx emissions, especially at high loads. Ethanol caused a decrease of up to 42% in NOx. At a high load (C1), an increase in the biodiesel blends did not cause an increase in NOx. At full load (C1), a reduction in CO emissions was observed with an increase in the blends of ethanol and biodiesel. Therefore, ternary diesel-biodiesel-ethanol blends reduced the emission of gases such as NOx but reduced the power and torque of the agricultural tractor engine. Therefore, further investigations must be conducted using optimization methods and additives to make the adoption of ethanol in agricultural tractors commercially viable.

REFERENCES

  • Abedin MJ, Masjuki HH, Kalam MA, Sanjid A, Rahman SA, Fattah IR (2014) Performance, emissions, and heat losses of palm and jatropha biodiesel blends in a diesel engine. Industrial Crops and Products 59:96-104. https://doi.org/10.1016/j.indcrop.2014.05.001
    » https://doi.org/10.1016/j.indcrop.2014.05.001
  • ANP - Agência Nacional do Petróleo, Gás Natural e Biocombustíveis (2008) Number 7 biodiesel standard. In: National Agency of Petroleum. Natural Gas and Biofuels, Brazil.
  • Atmanli A, Ileri E, Yilmaz N (2016) Optimization of diesel–butanol–vegetable oil blend ratios based on engine operating parameters. Energy 96: 569-580. https://doi.org/10.1016/j.energy.2015.12.091
    » https://doi.org/10.1016/j.energy.2015.12.091
  • Atmanli A, Ileri E, Yuksel B, Yilmaz N (2015) Extensive analyses of diesel–vegetable oil–n-butanol ternary blends in a diesel engine. Applied Energy 145: 155-162. https://doi.org/10.1016/j.apenergy.2015.01.071
    » https://doi.org/10.1016/j.apenergy.2015.01.071
  • Atmanli A, Yilmaz N (2020) An experimental assessment on semi-low temperature combustion using waste oil biodiesel/C3-C5 alcohol blends in a diesel engine. Fuel 260: 116357. https://doi.org/10.1016/j.fuel.2019.116357
    » https://doi.org/10.1016/j.fuel.2019.116357
  • Aydın S (2020) Detailed evaluation of combustion, performance and emissions of ethyl proxitol and methyl proxitol-safflower biodiesel blends in a power generator diesel engine. Fuel 270: 117492. https://doi.org/10.1016/j.fuel.2020.117492
    » https://doi.org/10.1016/j.fuel.2020.117492
  • Bhale PV, Deshpande NV, Thombre SB (2009) Improving the low temperature properties of biodiesel fuel. Renewable energy 34(3): 794-800. https://doi.org/10.1016/j.renene.2008.04.037
    » https://doi.org/10.1016/j.renene.2008.04.037
  • Carneiro MLN, Pradelle F, Braga SL, Gomes MSP, Martins ARF, Turkovics F, Pradelle RN (2017) Potential of biofuels from algae: Comparison with fossil fuels, ethanol and biodiesel in Europe and Brazil through life cycle assessment (LCA). Renewable and Sustainable Energy Reviews 73: 632-653. https://doi.org/10.1016/j.rser.2017.01.152
    » https://doi.org/10.1016/j.rser.2017.01.152
  • Cheenkachorn K, Fungtammasan B (2009) Biodiesel as an additive for diesohol. International Journal of Green Energy 6(1): 57-72. https://doi.org/10.1080/15435070802701819
    » https://doi.org/10.1080/15435070802701819
  • Geng L, Bi L, Li Q, Chen H, Xie Y (2021) Experimental study on spray characteristics, combustion stability, and emission performance of a CRDI diesel engine operated with biodiesel–ethanol blends. Energy Reports 7: 904-915. https://doi.org/10.1016/j.egyr.2021.01.043
    » https://doi.org/10.1016/j.egyr.2021.01.043
  • Guedes ADM, Braga SL, Pradelle F (2018) Performance and combustion characteristics of a compression ignition engine running on diesel-biodiesel-ethanol (DBE) blends–Part 2: Optimization of injection timing. Fuel 225:174-183. https://doi.org/10.1016/j.fuel.2018.02.120
    » https://doi.org/10.1016/j.fuel.2018.02.120
  • Heywood JB (1988) Internal combustion engine fundamentals. New York, McGraw-Hill. 930p.
  • Jin C, Zhang X, Geng Z, Pang X, Wang X, Ji J, Wang W, Liu H (2019) Effects of various co-solvents on the solubility between blends of soybean oil with either methanol or ethanol. Fuel 244: 461-471. https://doi.org/10.1016/j.fuel.2019.01.187
    » https://doi.org/10.1016/j.fuel.2019.01.187
  • Klajn FF, Gurgacz F, Lenz AM, Iacono GEP, de Souza SNM, Ferruzzi Y (2020) Comparison of the emissions and performance of ethanol-added diesel–biodiesel blends in a compression ignition engine with those of pure diesel. Environmental technology 41(4): 511-520. https://doi.org/10.1080/09593330.2018.1504122
    » https://doi.org/10.1080/09593330.2018.1504122
  • Kwanchareon P, Luengnaruemitchai A, Jai-In S (2007) Solubility of a diesel–biodiesel–ethanol blend, its fuel properties, and its emission characteristics from diesel engine. Fuel 86: 1053-1061. https://doi.org/10.1016/j.fuel.2006.09.034
    » https://doi.org/10.1016/j.fuel.2006.09.034
