Effect of Thermal Aging Conditions on the Corrosion Properties and Hardness of a Duplex Stainless Steel

TECHFIVE Gestão de Resíduos, Rod. Geraldo Scavone, 2300, Cond. California Center, CEP 12305-620, Jacareí, SP, Brazil Department of Chemical Technology and Materials, Federal University of Bahia, Av. Aristides Novis, 2, Federação, CEP 40210-630, Salvador, BA, Brazil Department of Materials Engineering – DEMa, Federal University of São Carlos, Rod. Washington Luis, Km 235, CEP 13565-905, São Carlos, SP, Brazil CEFET of Santa Catarina, Unidade Joinville, Coord. Mecânica, Rua Pavão, Costa e Silva, 1337, CEP 89220-200, Joinville, SC, Brazil Department of Physics, Federal University of Paraná, Rua Francisco H. dos Santos, Centro Politécnico, Bloco 11, sala 37, CEP 81531-990, Curitiba, PR, Brazil


Introduction
Duplex stainless steel has excellent properties in several environments due to its high pitting corrosion and stress-corrosion cracking resistance, along with high mechanical strength, good weldability, and low thermal expansion coefficient 1 .The corrosion resistance of these alloys is the same or higher than that of their austenitic analogues and they have higher strength, enabling gauge, weight and cost reductions 2 .The superior properties of duplex stainless steels, which are mainly due to equivalent amounts of austenite (γ) and δ-ferrite, justify their wide use in the chemical, petrochemical, nuclear, fertilizer and food industries 3 .
Duplex stainless steel has an unstable microstructure in the range of 300 to 1050 °C and, when subjected to these temperatures, it may undergo phase precipitation of several compounds such as chromium carbides, nitrides, sigma phase and other intermetallic phases.Service conditions at high temperature, and improper welding or fabrication processes may cause these phases to precipitate, decreasing its corrosion and mechanical properties, especially its toughness.The effects of phase precipitation at high temperatures on the mechanical and corrosion properties of duplex stainless steels have been studied extensively [4][5][6][7][8][9][10][11] .However, the literature offers little information about the effect of long-term thermal aging at low temperatures (300-600 °C) on the corrosion resistance of duplex stainless steel.
The temperature range of 300 to 600 °C is characterized by the spinodal decomposition of ferrite into Cr-poor α and Cr-rich α' domains, which can cause embrittlement of duplex stainless steel alloy.Investigations of 2205 duplex stainless steel by high-resolution transmission electron microscopy 12 revealed that isotropic spinodal decomposition occurred during aging at 475 °C; the original δ-ferrite decomposed into a nanometer-scale modulated structure with a complex interconnected network containing an iron-rich BCC phase (α) and a chromium-enriched BCC phase (α').It has been suggested 12 that the locking of dislocations in the modulated structure leads to severe embrittlement.
Other precipitation processes besides α' phase also occur between 300 and 600 °C in duplex stainless steel, such as G phase precipitation in ferrite 13 and carbide 14 , and γ 2 phase precipitation at the grain boundaries 15 .Among these processes, the main one is Ni, Si, Mo-rich G phase precipitation 12,16 .These particles are very small (1 nm, occasionally up to 50 nm) and are usually present in very high concentrations.They precipitate within the ferrite grain preferentially on dislocations and at α-γ interfaces.It has been reported 17 that G phase precipitation occurs from Cr-rich α' phase in the second stage of aging, which corresponds to aging of more than 3000 hours at 400 °C.During this stage, the precipitated chromium-enriched phase aggregates and coarsens, and G phase precipitation also occurs.TEM observations 18 suggest that the kinetics of spinodal decomposition and G phase precipitation is influenced by the ferrite-to-austenite ratio.Thus, duplex stainless steel tempered at 475 °C and aged for 1000 hours with high ferrite content (α/γ = 1.5) is characterized by a more advanced spinodal decomposition and G phase precipitation than steel with low ferrite content (α/γ = 1).
The effect of phase precipitation on the corrosion resistance of duplex stainless steel at lower temperatures ranging from 300 to 600 °C has been studied 19,20 at 475 °C, at which temperature alloy embrittlement is maximum.It has been reported that localized corrosion attack occurs only after a long aging period.Decreased corrosion resistance is attributed to spinodal decomposition and the resulting Cr-rich α' precipitation, which depletes Cr in the alloy's surrounding matrix.This susceptibility to corrosion increases as the ferrite content increases in response to spinodal decomposition and G phase precipitation, affecting the ferrite phase more than the austenite phase 18 .
However, the information reported in the literature does not suffice to explain the effect of aging on duplex stainless steel corrosion resistance at low temperatures, particularly from 300 to 400 °C.The aim of this work is to evaluate the effect of long-term aging (3000, 5000 and 7000 hours) at 300 and 400 °C on the corrosion resistance and hardness of duplex stainless steel containing 22.5 wt.(%) Cr.

