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Chemical and mineralogical properties of charcoals from different environments

The increased emissions of greenhouse gases have motivated researches about capture and sequestration of C. The use of biochar in soils is an efficient way to maintain the C in the biochar stabilized and benefit the crop yield. The objective of this research was to characterize charcoals collected at different places.It was determined: total and organic C contents; elementary analysis by calcination; characterization of the samples by X-ray diffractometry, absorption spectroscopy and scanning electron microscopy. The samples in contact with soil showedhigher TOC contents, while total C contents were higher in the charcoals without contact with soil. The pH-H2O values of charcoal samples in contact with soil ranged between 4,42-7,24, average 6,8, while pH-KCl values ranged between 2,91-6,88, average 4,68. All samples presented low nutrient contents. In the samples of charcoal in contact with soil,kaolinite, quartz, graphite and gibbsitewere detected.The main functional groups identified were O-H, C=O, C=C and C-O. In the SEM of thesamples 1 and 2,wood structures were less evident and there was influence of the soil components and organisms in these charcoals.

Biochar; Carbon sequestration; Reactivity


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