1 |
3.2 |
Phenylalanine |
|
166, 120 |
C9H12NO2
|
|
166.086 |
166.0863 |
-1.3614 |
260 |
* |
* |
* |
1 |
63-91-2 |
Std |
2 |
3.5 |
Caffeic acid-glucoside |
341, 179, 161, 113 |
|
C15H18O9
|
|
|
Not detected in HR MS |
304sh |
* |
|
|
2 |
|
Parveen et al., 2013Parveen, I., Wilson, I.T., Donnison, S., Cookson, A.R., Threadgill, H.B., 2013. Potential sources of high value chemicals from leaves, stems and flowers of Miscanthus sinensis “Goliath” and Miscanthus sacchariflorus. Phytochemistry 92, 160-167.
|
3 |
4.3 |
Pinoresinol |
357, 241, 151, |
|
C20H21O6
|
|
357.13474 |
357.1344 |
1.059 |
275 |
|
|
* |
2 |
487-36-5 |
Ye et al., 2005Ye, M., Yan, Y., Guo, D.A., 2005. Characterization of phenolic compounds in the Chinese herbal drug Tu-Si-Zi by liquid chromatography coupled to electro spray ionization mass spectrometry. Rapid Commun. Mass Spectrom. 19, 1469-1484.; Eklund et al., 2008Eklund, P.C., Backman, M.J., Kronberg, L.A., Smeds, A.I., Sjöholm, R.E., 2008. Identification of lignans by liquid chromatography-electrospray ionization ion-trap mass spectrometry. J. Mass. Spectrom. 43, 97-107.
|
4 |
4.4 |
Dihydroxybenzoyl-hexoside |
315, 153
|
317, 155 |
C13H15O9
|
|
315.0718 |
315.0722 |
-1.1026 |
281 |
* |
* |
|
2 |
|
Parveen et al., 2013Parveen, I., Wilson, I.T., Donnison, S., Cookson, A.R., Threadgill, H.B., 2013. Potential sources of high value chemicals from leaves, stems and flowers of Miscanthus sinensis “Goliath” and Miscanthus sacchariflorus. Phytochemistry 92, 160-167.
|
5 |
4.9 |
Shikimate-hexoside |
319, 157
|
|
C13H19O9
|
|
319.10342 |
319.1035 |
-0.111 |
275, 300 |
|
* |
|
3 |
|
Parveen et al., 2013Parveen, I., Wilson, I.T., Donnison, S., Cookson, A.R., Threadgill, H.B., 2013. Potential sources of high value chemicals from leaves, stems and flowers of Miscanthus sinensis “Goliath” and Miscanthus sacchariflorus. Phytochemistry 92, 160-167.
|
6 |
5.3 |
Tryptophan |
203, 159, 116 |
205, 188 |
C11H13O2N2
|
|
205.097 |
205.0972 |
-0.9744 |
285 |
* |
* |
* |
1 |
73-22-3 |
Std |
7 |
7.1 |
Dihydroxybenzoyl-pentoside |
285, 153
|
287, 155 |
C12H13O8
|
|
285.0616 |
285.0616 |
-0.0215 |
286 |
* |
* |
* |
3 |
|
Parveen et al., 2013Parveen, I., Wilson, I.T., Donnison, S., Cookson, A.R., Threadgill, H.B., 2013. Potential sources of high value chemicals from leaves, stems and flowers of Miscanthus sinensis “Goliath” and Miscanthus sacchariflorus. Phytochemistry 92, 160-167.
|
8 |
7.3 |
Dihydroxybenzoyl-glucosylpentoside |
447, 267, 153 |
|
C18H23O13
|
|
447.11441 |
447.1144 |
-0.0078 |
284 |
* |
|
* |
3 |
|
Parveen et al., 2013Parveen, I., Wilson, I.T., Donnison, S., Cookson, A.R., Threadgill, H.B., 2013. Potential sources of high value chemicals from leaves, stems and flowers of Miscanthus sinensis “Goliath” and Miscanthus sacchariflorus. Phytochemistry 92, 160-167.
|
9 |
8.8 |
Luteolin 6,8-di-C-glucoside-7-O-glucoside |
771, 651, 609, 489, 399, 369 |
|
C33H39O21
|
|
771.1978 |
771.1963 |
-2.0038 |
269, 335 |
|
* |
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
10 |
10.5 |
Isovitexin 8-C-arabonoside-7-O-glucoside |
725, 635, 605, 563, 473, 443, 353 |
727, 709, 643, 559 |
C32H37O19
|
|
725.1924 |
725.1907 |
-2.3184 |
270, 332 |
* |
* |
* |
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
11 |
10.5 |
Quercetin 3'-O-glucoside-7-O-glucosyldeoxyhexoside |
771, 609, 301 |
|
C33H39O21
|
|
771.1978 |
771.1978 |
-0.0252 |
272, 345 |
* |
|
* |
3 |
|
Kachlicki et al., 2008Kachlicki, P., Einhorn, J., Muth, D., Kerhoas, L., Stobiecki, M., 2008. Evaluation of glycosylation and malonylation patterns in flavonoid glycosides during LC/MS/MS metabolite profiling. J. Mass Spectrom. 43, 572-586.
