Analysis of the Carbothermic Reduction of Iron Ore-Coke Composite Mixtures by Microwave Heating

Abstract

In recent decades, microwave energy has been successfully experimented for mining and metallurgy processes and is considered a promising new method for ironmaking. In this context, in the present work, self-reducing mixtures composed of fines of iron ore and coke were prepared, intending to evaluate the degree of reduction of iron ore using microwave energy, applying different contents of coke, levels of power, and reaction times. For this, the degree of reduction was assessed as a function of these variables. Additionally, the reduction kinetics was investigated using chemical and diffusional models, and the microstructure of the samples was evaluated using scanning electron microscopy (SEM). The highest degree of reduction obtained after the experiments was greater than 60% and a statistical investigation showed that the reaction time is the factor with the greatest influence on these results, followed by microwave power and coke content. The investigation of the reaction kinetics showed that the process is chemically controlled, depending on the gasification steps governed by the Boudouard reaction. The images obtained by SEM led to the conclusion that the temperature inside the sample reached 1200°C. Pig iron was found both in the form of whiskers and in the form of metallic droplets.

Keywords
: Microwave energy; Iron ore; Self-reduction