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Communication • J. Braz. Chem. Soc. 19 (5) • 2008 • https://doi.org/10.1590/S0103-50532008000500002   copy

A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction

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A homoenolate generated by tellurium/lithium exchange reaction was employed in a straightforward enantioselective synthesis of (+)-endo-brevicomin in 70% yield and 84.4% e.e.

tellurium/lithium exchange; homoenolate; epoxide opening

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