|
12 |
10.6 |
Isovitexin 2"-O-glucoside-7-O-glucoside (apigenin 6-C-glucoside 2"-O-glucoside-7-O-glucoside) |
755, 593, 455, 413, 293 |
757, 595, 577, 529, 445, 379, 337, 293 |
C33H39O20
|
|
755.2029 |
755.1998 |
-4.1733 |
269, 332 |
|
* |
|
3 |
|
Simigriotis et al., 2013Simigriotis, M.J., Schmeda-Hirschmann, G., Borquez, J., Kennelly, E.J., 2013. The Passiflora tripartita (Banana Passion) fruit: a source of bioactive flavonoid C-glycosides isolated by HSCCC and characterized by HPLC–DAD–ESI/MS/MS. Molecules 18, 1672-1692.
|
13 |
11.2 |
Luteolin 6-C-hydroxybenzoylpentoside-di-O-glucoside |
861, 699, 647, 327 |
|
C39H41O22
|
|
861.21027 |
861.2095 |
0.899 |
269, 340 |
|
|
* |
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.; Ye et al., 2005Ye, M., Yan, Y., Guo, D.A., 2005. Characterization of phenolic compounds in the Chinese herbal drug Tu-Si-Zi by liquid chromatography coupled to electro spray ionization mass spectrometry. Rapid Commun. Mass Spectrom. 19, 1469-1484.
|
14 |
11.4 |
Luteolin 6,8-di-C-glucoside |
609, 489, 369, 399 |
611, 593, 473, 408, 353, 299 |
C27H29O16
|
|
609.1456 |
609.1477 |
-3.521 |
270, 344 |
* |
* |
|
2 |
29428-58-8 |
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.; Waridel et al., 2001Waridel, P., Wolfender, J.L., Ndjoko, K., Hobby, K.R., Major, H.J., Hostettmann, K., 2001. Evaluation of quadrupole time-of-flight tandem mass spectrometry and ion-trap multiple-stage mass spectrometry for the differentiation of C-glycosidic flavonoid isomers. J. Chromatogr. A 926, 29-41.
|
15 |
11.9 |
Apigenin 6,8-di-C-glucoside |
593, 473, 383, 353 |
595, 577, 511, 457 |
C27H29O16
|
|
593.1501 |
593.1497 |
-0.7389 |
269, 333 |
* |
* |
|
2 |
23666-13-9 |
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.; Waridel et al., 2001Waridel, P., Wolfender, J.L., Ndjoko, K., Hobby, K.R., Major, H.J., Hostettmann, K., 2001. Evaluation of quadrupole time-of-flight tandem mass spectrometry and ion-trap multiple-stage mass spectrometry for the differentiation of C-glycosidic flavonoid isomers. J. Chromatogr. A 926, 29-41.
|
16 |
12.3 |
Apigenin 6, 8-di-C-glucoside-7-O-glucoside |
755, 593, 473, 383, 353 |
|
C33H39O20
|
|
755.2029 |
755.1998 |
-4.1733 |
268, 334 |
* |
* |
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
17 |
13.5 |
Luteolin 6-C-pentoside-8-C-glucoside |
579, 489, 459, 399, 367 |
|
C26H27O15
|
|
579.135 |
579.1376 |
-2.751 |
270, 241 |
* |
|
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
18 |
14.2 |
Vitexin 6"-O-glucoside (apigenin 8-C-glucoside 6"-O-glucoside) |
593, 473, 431, 311 |
595, 577, 529, 433, 337, 267, 283 |
C27H29O15
|
|
593.1501 |
593.1477 |
-4.0371 |
271, 335 |
* |
|
|
3 |
639850-16-1 |
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Wojakowska et al., 2013Wojakowska, A., Piasecka, A., García-López, P.M., Zamora-Natera, F., Krajewski, P., Marczak, Ł., Kachlicki, P., Stobiecki, M., 2013. Structural analysis and profiling of phenolic secondary metabolites of Mexican lupine species using LC-MS techniques. Phytochemistry 92, 71-86.
|
19 |
14.6 |
Isoorientin 7-O-glucoside (luteolin 6-C-glucoside 7-O-glucoside) |
609, 489, 447, 327 |
|
C27H29O16
|
|
609.145 |
609.1423 |
-4.3948 |
272, 345 |
* |
* |
|
2 |
35450-86-3 |
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Simigriotis et al., 2013Simigriotis, M.J., Schmeda-Hirschmann, G., Borquez, J., Kennelly, E.J., 2013. The Passiflora tripartita (Banana Passion) fruit: a source of bioactive flavonoid C-glycosides isolated by HSCCC and characterized by HPLC–DAD–ESI/MS/MS. Molecules 18, 1672-1692.