  • Masera K, Hossain AK (2023) Advancement of biodiesel fuel quality and NOx emission control techniques. Renewable and Sustainable Energy Reviews 178:113235. https://doi.org/10.1016/j.rser.2023.113235
    » https://doi.org/10.1016/j.rser.2023.113235
  • Odibi C, Babaie M, Zare A, Nabi MN, Bodisco TA, Brown RJ (2019) Exergy analysis of a diesel engine with waste cooking biodiesel and triacetin. Energy Conversion and Management 198: 111912 https://doi.org/10.1016/j.enconman.2019.111912
    » https://doi.org/10.1016/j.enconman.2019.111912
  • Randazzo ML, Sodré JR (2011) Exhaust emissions from a diesel powered vehicle fuelled by soybean biodiesel blends (B3–B20) with ethanol as an additive (B20E2–B20E5). Fuel 90(1): 98-103. https://doi.org/10.1016/j.fuel.2010.09.010
    » https://doi.org/10.1016/j.fuel.2010.09.010
  • Shahir SA, Masjuki HH, Kalam MA, Imran A, Ashraful AM (2015) Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review. Renewable and Sustainable Energy Reviews 48: 62-78. https://doi.org/10.1016/j.rser.2015.03.049
    » https://doi.org/10.1016/j.rser.2015.03.049
  • Gongora B, Souza SNM, Bassegio D, Santos RF, Siqueira JAC, Bariccatti RA, Sequinel R (2022) Comparison of emissions and engine performance of safflower and commercial biodiesels. Industrial Crops and Products 179: 114680. https://doi.org/10.1016/j.indcrop.2022.114680
    » https://doi.org/10.1016/j.indcrop.2022.114680
  • Uyumaz A (2020) Experimental evaluation of linseed oil biodiesel/diesel fuel blends on combustion, performance and emission characteristics in a DI diesel engine. Fuel 267:117150. https://doi.org/10.1016/j.fuel.2020.117150
    » https://doi.org/10.1016/j.fuel.2020.117150
  • Thiyagarajan S, Sonthalia A, Geo VE, Prakash T, Karthickeyan V, Ashok B, Dhinesh B (2020) Effect of manifold injection of methanol/n-pentanol in safflower biodiesel fuelled CI engine. Fuel 261:116378. https://doi.org/10.1016/j.fuel.2019.116378
    » https://doi.org/10.1016/j.fuel.2019.116378
  • Tongroon M, Saisirirat P, Suebwong A, Aunchaisri J, Kananont M, Chollacoop N (2019) Combustion and emission characteristics investigation of diesel-ethanol-biodiesel blended fuels in a compression-ignition engine and benefit analysis. Fuel 255: 115728. https://doi.org/10.1016/j.fuel.2019.115728
    » https://doi.org/10.1016/j.fuel.2019.115728
  • Wei L, Cheung CS, Ning Z (2018) Effects of biodiesel-ethanol and biodiesel-butanol blends on the combustion, performance and emissions of a diesel engine. Energy 155: 957-970. https://doi.org/10.1016/j.energy.2018.05.049
    » https://doi.org/10.1016/j.energy.2018.05.049
  • Xue J, Grift TE, Hansen AC (2011) Effect of biodiesel on engine performances and emissions. Renewable and Sustainable Energy Reviews 15: 1098-1116. https://doi.org/10.1016/j.rser.2010.11.016
    » https://doi.org/10.1016/j.rser.2010.11.016
  • Volpato CES, Conde ADP, Barbosa JA, Salvador N (2009) Desempenho de motor diesel quatro tempos alimentado com biodiesel de óleo de soja (B 100). Ciência e Agrotecnologia 33:1125-1130. http://dx.doi.org/10.1590/S141370542009000400025
    » http://dx.doi.org/10.1590/S141370542009000400025
  • Yesilyurt MK, Cesur C, Aslan V, Yilbasi Z (2020) The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potencial feedstock and is usage in compression ignition engine. Renewable and Sustainable Energy Reviews 119: 109574 https://doi.org/10.1016/j.rser.2019.109574
    » https://doi.org/10.1016/j.rser.2019.109574
  • Yilmaz N, Atmanli A, Vigil FM (2018) Quaternary blends of diesel, biodiesel, higher alcohols and vegetable oil in a compression ignition engine. Fuel 212: 462-469. https://doi.org/10.1016/j.fuel.2017.10.050
    » https://doi.org/10.1016/j.fuel.2017.10.050
  • Yilmaz N, Atmanli A, Hall MJ, Vigil FM (2022) Determination of the optimum blend ratio of diesel, waste oil derived biodiesel and 1-pentanol using the response surface method. Energies 15(14): 5144. https://doi.org/10.3390/en15145144
    » https://doi.org/10.3390/en15145144
  • Yilmaz N, Sanchez TM (2012) Analysis of operating a diesel engine on biodiesel-ethanol and biodiesel-methanol blends. Energy 46(1): 126-129. https://doi.org/10.1016/j.energy.2011.11.062
    » https://doi.org/10.1016/j.energy.2011.11.062
  • Zhu L, Cheung CS, Zhang WG, Huang Z (2010) Emissions characteristics of a diesel engine operating on biodiesel and biodiesel blended with ethanol and methanol. Science of the Total Environment 408(4): 914-921. https://doi.org/10.1016/j.scitotenv.2009.10.078
    » https://doi.org/10.1016/j.scitotenv.2009.10.078

Edited by

Area Editor: João Paulo Arantes Rodrigues da Cunha

Publication Dates

  • Publication in this collection
    08 Apr 2024
  • Date of issue
    2024

History

  • Received
    16 June 2023
  • Accepted
    29 Jan 2024
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