Experimental Procedure
The samples were taken from a hot rolled duplex stainless steel, whose composition is described in Table 1.
The samples were solubilized at 1050 °C for 1 hour, followed by quenching in cold water at around 5 °C.The resulting microstructure presented a α/γ ratio of about 50:50%.Thermal aging treatments were conducted for 3000, 5000 and 7000 hours at temperatures of 300 and 400 °C.
Corrosion properties were determined based on the weight loss test, anodic potentiodynamic polarization curves, and corrosion current density (i corr ) at room temperature (25 °C).The mass loss measurements were carried out in an aerated 1.7 M FeCl 3 solution, following the ASTM G 38 standard.Each test was performed with the same sample immersed during different times and the weight loss corrosion test was performed in triplicate for each condition.The error bars correspond to the lowest and highest mass loss obtained in these three tests.
The i corr was determined in aerated 0.1 M H 2 SO 4 solution by the linear polarization method, using the Stern-Geary equation 21 .
The anodic potentiodynamic polarization curves were obtained by stepping the potential using a scan rate of 10 mV/s from -250 mV (SCE) to +250 mV (SCE) in an aerated 0.1 M H 2 SO 4 solution at room temperature.The work electrodes were cylindrical samples (0.79 cm 2 of exposed area), which were insulated with epoxy resin, polished with SiC #600 grit sandpaper, rinsed in distilled water and immediately immersed in the test solution before each measurement.A platinum auxiliary was used and the reference electrode was a saturated calomel electrode (SCE).The electrochemical measurements were taken with a SOLARTRON 287 electrochemical system.Each polarization curve represents a coincident experiment in triplicate, according to the usual procedure.
The hardness of austenite and ferrite phases was determined by instrumented indentation, using a Nanoindenter XP (MTS System Corporation) with a Berkovich indenter (three-sided pyramid), under applied loads of 3 to 400 mN corresponding to eight complete loading-unloading cycles.Three indentations were made on each sample.The residual indenter prints of each phase were separated using optical microscopy (Olympus BX51), and the results represent the average of the 3 indentations.Specimen surfaces were prepared for nanoindentation by mechanical polishing with SiC #1200 sandpaper followed by polishing with 0.3 mm alumina.
Structural analyses were performed using a transmission electron microscope (Philips model CM120).Thin foils for transmission electron microscope observations were prepared by preliminary mechanical thinning to a thickness of 70 mm, followed by dimpling up to 20 mm at the center, then ion beam polishing for about 20 hours.
The surface of the solubilized sample and the samples aged at 300 °C for 5000 and 7000 hours were analyzed using Mg-Kα radiation X-ray photoelectron spectroscopy (Kratos XSAM HS).The energy of the C 1 s peak due to adventitious hydrocarbons was used as binding energy reference (284.8 eV).The X-ray photoelectron spectroscopy analysis was performed after polarizing the sample in aerated 0.1 M H 2 SO 4 solution for 15 minutes at a potential in the passive region.The corrosion rate was directly proportional to i corr ; therefore, the results in Figure 1 indicate that the corrosion resistance of solubilized alloy changed as a function of the thermal aging treatment.As can be seen, the corrosion rate increased slightly in alloys aged for 3000 hours.However, this rate was significant after 5000 hours of aging, thereafter declining up to 7000 hours of aging, indicating that, in the conditions analyzed in this study, the highest corrosion rate occurred after 5000 hours of aging.These results also demonstrate that aging at 400 °C resulted in a higher corrosion rate than at 300 °C, except for the alloy aged for 3000 hours in the 0.1 M H 2 SO 4 solution.