|
20 |
15.2 |
Isoorientin (luteolin 6-C-glucoside) |
447, 327 |
449, 431, 383, 353, 299 |
C21H19O11
|
|
447.0922 |
447.0907 |
-3.2633 |
272, 345 |
|
* |
|
1 |
4261-42-1 |
std |
21 |
15.4 |
Orientin 7-O-deoxyhexoside (luteolin 8-C-glucoside 7-O-deoxyhexoside) |
593, 473, 429, 377, 299 |
595, 577, 529, 449, 367 |
C27H29O15
|
|
593.1989 |
593.1479 |
-3.9288 |
268, 344 |
* |
|
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
22 |
16.1 |
Apigenin 6,8-di-C-pentoside |
533, 473, 443, 413, 383, 353 |
535, 499, 481, 379, 283 |
C25H27O13
|
|
535.1458 |
535.1446 |
2.2345 |
269, 332 |
* |
* |
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
23 |
16.6 |
Isoscoparin 2"-O-glucoside (chrysoeriol 6-C-glucoside 2"-O-glucoside |
623, 443, 323, 309 |
625, 463, 445, 391, 313 |
C28H31O16
|
|
623.1612 |
623.1634 |
-3.5303 |
243, 271, 349 |
|
* |
|
3 |
97605-25-9 |
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
24 |
17.4 |
Vitexin 6"-O-pentoside (apigenin 8-C-glucoside 6"-O-pentoside) |
563, 473, 443, 413, 341, 311
|
565, 499, 427, 313 |
C26H27O10
|
|
563.1395 |
563.1414 |
3.246 |
269, 332 |
* |
|
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
25 |
17.6 |
Orientin 6"-O-glucoside (luteolin 8-C-glucoside 6"-O-glucoside) |
609, 489, 429, 357, 327 |
611, 593, 545, 473, 425, 395, 341, 299 |
C27H29O16
|
|
609.1456 |
609.1477 |
-3.521 |
272, 345 |
|
* |
|
3 |
|
Piasecka et al., 2015Piasecka, A., Sawikowska, A., Krajewski, P., Kachlicki, P., 2015. Combined mass spectrometric and chromatographic methods for in-depth analysis of phenolic secondary metabolites in barley leaves. J. Mass Spectrom. 50, 513-532.; Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
26 |
18.1 |
Isovitexin 7-O-glucoside (apigenin 6-C-glucoside 7-O-glucoside) |
593, 431, 311 |
|
C27H29O15
|
|
593.1501 |
593.1477 |
-4.0371 |
269, 335 |
|
* |
|
3 |
20310-89-8 |
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
27 |
18.2 |
Quercetin glucosyldeoxyhexoside |
609, 301
|
|
C27H29O16
|
|
609.145 |
609.1424 |
-4.2946 |
273, 350 |
* |
|
|
3 |
|
Cuyckens et al., 2001Cuyckens, F., Rozenberg, R., de Hoffmann, E., Claeys, M., 2001. Structure characterization of flavonoid O-diglycosides by positive and negative nano-electrospray ionization ion trap mass spectrometry. J. Mass Spectrom. 6, 1203-1210.
|
28 |
18.6 |
Luteolin 7-O-glucosyldeoxyhexoside |
593, 447, 413, 285, 257 |
|
C27H29O15
|
|
593.1501 |
593.1477 |
-4.0317 |
268, 345 |
|
* |
|
3 |
|
Cuyckens et al., 2001Cuyckens, F., Rozenberg, R., de Hoffmann, E., Claeys, M., 2001. Structure characterization of flavonoid O-diglycosides by positive and negative nano-electrospray ionization ion trap mass spectrometry. J. Mass Spectrom. 6, 1203-1210.
|
29 |
18.8 |
Apigenin 6-C-pentoside-8-C-glucoside |
563, 473, 443, 353, 383 |
|
C26H27O14
|
|
563.1395 |
563.1411 |
3.779 |
269, 333 |
* |
* |
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
30 |
19 |
Isovitexin 6"-O-deoxyhexoside (apigenin 6-C-glucoside 6"-O-deoxyhexoside) |
577, 413, 311 |
579, 433, 415, 367, 337, 283 |
C27H29O14
|
|
577.15625 |
577.1563 |
-0.05 |
270, 335 |
|
* |
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
31 |
19.2 |
Apigenin 6-C-deoxyhexoside-8-C-pentoside |
547, 487, 457, 427, 367, 337, 309, 281 |
549, 531, 483, 465, 375 |
C26 H27O13
|
|
547.1457 |
547.1449 |
-1.488 |
268, 334 |
* |
|
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
32 |
19.6 |
Isoscoparin 2"-O-deoxyhexoside (chrysoeriol 6-C-glucoside 2"-O-deoxyhexoside) |
607, 443, 323, 307 |
609, 463, 397, 313 |
C28H31O15
|
|
607.1663 |
607.1697 |
-2.751 |
246, 272, 349 |
* |
|
* |
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
33 |
20.8 |
Apigenin C-glucose C-deoxyhexose |
577, 503, 473,443,383, 353 |
565, 547, 499, 403, 295 |
C27H29O14
|
|
577.1552 |
577.1533 |
-3.3312 |
268, 335 |
* |
* |
|
3 |
|
Piasecka et al., 2015Piasecka, A., Sawikowska, A., Krajewski, P., Kachlicki, P., 2015. Combined mass spectrometric and chromatographic methods for in-depth analysis of phenolic secondary metabolites in barley leaves. J. Mass Spectrom. 50, 513-532.; Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.
