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Optic- electronic effects of the solvents in the electronic polarizabilities of the Ni2+ ion in the [Ni(C3H4N2)6](CF3SO3)2 complex

Electronic polarizabilities were obtained for the salt of nickel trifluorometanesulfonate and for the complex with imidazole, in methanol and acetonitrile solutions. Starting from the electronic spectra, registered in a concentration of 10-3 mol L-1 and using the program SIMP2FOS to calculate the force of the experimental oscillator and POLAZ-F to calculate the electronic polarizabilities, it was possible to notice the different influence of the solvents in the deformation of the electronic cloud of the nickel (II).

Nickel compounds; trifluorometanesulfonate; imidazole; oscillator strength; electronic polarizability


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