Corrosion resistance measurements
Mass loss was also measured to evaluate the effect of aging time on the corrosion resistance of alloys.These measurements were obtained in a 1.7 M FeCl 3 solution to adapt them to the experimental time.The results shown in Figure 2 confirm that the corrosion rate was highest at an aging time of around 5000 hours.
To understand the effect of aging treatment on the alloy, its passivity behavior was determined based on experimental anodic potentiodynamic polarization curves.These curves were similar to each other, indicating a behavior typical of duplex stainless steels.Figure 3 shows the curve for the sample solubilized at 1050 °C for 1 hours.Two current peaks, which indicate a region of secondary passivation, are visible in these curves.The peak current density of active-passive transition, i a/p , occurred at a lower potential of around 100 mV vs. SCE.The passive region occurred between 100 mV and 900 mV vs. SCE, while transpassivation occurred up to 1000 mV vs. SCE.The peak current of secondary passivation occurred at a higher potential of around 1250 mV vs. SCE.The region of secondary passivation extended up to the potential of 1500 mV vs. SCE, at which point oxygen evolution occurred.The intensity of the peak current density of the active-passive transition and secondary passivation was attributed to the alloy's facility to form a passive film and a secondary passive film, respectively.Thus, the lower intensity of this peak current density led to higher passivation.The partial anodic potentiodynamic polarization curves in Figure 4 show the presence of the peak current density of the active-passive transition, i a/p, at 300 and 400 °C.
Figure 5 illustrates the peak current densities, i a/p , shown in Figure 4 as a function of aging time.This behavior is affected by the aging temperature.The behavior of the current density of the active-passive transition peak indicates that the aging time of the samples treated at 400 °C increased up to 5000 hours, preventing the occurrence of passivation.However, 7000 hours of aging decreased the peak current density.The effect of aging time on the peak current density was not clear in the sample aged at 300 °C.

Hardness tests
The effect of aging on the corrosion resistance of the alloy under study can probably be ascribed to microstructural changes.To understand these changes, the effect of aging conditions on the hardness of the samples was investigated.
Figure 6a and 6b shows the hardness of ferrite and austenite phases, and the global hardness of the alloy as a function of the aging heat-treatment conditions.The global hardness represents the average hardness of ferrite and austenite phases.

Figure 6a and 6b indicates that the global hardness increased
with advancing aging time.The hardness also increased along with aging temperature.This effect of thermal aging on the alloy's hardness occurs in response to phase changes that take place during heat treatments, which are related to the effect of aging on corrosion resistance.
Figure 6a and 6b also shows that global hardness was changed mainly by the ferrite phase.The effect of aging time on the hardness of austenite was less significant than on that of the ferrite phase.

Structural analysis by transmission electron microscopy (TEM)
The purpose of the TEM analysis was to correlate the effect of aging treatments with the morphology of the duplex stainless steel alloys.Figures 7 show TEM images of the microstructures of samples aged at 400 °C for 3000 hours.
Figure 7 shows the presence of a discontinuous phase indicating the possible presence of precipitates.Note that the precipitates occur next to dislocations; hence, it is possible that this precipitate corresponds to the G phase, which occurs in ferrite phase associated with the dislocation 16 .However, this discontinuous phase must be analyzed, which will be done in future work.The XPS analysis indicated that the aging time exerts an inverse effect on the oxidized iron and oxidized chromium content in passive film.Aging for 5000 hours decreased the oxidized chromium in passive film, but its content increased with 7000 hours of aging.