|
34 |
21 |
Isovitexin 2"-O-dideoxyhexoside (apigenin 6-C-glucoside 2"-O-dideoxyhexoside) |
561, 413, 251 |
|
C27H29O13
|
|
561.16187 |
561.1614 |
0.902 |
329, 333 |
|
|
* |
3 |
|
Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.
|
35 |
21.1 |
Vitexin 2"-O-glucoside (apigenin 8-C-glucoside 2"-O-glucoside) |
593, 473, 413, 357, 293
|
595, 577, 457, 283 |
C27H29O15
|
|
593.1501 |
593.1477 |
-4.0371 |
270, 334 |
* |
* |
|
3 |
61360-94-9 |
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
36 |
21.8 |
Luteolin 6-C-[6"-O-deoxyhexoside]- dideoxyhexoside |
561, 327 |
|
C27H29O13
|
|
561.29169 |
561.2916 |
0.071 |
271, 344 |
|
* |
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.
|
37 |
21.8 |
Orientin 6"-O-deoxyhexose (luteolin 8-C-glucoside 6"-O-deoxyhexose) |
593, 473, 327, 357 |
|
C27H29O16
|
|
593.1501 |
593.1497 |
-0.7389 |
269, 346 |
|
|
* |
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
38 |
22 |
Chrysin 6-C-glucoside-8-C-pentoside |
547, 457, 427, 337, 309 |
549, 513, 413, 309 |
C26H27O13
|
|
547.276 |
547.2766 |
1.115 |
264, 330 |
* |
|
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
39 |
23.2 |
Apigenin 6-C-[2"-O-deoxyhexoside] - pentoside |
547, 457, 383, 293
|
549, 265, 221 |
C26H27O13
|
|
547.276 |
547.2767 |
1.334 |
269, 335 |
* |
|
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.
|
40 |
23.4 |
Luteolin 7-O-[6"-acetyl]-deoxyhexoside |
473, 327, 285
|
|
C23H21O11
|
|
473.10907 |
473.1089 |
0.286 |
269, 346 |
|
|
* |
3 |
|
Simigriotis et al., 2013Simigriotis, M.J., Schmeda-Hirschmann, G., Borquez, J., Kennelly, E.J., 2013. The Passiflora tripartita (Banana Passion) fruit: a source of bioactive flavonoid C-glycosides isolated by HSCCC and characterized by HPLC–DAD–ESI/MS/MS. Molecules 18, 1672-1692.
|
41 |
24.4 |
Chrysin 6-C-glucoside |
415, 295, 267 |
|
C21H19O9
|
|
415.1035 |
415.1037 |
0.5863 |
271, 346 |
* |
|
|
3 |
28368-57-2 |
Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
42 |
24.5 |
Isoorientin 2"-O-glucoside (luteolin 6-C-glucoside 2"-O-glucoside) |
609, 489, 429, 357, 327, 309 |
611, 449, 431, 353, 299 |
C27H29O16
|
|
609.145 |
609.1424 |
-4.2946 |
271, 344 |
|
* |
|
3 |
55196-48-0 |
Piasecka et al., 2015Piasecka, A., Sawikowska, A., Krajewski, P., Kachlicki, P., 2015. Combined mass spectrometric and chromatographic methods for in-depth analysis of phenolic secondary metabolites in barley leaves. J. Mass Spectrom. 50, 513-532.; Waridel et al., 2001Waridel, P., Wolfender, J.L., Ndjoko, K., Hobby, K.R., Major, H.J., Hostettmann, K., 2001. Evaluation of quadrupole time-of-flight tandem mass spectrometry and ion-trap multiple-stage mass spectrometry for the differentiation of C-glycosidic flavonoid isomers. J. Chromatogr. A 926, 29-41.