Discussion
Our findings revealed that the aging treatment significantly affects the corrosion resistance of the duplex stainless steel alloy.This effect was probably caused by phase transitions occurring during aging, which is coherent with the hardness, TEM and XPS measurements.
According to the literature, precipitation of G 17 and α' 22 phases can occur in duplex stainless steels aged at temperatures of 300 and 400 °C.It is possible that aging duplex stainless steel alloy for long periods causes the ferrite to decompose into Cr (α') and Fe (α) rich phases.This phase transition is due to the compositional changes that favor G phase precipitation 23 .Experimental TEM results of the sample aged at 300 °C indicate the likely presence of G phase.These phases are rich in elements that can affect the alloy's corrosion resistance and mechanical properties.The α' phase is rich in Cr, while the G phase presents higher Cr, Ni, Mo and Si content than the matrix 23 .This behavior is coherent with the XPS results shown in Figure 8.These results indicate that 3000 hours of aging, which probably results in the formation of precipitates, decreased the oxidized chromium in passive film, indicating the presence of less Cr in the matrix.This reduction of Cr in passive film is probably related to the higher Cr content in the precipitate, resulting in Cr depletion in the proximities of precipitates and, in consequence, the lower amount of this element in the matrix.
As previously reported 20 , the aging of a 29.4 Cr-8.7Ni-0.41Siduplex stainless at 400 °C caused depletion of silicon in the ferrite phase, mainly due to the precipitation of silicon-rich phases such as G phase.The increased volumetric fraction of G phase with progressive aging has already been reported in duplex stainless steel 23 .These results show that the volumetric fraction of G phase in samples treated at 350 °C increased from 40 to 60% at aging times of 1000 and 3000 hours, respectively.
Therefore, the decrease in corrosion resistance of both alloys with aging time, which was observed in a 0.1 M H 2 SO 4 solution after 5000 hours, can be ascribed to phase precipitation occurring during aging.The precipitation of these phases resulted in regions depleted of elements as such the Cr and affected the corrosion resistance of the alloy in the proximities of the phase/matrix interface, leading to a galvanic corrosion effect between the alloy-depleted region and the alloy matrix.This hypothesis is coherent with the results of XPS measurements of the Fe-22.5Cralloy shown in Figure 8, which indicate that the Cr oxidized content diminished in the passive film at 5000 hours of aging, indicating a decline in the content of this element.
The higher corrosion resistance of the alloy in a 0.1 M H 2 SO 4 solution after 7000 hours of aging than that of alloy aged for 3000 and 5000 hours can be attributed to phase coarsening and/or the "healing" effect of longer aging times.It is possible that 7000 hours of aging enhances the size of phase precipitates due to coarsening.Thus, the phase/matrix interface area per volume, and hence, the area of the alloy-depleted regions decreased, minimizing the corrosion rate.It is also possible that in addition to coarsened phases, long aging periods such as 7000 hours promote the "healing" effect that results in chromium equalization.This effect, which has been observed in stainless steel containing chromium carbide and subjected to thermal treatment 24 , corresponds to the disappearance of chromium depleted zones around precipitated phases due to the diffusion of chromium in the matrix.
The minimized chromium-depleted zones around precipitated phases after 7000 hours of aging when compared with the sample aged for 5000 hours are also consistent with the XPS measurements depicted in Figure 8, which shows the presence of a larger amount of chromium in the passive film of the sample aged for 7000 hours.
The effect of aging time on the current density of the active-passive transition peak, i a/p , determined from the polarization curves (Figure 4) in a H 2 SO 4 solution, may also be related to the phase changes that occurred during aging.The growth of this peak in samples heat-treated at 400 °C and aged for up to 5000 hours can be attributed to the increased area of matrix/phase interfaces, and therefore, of the area of alloy-depleted regions at these interfaces, which hindered the passivation process.The increase of i a/p in response to 7000 hours of aging may be attributed to the diminished area of alloy-depleted regions resulting from chromium coalescence and/or equalization.However, in the sample aged at 400 °C, the effect of aging time on the i a/p in a H 2 SO 4 solution could not be unequivocally ascribed to the effect of aging time on the i corr .
The correlation between the decrease in corrosion resistance after 3000 and 5000 hours of aging and the precipitated phase is consistent with the hardness of aged alloys shown in Figure 6.The precipitated phases act as barriers against dislocation motion, resulting in increased hardness of the alloy.The possible increases in the volumetric fraction of precipitates in response to 3000 and 5000 hours of aging augment the alloy's hardness.The possible coarsening of precipitates caused by 7000 hours of aging decreases the surface area of precipitates, and hence, the area per unit volume of the barriers to dislocation motion.This effect should reduce the alloy's hardness.
However, the results show that 7000 hours of aging reduced the alloy's corrosion resistance but not its hardness.The increase in hardness after 7000 hours of aging indicates that this treatment increased the area per unit volume of the barriers to dislocation motion, probably due the high nucleation rate.Therefore, it is possible that the increase in corrosion resistance resulting from 7000 hours of aging was related mainly to the diffusion of chromium from the matrix to the chromium-depleted area, which probably did not affect the material's hardness.
The fact of that effect of aging time on the hardness of austenite was less significant than on that of the ferrite phase indicates that precipitation occurred mainly in ferrite phase.
The lower corrosion resistance of alloy aged at 400 °C than of that aged at 300 °C, except for the alloy aged for 3000 hours in a 0.1 M H 2 SO 4 solution was likely related to the area of the matrix/precipitate interface.It is possible that aging at 400 °C increases the phase nucleation rate, thus increasing the area of alloy-depleted regions at the precipitate/matrix interface.This effect was confirmed by the hardness measurements, which indicated that the alloy's hardness was greater when aged at 400 °C than at 300 °C.