|
43 |
24.9 |
Chrysin 6-C-[2"-O-glucoside]-glucoside |
|
579, 417, 351 |
C27H29O14
|
|
577.1563 |
577.1564 |
0.1618 |
266, 331 |
* |
|
|
3 |
|
Wojakowska et al., 2013Wojakowska, A., Piasecka, A., García-López, P.M., Zamora-Natera, F., Krajewski, P., Marczak, Ł., Kachlicki, P., Stobiecki, M., 2013. Structural analysis and profiling of phenolic secondary metabolites of Mexican lupine species using LC-MS techniques. Phytochemistry 92, 71-86.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
44 |
25.5 |
Chrysin 6-C-glucoside-7-O-glucosyldeoxyhexoside |
|
725, 561, 417, 351 |
C33H39O18
|
|
723.2142 |
723.214 |
-0.2739 |
272, 329 |
* |
|
|
3 |
|
Wojakowska et al., 2013Wojakowska, A., Piasecka, A., García-López, P.M., Zamora-Natera, F., Krajewski, P., Marczak, Ł., Kachlicki, P., Stobiecki, M., 2013. Structural analysis and profiling of phenolic secondary metabolites of Mexican lupine species using LC-MS techniques. Phytochemistry 92, 71-86.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
45 |
25.7 |
Blumenol C-glucoside |
|
373, 211, 193 |
C19 H15O8
|
|
371.0772 |
371.0772 |
-0.0018 |
253 |
* |
* |
|
3 |
135820-80-3 |
Peipp et al., 1997Peipp, H., Maier, W., Schmidt, J., Wray, V., Strack, D., 1997. Arbuscular mycorrhizal fungus-induced changes in the accumulation of secondary compounds in barley roots. Phytochemistry 44, 581-587.; Marino et al., 2008Marino, S., Gala, F., Zollo, F., Vitalini, S., Fico, G., Visioli, F., Iorizzi, M., 2008. Identification of minor secondary metabolites from the latex of Croton lechleri (Muell-Arg) and evaluation of their antioxidant activity. Molecules 13, 1219-1229.
|
46 |
25.8 |
Vitexin (apigenin 8-C-glucoside |
|
433, 367, 337, 309 |
C21H19O10
|
|
431.0978 |
431.0988 |
0.001 |
269, 333 |
|
* |
|
1 |
3681-93-4 |
std |
47 |
26 |
Isovitexin (apigenin 6-C-glucoside) |
431, 311 |
433, 415, 367, 283 |
C21H19O10
|
|
431.09833 |
431.0984 |
-0.093 |
269, 334 |
|
* |
|
1 |
38953-85-4 |
std |
48 |
26.2 |
Isovitexin 7-O-deoxyhexoside (apigenin 6-C-glucoside 7-O-deoxyhexoside) |
577, 413, 311
|
|
C27H29O14
|
|
577.1563 |
577.1544 |
3,2222 |
269, 335 |
|
* |
|
3 |
|
Cuyckens et al., 2001Cuyckens, F., Rozenberg, R., de Hoffmann, E., Claeys, M., 2001. Structure characterization of flavonoid O-diglycosides by positive and negative nano-electrospray ionization ion trap mass spectrometry. J. Mass Spectrom. 6, 1203-1210.
|
49 |
26.3 |
Pinoresinol O-glucosyldeoxyhexoside-O-glucoside |
827, 519, 357, 151 |
|
C38 H51 O20
|
|
827.29913 |
827.2979 |
1.466 |
278 |
|
* |
|
3 |
|
Eklund et al., 2008Eklund, P.C., Backman, M.J., Kronberg, L.A., Smeds, A.I., Sjöholm, R.E., 2008. Identification of lignans by liquid chromatography-electrospray ionization ion-trap mass spectrometry. J. Mass. Spectrom. 43, 97-107.
|
50 |
26.5 |
Isovitexin 2"-O-deoxyhexoside (apigenin 6-C-glucoside 2"-O-deoxyhexoside) |
577, 413, 293 |
|
C27H29O14
|
|
577.1563 |
577.1544 |
3.2222 |
269, 335 |
* |
* |
* |
3 |
|
Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
51 |
26.5 |
Chrysin di-O-glucoside |
|
579, 417, 255 |
C27H29O14
|
|
577.15686 |
577.1563 |
1.007 |
265, 330 |
|
* |
|
3 |
|
Piasecka et al., 2015Piasecka, A., Sawikowska, A., Krajewski, P., Kachlicki, P., 2015. Combined mass spectrometric and chromatographic methods for in-depth analysis of phenolic secondary metabolites in barley leaves. J. Mass Spectrom. 50, 513-532.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
52 |
26.6 |
Apigenin 7-O-glucosyldideoxyhexoside |
561, 269 |
|
C27H29O13
|
|
561.16144 |
561.1614 |
0.137 |
269, 335 |
|
* |
|
3 |
|
Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.; Wojakowska et al., 2013Wojakowska, A., Piasecka, A., García-López, P.M., Zamora-Natera, F., Krajewski, P., Marczak, Ł., Kachlicki, P., Stobiecki, M., 2013. Structural analysis and profiling of phenolic secondary metabolites of Mexican lupine species using LC-MS techniques. Phytochemistry 92, 71-86.
|
53 |
26.8 |
Apigenin 7-O-glucosyldeoxyhexoside |
577, 269 |
|
C27H29O14
|
|
577.1563 |
577.1563 |
0.779 |
268, 335 |
|
* |
|
3 |
|
Kachlicki et al., 2008Kachlicki, P., Einhorn, J., Muth, D., Kerhoas, L., Stobiecki, M., 2008. Evaluation of glycosylation and malonylation patterns in flavonoid glycosides during LC/MS/MS metabolite profiling. J. Mass Spectrom. 43, 572-586.