Conclusions
Long-term aging (3000, 5000 and 7000 hours) at 300 and 400 °C significantly affected the corrosion resistance of 22.5 wt.(%) Cr content duplex stainless steel alloy.This effect was caused by phase transitions after aging.The alloy's corrosion resistance in the 0.1 M H 2 SO 4 and 1.7 M FeCl 3 solutions decreased continually up to 5000 hours of aging.However, longer aging periods of 7000 hours increased the corrosion resistance when compared to samples aged for 3000 and 5000 hours.
The XPS analysis showed that 5000 hours of aging reduced the chromium oxide content in the passive film, but that this content increased after aging for 7000 hours.G phase precipitation was identified by transmission electron microscopy.The alloy aged for

Figure 1
Figure1illustrates the effect of aging time and temperature on the i corr of the duplex stainless steel alloy samples in a 0.1 M H 2 SO 4 solution.The corrosion rate was directly proportional to i corr ; therefore, the results in Figure1indicate that the corrosion resistance of solubilized alloy changed as a function of the thermal aging treatment.As can be seen, the corrosion rate increased slightly in alloys aged for 3000 hours.However, this rate was significant after 5000 hours of aging, thereafter declining up to 7000 hours of aging, indicating that, in the conditions analyzed in this study, the highest corrosion rate occurred after 5000 hours of aging.These results also demonstrate that aging at 400 °C resulted in a higher corrosion rate than at 300 °C, except for the alloy aged for 3000 hours in the 0.1 M H 2 SO 4 solution.Mass loss was also measured to evaluate the effect of aging time on the corrosion resistance of alloys.These measurements were obtained in a 1.7 M FeCl 3 solution to adapt them to the experimental time.The results shown in Figure2confirm that the corrosion rate was highest at an aging time of around 5000 hours.To understand the effect of aging treatment on the alloy, its passivity behavior was determined based on experimental anodic potentiodynamic polarization curves.These curves were similar to each other, indicating a behavior typical of duplex stainless steels.Figure3shows the curve for the sample solubilized at 1050 °C for 1 hours.Two current peaks, which indicate a region of secondary passivation, are visible in these curves.The peak current density of active-passive transition, i a/p , occurred at a lower potential of around 100 mV vs. SCE.The passive region occurred between 100 mV and 900 mV vs. SCE, while transpassivation occurred up to 1000 mV vs. SCE.The peak current of secondary passivation occurred at a

Figure 4 .
Figure 4. Partial anodic potentiodynamic curves, with the presence of a current density peak of active-passive transition, i a/p , in the duplex stainless steel aged under different conditions of time and temperature.Solution: H 2 SO 4 0.1 M, v = 10 mV/s.a) Aging at 300 °C and b) aging at 400 °C.

Figure 5 .
Figure 5. Critical current density at the peak as a function of aging time and temperature in duplex stainless steel alloy in 0.1 M H 2 SO 4 solution.

Figure 6 .
Figure 6.Effect of aging time on the overall hardness and nanohardness of ferrite and austenite phases: a) Aging at 300 °C and b) aging at 400 °C.Error: ±0.10.

Figure 7 .
Figure 7. TEM analysis of duplex stainless steel alloy aged for 3000 hours at 300 °C, bright field.

Figure 8
Figure 8 shows the effect of aging on the composition of the passive film of the alloy aged at 300 °C.This figure shows the mass percent of iron and chromium oxide in relation to passive film mass.The mass percent of oxide iron was calculated from the Equation 1: oxidized oxidized oxidized Fe Cr Fe +

Figure 8 .
Figure 8. Composition of the oxide layer analyzed by XPS of duplex stainless steel alloy aged at 300 °C.
22.6 5.38 0.024 1.57 0.35 0.013 0.008 2.58 0.13Figure 1.Effect of aging time and temperature on the corrosion current density, i corr , of 22.5 wt.(%) Cr duplex stainless steel alloy in a 0.1 M H 2 SO 4 solution at room temperature.