|
54 |
26.8 |
Apigenin 6-C-[6"-acetyl-2"-O-deoxyhexoside]-glucoside |
619, 559, 455, 293 |
|
C29H31O15
|
|
619.1668 |
619.1658 |
-1.7311 |
275, 339 |
* |
|
|
3 |
|
Simigriotis et al., 2013Simigriotis, M.J., Schmeda-Hirschmann, G., Borquez, J., Kennelly, E.J., 2013. The Passiflora tripartita (Banana Passion) fruit: a source of bioactive flavonoid C-glycosides isolated by HSCCC and characterized by HPLC–DAD–ESI/MS/MS. Molecules 18, 1672-1692.
|
55 |
26.9 |
Quercetin 7-O-glucoside |
|
465, 303
|
C21H21O12
|
|
465.10345 |
465.1038 |
-0.858 |
245, 271, 351 |
|
* |
|
1 |
491-50-9 |
std |
56 |
27 |
Scoparin 2"-O-glucoside (chrysoeriol 8-C-glucoside 2"-O-glucoside) |
623, 503, 443, 323, 298 |
|
C28H31O16
|
|
623.1612 |
623.1636 |
3.85 |
242, 269, 348 |
|
* |
|
3 |
124902-15-4 |
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Wojakowska et al., 2013Wojakowska, A., Piasecka, A., García-López, P.M., Zamora-Natera, F., Krajewski, P., Marczak, Ł., Kachlicki, P., Stobiecki, M., 2013. Structural analysis and profiling of phenolic secondary metabolites of Mexican lupine species using LC-MS techniques. Phytochemistry 92, 71-86.
|
57 |
27 |
Apigenin 7-O-glucosylpentoside |
563, 269
|
|
C26H27O10
|
|
563.1395 |
563.1414 |
3.246 |
269, 335 |
|
* |
|
3 |
|
Cuyckens et al., 2001Cuyckens, F., Rozenberg, R., de Hoffmann, E., Claeys, M., 2001. Structure characterization of flavonoid O-diglycosides by positive and negative nano-electrospray ionization ion trap mass spectrometry. J. Mass Spectrom. 6, 1203-1210.
|
58 |
27.2 |
Feruloylquinic acid diglucoside |
691, 659, 335, 317, 273
|
693, 675, 643, 504, 359, 337 |
C29H39O19
|
|
691.2091 |
691.2079 |
-1.753 |
325sh |
* |
* |
|
2 |
|
Sakalem et al., 2012Sakalem, M.E., Negri, G., Tabach, R., 2012. Chemical composition of hydroethanolic extracts from five species of the Passiflora genus. Rev. Bras. Farmacogn. 22, 1219-1232.
|
59 |
27.4 |
Chrysin 6-C-[6", 2"-di-O-deoxyhexoside]-glucoside |
707, 453, 277
|
709, 563, 417, 321 |
C33H39O17
|
|
707.2193 |
707.2193 |
0.039 |
275, 332 |
* |
|
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
60 |
27.6 |
Luteolin 7-O-glucoside |
|
449, 285 |
C21H21O11
|
|
449.10797 |
449.1089 |
-2.148 |
269, 345 |
|
* |
|
1 |
5373-11-5 |
std |
61 |
29.6 |
Chrysin 6-C-[2"-O-pentoside]-glucoside |
547, 277, 175 |
549, 417, 399, 351, 321, 267 |
C26H27O13
|
|
547.276 |
547.277 |
1.8979 |
265, 331 |
* |
|
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
62 |
30.3 |
Chrysin 6-C-[2"-O-deoxyhexoside]-glucoside |
561, 277, 175 |
563, 417, 399, 351, 321, 267 |
C27H29O13
|
|
561.1614 |
561.1613 |
-0.203 |
269, 331 |
* |
* |
|
3 |
|
Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
63 |
32.7 |
Blumenol C |
|
211, 175, 133, 119 |
C13H23O2
|
|
211.16896 |
211.1693 |
-1.404 |
255 |
|
* |
|
2 |
36151-02-7 |
Peipp et al., 1997Peipp, H., Maier, W., Schmidt, J., Wray, V., Strack, D., 1997. Arbuscular mycorrhizal fungus-induced changes in the accumulation of secondary compounds in barley roots. Phytochemistry 44, 581-587.; Marino et al., 2008Marino, S., Gala, F., Zollo, F., Vitalini, S., Fico, G., Visioli, F., Iorizzi, M., 2008. Identification of minor secondary metabolites from the latex of Croton lechleri (Muell-Arg) and evaluation of their antioxidant activity. Molecules 13, 1219-1229.
|
64 |
34.2 |
Phillygenin O-glucoside-O-pentoside |
665, 503, 371 |
|
C32H41O15
|
|
665.24664 |
665.25 |
2.325 |
274 |
|
|
* |
3 |
|
Eklund et al., 2008Eklund, P.C., Backman, M.J., Kronberg, L.A., Smeds, A.I., Sjöholm, R.E., 2008. Identification of lignans by liquid chromatography-electrospray ionization ion-trap mass spectrometry. J. Mass. Spectrom. 43, 97-107.
|
65 |
34.7 |
Chrysin 6-C-glucoside |
|
417, 351 |
C21H19O9
|
|
415.1035 |
415.1035 |
0.0716 |
265, 333 |
* |
|
|
3 |
28368-57-2 |
Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
66 |
35.4 |
Isoorientin 2"-O-deoxyhexoside (luteolin 6-C-glucoside 2"-O-deoxyhexoside) |
|
595, 449, 413, 329, 299 |
C27H29O15
|
|
593.1501 |
593.1522 |
3.58 |
269, 346 |
|
* |
|
3 |
|
Piasecka et al., 2015Piasecka, A., Sawikowska, A., Krajewski, P., Kachlicki, P., 2015. Combined mass spectrometric and chromatographic methods for in-depth analysis of phenolic secondary metabolites in barley leaves. J. Mass Spectrom. 50, 513-532.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
67 |
36.1 |
Luteolin O-glucoside-O-deoxyhexoside |
|
595, 449, 431, 287 |
C27H29O16
|
|
593.1507 |
593.1522 |
3.58 |
271, 348 |
|
* |
|
3 |
|
Kachlicki et al., 2008Kachlicki, P., Einhorn, J., Muth, D., Kerhoas, L., Stobiecki, M., 2008. Evaluation of glycosylation and malonylation patterns in flavonoid glycosides during LC/MS/MS metabolite profiling. J. Mass Spectrom. 43, 572-586.
|
68 |
36.5 |
Blumenol B glucoside |
387, 369, 225, 207 |
|
C19H31O8
|
|
387.20255 |
387.2024 |
0.281 |
256 |
|
|
* |
3 |
|
Marino et al., 2008Marino, S., Gala, F., Zollo, F., Vitalini, S., Fico, G., Visioli, F., Iorizzi, M., 2008. Identification of minor secondary metabolites from the latex of Croton lechleri (Muell-Arg) and evaluation of their antioxidant activity. Molecules 13, 1219-1229.
|
69 |
37.4 |
Apigenin-6-C-deoxyhexoside-7-O-glucoside |
577, 415, 311, 283 |
|
C27H29O14
|
|
577.1552 |
577.1533 |
-3.3312 |
269, 335 |
* |
|
|
3 |
|
Simigriotis et al., 2013Simigriotis, M.J., Schmeda-Hirschmann, G., Borquez, J., Kennelly, E.J., 2013. The Passiflora tripartita (Banana Passion) fruit: a source of bioactive flavonoid C-glycosides isolated by HSCCC and characterized by HPLC–DAD–ESI/MS/MS. Molecules 18, 1672-1692.
|
70 |
37.5 |
Blumenol C pentoside |
341, 209 |
|
C18H29O6
|
|
341.19672 |
341.197 |
-0.709 |
255 |
|
|
* |
3 |
|
Peipp et al., 1997Peipp, H., Maier, W., Schmidt, J., Wray, V., Strack, D., 1997. Arbuscular mycorrhizal fungus-induced changes in the accumulation of secondary compounds in barley roots. Phytochemistry 44, 581-587.; Marino et al., 2008Marino, S., Gala, F., Zollo, F., Vitalini, S., Fico, G., Visioli, F., Iorizzi, M., 2008. Identification of minor secondary metabolites from the latex of Croton lechleri (Muell-Arg) and evaluation of their antioxidant activity. Molecules 13, 1219-1229.
|
71 |
37.5 |
orientin 2"-O-dideoxyhexoside (luteolin 8-C-glucoside 2"-O-dideoxyhexoside |
|
579, 431, 413, 335, 299 |
C27H29O14
|
|
577.15668 |
577.1563 |
0.695 |
269, 344 |
|
* |
|
3 |
|
Piasecka et al., 2015Piasecka, A., Sawikowska, A., Krajewski, P., Kachlicki, P., 2015. Combined mass spectrometric and chromatographic methods for in-depth analysis of phenolic secondary metabolites in barley leaves. J. Mass Spectrom. 50, 513-532.; Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.
|
72 |
38.6 |
Chrysin O-deoxyhexoside-O-glucoside |
|
563, 417, 255
|
C27H29O13
|
|
561.1614 |
561.1617 |
0.5668 |
264, 331 |
* |
|
|
3 |
|
Wojakowska et al., 2013Wojakowska, A., Piasecka, A., García-López, P.M., Zamora-Natera, F., Krajewski, P., Marczak, Ł., Kachlicki, P., Stobiecki, M., 2013. Structural analysis and profiling of phenolic secondary metabolites of Mexican lupine species using LC-MS techniques. Phytochemistry 92, 71-86.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
73 |
39.1 |
Myricetin glucosyldeoxyhexoside |
625, 463, 317
|
|
C27H45O16
|
|
625.2713 |
625.2718 |
0.77 |
271, 355 |
* |
|
|
3 |
|
Simigriotis et al., 2013Simigriotis, M.J., Schmeda-Hirschmann, G., Borquez, J., Kennelly, E.J., 2013. The Passiflora tripartita (Banana Passion) fruit: a source of bioactive flavonoid C-glycosides isolated by HSCCC and characterized by HPLC–DAD–ESI/MS/MS. Molecules 18, 1672-1692.
|
74 |
40.1 |
Cyclopassifloic acid glucoside |
697, 535, 517
|
|
C37H61O12
|
|
697.41718 |
697.4169 |
0.473 |
244 |
|
* |
|
3 |
|
Yoshikawa et al., 2000Yoshikawa, K., Katsuta, S., Mizumori, J., Arihara, S., 2000. New cycloartane triterpenoids from Passiflora edulis. J. Nat. Prod. 63, 1377-1380.
|
75 |
41.7 |
Luteolin 6-C-deoxyhexoside 7-O-glucoside |
593, 431, 327 |
595, 449, 431, 413, 329, 299 |
C27H29O15
|
|
593.1989 |
593.1479 |
-3.9288 |
269, 347 |
|
* |
|
3 |
|
Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
76 |
42.7 |
Apigenin O-deoxyhexoside-O-glucoside |
577, 415, 269 |
|
C27H29O14
|
|
577.15649 |
577.1563 |
0.366 |
269, 333 |
|
* |
|
3 |
|
Cuyckens et al., 2001Cuyckens, F., Rozenberg, R., de Hoffmann, E., Claeys, M., 2001. Structure characterization of flavonoid O-diglycosides by positive and negative nano-electrospray ionization ion trap mass spectrometry. J. Mass Spectrom. 6, 1203-1210.
|
77 |
43.6 |
Dicaffeoylquinic acid |
515, 353
|
517, 193 |
C25 H39 O11
|
|
515.25018 |
515.2498 |
0.766 |
315 |
|
* |
|
2 |
89919-62-0 |
Clifford et al., 2005Clifford, M.N., Knight, S., Kuhnert, N., 2005. Discriminating between six isomers of dicaffeoylquinic acid by LC-MSn. J. Agric. Food Chem. 53, 3821-3832.
|
78 |
44.4 |
Chrysin 6-C-deoxyhexoside-7-O-glucoside |
561, 399, 295 |
|
C27H29O13
|
|
561.16199 |
561.1614 |
1.1106 |
264, 331 |
|
* |
|
3 |
|
Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
79 |
46 |
Apigenin 6-C-[2"-O-deoxyhexoside]-deoxyhexoside |
561, 397, 293 |
|
C27H29O13
|
|
561.16144 |
561.1614 |
0.1317 |
269, 335 |
|
* |
|
3 |
|
Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.; Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
80 |
46.7 |
Chrysin 6-C-glucoside-6"-O-deoxyhexoside- |
561, 457, 295 |
563, 401, 365, 311 |
C27H29O13
|
|
561.16199 |
561.1614 |
1.115 |
266, 333 |
|
* |
|
3 |
|
Zucolotto et al., 2011Zucolotto, S.M., Fagundes, C., Reginatto, F.H., Ramos, F.A., Castellanos, L., Duque, C., Schenkel, E.P., 2011. Analysis of C-glycosyl flavonoids from South American Passiflora species by HPLC-DAD and HPLC-MS. Phytochem. Anal. 23, 232-239.
|
81 |
47.1 |
Apigenin-8-C-deoxyhexoside-7-O-glucoside |
577, 473, 415, 353, 311, 283 |
579, 417, 399, 355 |
C27H29O14
|
|
577.15729 |
577.1563 |
1.752 |
269, 334 |
|
* |
|
3 |
|
Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.
|
82 |
47.7 |
Luteolin 8-C-[6"-O-glucoside]-dideoxyhexoside |
577,473, 415, 357, 327
|
|
C27H29O14
|
|
577.15753 |
577.1563 |
2.168 |
269, 346 |
|
* |
|
3 |
|
Ferreres et al., 2003Ferreres, F., Silca, B.M., Andrade, P.B., Seabra, R.M., Ferreira, M.A., 2003. Approach to the study of C-glycosyl flavones by ion trap HPLC-PAD-ESI/MS/MS: application to seeds of quince (Cydonia oblonga). Phytochem. Anal. 14, 352-359.; Ferreres et al., 2007Ferreres, F., Gil-Izquierdo, A., Andrade, P.B., Valentao, P., Tomas-Barberan, F.A., 2007. Characterization of C-glycosyl flavones O-glycosylated by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1161, 214-223.; Xu et al., 2013Xu, F., Wang, C., Yang, L., Luo, H., Fan, W., Zi, C., Dong, F., Hua, J., Zhou, J., 2013. C-dideoxyhexosyl flavones from the stems and leaves of Passiflora edulis Sims. Food Chem. 136, 94-99.
|